Investigating the photodissociation of H2O2 using frequency modulation laser absorption spectroscopy to monitor radical products

Lockhart, James P. A.; Gross, Eisen C.; Sears, Trevor J.; Hall, Gregory E.

doi:10.1016/j.cplett.2018.09.004

Investigating the photodissociation of H₂O₂ using frequency modulation laser absorption spectroscopy to monitor radical products

Journal Article · Mon Sep 10 00:00:00 EDT 2018 · Chemical Physics Letters

DOI:https://doi.org/10.1016/j.cplett.2018.09.004· OSTI ID:1473654

Lockhart, James P. A. ^[1]; Gross, Eisen C. ^[2]; Sears, Trevor J. ^[3]; ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States). Division of Chemistry
Stony Brook Univ., NY (United States). Department of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Division of Chemistry; Stony Brook Univ., NY (United States). Department of Chemistry

In this study, the photodissociation of H₂O₂ dilute in argon at 193 nm has been investigated using near infrared frequency modulation laser absorption spectroscopy on selected rotational lines of the OH vibrational overtone bands between 6500 and 7100 cm^-1 to detect the OH and HO₂ radical products with the same laser. Sequential OH and HO₂ time-dependent profiles have been measured at room temperature and total pressures ranging from 3 to 56 Torr. Kinetic analysis gives the product distribution following H₂O₂ photolysis of (82±1) % OH and (18±1)% HO₂ under the present conditions, in excellent agreement with previously reported measurements.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0012704

OSTI ID:: 1473654

Alternate ID(s):: OSTI ID: 23115471

Report Number(s):: BNL--209064-2018-JAAM

Journal Information:: Chemical Physics Letters, Journal Name: Chemical Physics Letters Journal Issue: C Vol. 711; ISSN 0009-2614

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Kinetic study of the OH + ethylene reaction using frequency‐modulated laser absorption spectroscopy Lockhart, James P. A.; Gross, Eisen C.; Sears, Trevor J. International Journal of Chemical Kinetics, Vol. 51, Issue 6 https://doi.org/10.1002/kin.21265	journal	April 2019

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