Laser Rewritable Dichroics through Reconfigurable Organic Charge-Transfer Liquid Crystals

Van Winkle, Madeline; Scrymgeour, David A.; Kaehr, Bryan; Reczek, Joseph J.

doi:10.1002/adma.201706787

Laser Rewritable Dichroics through Reconfigurable Organic Charge-Transfer Liquid Crystals

Journal Article · Fri Mar 30 00:00:00 EDT 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201706787· OSTI ID:1473924

Van Winkle, Madeline ^[1]; Scrymgeour, David A. ^[2]; Kaehr, Bryan ^[2]; ^[1]

Denison Univ., Granville, OH (United States). Dept. of Chemistry and Biochemistry
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Advanced Materials Lab.

Charge-transfer materials based on the self-assembly of aromatic donor–acceptor complexes enable a modular organic-synthetic approach to develop and fine-tune electronic and optical properties, and thus these material systems stand to impact a wide range of technologies. Through laser-induction of temperature gradients, in this paper, user-defined patterning of strongly dichroic and piezoelectric organic thin films composed of donor–acceptor columnar liquid crystals is shown. Finally, fine, reversible control over isotropic versus anisotropic regions in thin films is demonstrated, enabling noncontact writing/rewriting of micropolarizers, bar codes, and charge-transfer based devices.

View Accepted Manuscript (DOE)

Research Organization:: Denison Univ., Granville, OH (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: Denison Univ. Research Foundation (United States); National Science Foundation (NSF) (United States); USDOE; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: NA0003525

OSTI ID:: 1473924

Alternate ID(s):: OSTI ID: 1430588

Report Number(s):: SAND--2018-10060J; 667847

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 20 Vol. 30; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

36 MATERIALS SCIENCE
columnar liquid crystals
dichroics
donor–acceptor materials
piezoelectric materials
rewritable media

Laser Rewritable Dichroics through Reconfigurable Organic Charge-Transfer Liquid Crystals

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