Synthesis and application of a metal ion coordinating ionic liquid monomer: Towards size and dispersity control of nanoparticles formed within a structured polyelectrolyte

Dreier, Timothy A.; Ringstrand, Bryan S.; Seifert, Sönke; Firestone, Millicent A.

doi:10.1016/j.eurpolymj.2018.08.017

Synthesis and application of a metal ion coordinating ionic liquid monomer: Towards size and dispersity control of nanoparticles formed within a structured polyelectrolyte

Journal Article · Tue Aug 07 00:00:00 EDT 2018 · European Polymer Journal

DOI:https://doi.org/10.1016/j.eurpolymj.2018.08.017· OSTI ID:1473822

^[1]; Ringstrand, Bryan S. ^[1]; Seifert, Sönke ^[2]; ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Sciences Division

Here, the design, synthesis, and characterization of an amphiphilic ionic liquid (IL) monomer possessing a transition metal coordinating acrylamide moiety is described. Incorporation of the acrylamide moiety is achieved by converting l-histidine into an imidazolium, followed by alkylation to introduce a decyl chain, and acrylation of the α-amino group. The acrylamide containing IL monomer and a co-monomer, poly(ethylene glycol) diacrylate (PEGDA M_n 575), self-assembles into a weakly ordered 2D hexagonal lyotropic mesophase in water (34 ± 2 (w/w)%). Upon photo-irradiation of the mesophase a nanostructured polyelectrolyte retaining the 2D hexagonal structure is produced. Doping the mesophase with Au³⁺ ions prior to photo-irradiation produces plasmonic Au NP copolymer composites only at a threshold mole ratio of IL monomer to gold ions (i.e., onset at 1740:1 mole ratio). At higher monomer to Au³⁺ mole ratios plasmonic NPs are not formed. Evaluation of the in-situ synthesized plasmonic Au NPs by SAXS and optical spectroscopy indicate they are smaller, more uniform spherical particles that resist aggregation upon swelling and de-swelling in ethanol when compared to previously reported composites employing an IL monomer that lacks a metal ion coordination site (e.g., 3-decyl-1-vinylimidazolium IL).

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: Argonne National Laboratory - Advanced Photon Source; Los Alamos National Laboratory (LANL); USDOE; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357; AC52-06NA25396

OSTI ID:: 1473822

Alternate ID(s):: OSTI ID: 1703153
OSTI ID: 1508371

Report Number(s):: LA-UR--18-27591

Journal Information:: European Polymer Journal, Journal Name: European Polymer Journal Journal Issue: C Vol. 107; ISSN 0014-3057

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
77 NANOSCIENCE AND NANOTECHNOLOGY
Acrylamide IL
Inorganic and Physical Chemistry
Material Science
Metal coordinating
Nanostructured
Plasmonic nanoparticles
Poly(ionic liquid)s
acrylamide IL
nanostructured
plasmonic nanoparticles

Synthesis and application of a metal ion coordinating ionic liquid monomer: Towards size and dispersity control of nanoparticles formed within a structured polyelectrolyte

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References (54)

Cited By (1)

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