Measuring the soot onset temperature in high-pressure n-dodecane spray pyrolysis

Skeen, Scott A.; Yasutomi, Koji

doi:10.1016/j.combustflame.2017.09.030

Title: Measuring the soot onset temperature in high-pressure n-dodecane spray pyrolysis

Journal Article · Sun Nov 05 00:00:00 EDT 2017 · Combustion and Flame

DOI:https://doi.org/10.1016/j.combustflame.2017.09.030· OSTI ID:1473931

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Sandia National Lab. (SNL-CA), Livermore, CA (United States). Combustion Research Facility

In this paper, soot formation in pyrolyzing sprays of n-dodecane is visualized and quantified in a high-pressure, high-temperature, constant-volume spray chamber at 38 bar, 76 bar, and 114 bar. Sprays of n-dodecane are injected at 500 bar from a single-hole, 186-µm orifice diameter fuel injector. We quantify the temporal evolution of the soot optical thickness and the total soot mass formed in the pyrolyzing sprays using a high-speed extinction imaging diagnostic. The vessel ambient temperature and pressure are varied independently to identify the soot onset temperature for n-dodecane pyrolysis. Linear extrapolation of the maximum soot formation rates as a function of ambient temperature reveals a soot onset temperature near 1450 K. Finally, the onset temperature determined here for n-dodecane is within 50 K of those previously measured along the centerline of atmospheric pressure coflow diffusion flames for smaller alkane fuels.

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Research Organization:: Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); SNL Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: NA0003525

OSTI ID:: 1473931

Alternate ID(s):: OSTI ID: 1576831

Report Number(s):: SAND-2018-9941J; 667773

Journal Information:: Combustion and Flame, Vol. 188; ISSN 0010-2180

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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References (25)

Comparative study of soot formation on the centerline of axisymmetric laminar diffusion flames: Fuel and temperature effects Gomez, A.; Littman, M. G.; Glassman, I. Combustion and Flame, Vol. 70, Issue 2 https://doi.org/10.1016/0010-2180(87)90081-2	journal	November 1987
A Study of the Early History of Soot Formation in Various Hydrocarbon Diffusion Flames Saito, K.; Gordon, A. S.; Williams, F. A. Combustion Science and Technology, Vol. 80, Issue 1-3 https://doi.org/10.1080/00102209108951779	journal	November 1991
Soot zone structure and sooting limit in diffusion flames: Comparison of counterflow and co-flow flames Kang, K. T.; Hwang, J. Y.; Chung, S. H. Combustion and Flame, Vol. 109, Issue 1-2 https://doi.org/10.1016/S0010-2180(96)00163-0	journal	April 1997
Measurement and analysis of soot inception limits of oxygen-enriched coflow flames Kumfer, B. M.; Skeen, S. A.; Chen, R. Combustion and Flame, Vol. 147, Issue 3 https://doi.org/10.1016/j.combustflame.2006.08.004	journal	November 2006
Soot inception limits in laminar diffusion flames with application to oxy–fuel combustion Kumfer, B. M.; Skeen, S. A.; Axelbaum, R. L. Combustion and Flame, Vol. 154, Issue 3 https://doi.org/10.1016/j.combustflame.2008.03.008	journal	August 2008
Flow time effects on hydrocarbon growth and soot formation in coflowing methane/air non-premixed flames McEnally, Charles S.; Pfefferle, Lisa D. Symposium (International) on Combustion, Vol. 27, Issue 1 https://doi.org/10.1016/S0082-0784(98)80562-6	journal	January 1998
Comparison of non-fuel hydrocarbon concentrations measured in coflowing nonpremixed flames fueled with small hydrocarbons McEnally, Charles S.; Pfefferle, Lisa D. Combustion and Flame, Vol. 117, Issue 1-2 https://doi.org/10.1016/S0010-2180(98)00102-3	journal	April 1999
Modeling and measurements of soot and species in a laminar diffusion flame Kennedy, Ian M.; Yam, Clement; Rapp, Darrell C. Combustion and Flame, Vol. 107, Issue 4 https://doi.org/10.1016/S0010-2180(96)00092-2	journal	December 1996
Effect of fuel structure on pathways to soot Frenklach, Michael; Clary, David W.; Gardiner, William C. Symposium (International) on Combustion, Vol. 21, Issue 1 https://doi.org/10.1016/S0082-0784(88)80337-0	journal	January 1988
Shock-tube pyrolysis of chlorinated hydrocarbons: Formation of soot Frenklach, M.; Hsu, J. P.; Miller, D. L. Combustion and Flame, Vol. 64, Issue 2 https://doi.org/10.1016/0010-2180(86)90051-9	journal	May 1986
Soot formation in shock-tube oxidation of hydrocarbons Frenklach, M.; Ramachandra, M. K.; Matula, R. A. Symposium (International) on Combustion, Vol. 20, Issue 1 https://doi.org/10.1016/S0082-0784(85)80576-2	journal	January 1985
Soot particle size and soot yield in shock tube studies Frenklach, M.; Taki, S.; Cheong, C. K. Li Kwok Combustion and Flame, Vol. 51 https://doi.org/10.1016/0010-2180(83)90081-0	journal	January 1983
Soot formation in shock-tube pyrolysis of acetylene, allene, and 1,3-butadiene☆ Frenklach, M.; Taki, S.; Durgaprasad, M. Combustion and Flame, Vol. 54, Issue 1-3 https://doi.org/10.1016/0010-2180(83)90024-X	journal	December 1983
A conceptual model for soot formation in pyrolysis of aromatic hydrocarbons Frenklach, M.; Taki, S.; Matula, R. A. Combustion and Flame, Vol. 49, Issue 1-3 https://doi.org/10.1016/0010-2180(83)90170-0	journal	January 1983
Effects of oxygen on soot formation in methane, propane, and n-Butane diffusion flames Gülder, Ömer L. Combustion and Flame, Vol. 101, Issue 3 https://doi.org/10.1016/0010-2180(94)00217-G	journal	May 1995
Effects of oxygen and propane addition on soot formation in counterflow ethylene flames and the role of C3 chemistry Hwang, J. Y.; Chung, S. H.; Lee, W. Symposium (International) on Combustion, Vol. 27, Issue 1 https://doi.org/10.1016/S0082-0784(98)80561-4	journal	January 1998
Diffuse back-illumination setup for high temporally resolved extinction imaging Westlye, Fredrik R.; Penney, Keith; Ivarsson, Anders Applied Optics, Vol. 56, Issue 17 https://doi.org/10.1364/AO.56.005028	journal	January 2017
Measurement of the dimensionless extinction coefficient of soot within laminar diffusion flames Williams, T. C.; Shaddix, C. R.; Jensen, K. A. International Journal of Heat and Mass Transfer, Vol. 50, Issue 7-8 https://doi.org/10.1016/j.ijheatmasstransfer.2006.08.024	journal	April 2007
Comparisons of the soot volume fraction using gravimetric and light extinction techniques Choi, M. Y.; Mulholland, G. W.; Hamins, A. Combustion and Flame, Vol. 102, Issue 1-2 https://doi.org/10.1016/0010-2180(94)00282-W	journal	July 1995
Modelling the internal structure of nascent soot particles Totton, Tim S.; Chakrabarti, Dwaipayan; Misquitta, Alston J. Combustion and Flame, Vol. 157, Issue 5 https://doi.org/10.1016/j.combustflame.2009.11.013	journal	May 2010
Mechanisms of soot nucleation in flames—A critical review Calcote, H. F. Combustion and Flame, Vol. 42 https://doi.org/10.1016/0010-2180(81)90159-0	journal	January 1981
The evolution of soot precursor particles in a diffusion flame Dobbins, R. A.; Fletcher, R. A.; Chang, H. -C. Combustion and Flame, Vol. 115, Issue 3 https://doi.org/10.1016/S0010-2180(98)00010-8	journal	November 1998
Fuel-structure dependence of benzene formation processes in premixed flames fueled by C6H12 isomers Hansen, N.; Kasper, T.; Yang, B. Proceedings of the Combustion Institute, Vol. 33, Issue 1 https://doi.org/10.1016/j.proci.2010.05.056	journal	January 2011
Exploring formation pathways of aromatic compounds in laboratory-based model flames of aliphatic fuels Hansen, N.; Miller, J. A.; Klippenstein, S. J. Combustion, Explosion, and Shock Waves, Vol. 48, Issue 5 https://doi.org/10.1134/S0010508212050024	journal	September 2012
Thermal decomposition of n-dodecane: Experiments and kinetic modeling Herbinet, Olivier; Marquaire, Paul-Marie; Battin-Leclerc, Frédérique Journal of Analytical and Applied Pyrolysis, Vol. 78, Issue 2 https://doi.org/10.1016/j.jaap.2006.10.010	journal	March 2007

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
soot
pyrolysis
high-speed imaging
spray combustion

Title: Measuring the soot onset temperature in high-pressure n-dodecane spray pyrolysis

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