CoO nanofiber decorated nickel foams as lithium dendrite suppressing host skeletons for high energy lithium metal batteries

Yue, Xin-Yang; Wang, Wei-Wen; Wang, Qin-Chao; Meng, Jing-Ke; Zhang, Zhao-Qiang; Wu, Xiao-Jing; Yang, Xiao-Qing; Zhou, Yong-Ning

doi:10.1016/j.ensm.2018.05.017

CoO nanofiber decorated nickel foams as lithium dendrite suppressing host skeletons for high energy lithium metal batteries

Journal Article · Thu May 17 00:00:00 EDT 2018 · Energy Storage Materials

DOI:https://doi.org/10.1016/j.ensm.2018.05.017· OSTI ID:1473663

Yue, Xin-Yang ^[1]; Wang, Wei-Wen ^[1]; Wang, Qin-Chao ^[1]; Meng, Jing-Ke ^[1]; Zhang, Zhao-Qiang ^[1]; Wu, Xiao-Jing ^[1]; Yang, Xiao-Qing ^[2]; Zhou, Yong-Ning ^[1]

Fudan Univ., Shanghai (China). Dept. of Materials Science
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division

Lithium metal is considered to be the most promising anode for the next-generation lithium batteries. However, dendrite growth due to uneven Li plating during battery cycling leads to short circuit and safety hazards, as well as shorted cycling life for the battery, which is the vital obstacle for the practical application of Li metal anode in lithium batteries. We report a CoO nanofiber decorated Ni foam (CONF) skeleton used as a 3D conductive host to suppress the dendrite formation for composite Li anode (CONF-Li) fabricated by thermal infusion method. The uniformly distributed CoO nanofibers on the Ni foam can improve the lithiophilicity of Ni foam, and decrease the local current inhomogeneity of the anode, leading to a mild and uniform Li plating/stripping behavior which effectively suppresses the Li dendrite formation. As a result, the electrochemical performances of CONF-Li anode are significantly improved both in symmetric cells and full cells (lithium-sulfur and lithium-LiNi_0.8Co_0.15Al_0.05O₂ cells) proving its advancement over the pure Li anode.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NNSFC); USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: SC0012704

OSTI ID:: 1473663

Alternate ID(s):: OSTI ID: 1496489

Report Number(s):: BNL--209067-2018-JAAM

Journal Information:: Energy Storage Materials, Journal Name: Energy Storage Materials Journal Issue: C Vol. 14; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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CoO nanofiber decorated nickel foams as lithium dendrite suppressing host skeletons for high energy lithium metal batteries

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References (45)

Cited By (7)

Figures / Tables (6)

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