Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery

Abraham, Alyson; Huang, Jianping; Smith, Paul F.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.

doi:10.1149/2.0371810jes

Title: Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)₂ Based Li/I₂ Battery

Journal Article · Wed Jul 11 00:00:00 EDT 2018 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0371810jes· OSTI ID:1473649

Abraham, Alyson ^[1];

^[1]; Smith, Paul F. ^[1];

^[2];

^[3];

^[2]

Stony Brook Univ., NY (United States). Dept. of Chemistry
Stony Brook Univ., NY (United States). Dept. of Chemistry and Department of Materials Science and Chemical Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
Stony Brook Univ., NY (United States). Dept. of Chemistry and Department of Materials Science and Chemical Engineering

While solid state electrolytes hold promise for safer batteries, the lithium/solid-state electrolyte interface has presented challenges. In this paper, we report a fully self-forming solid state rechargeable battery based on the Li/I2 couple using LiI rich lithium iodide-(3-hydroxyproprionitrile)2 electrolyte. Effective charge-discharge cycling was demonstrated, showing promise for future generations of high energy density self-forming, self-healing batteries.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: SC0012704; EE0007785

OSTI ID:: 1473649

Report Number(s):: BNL-209047-2018-JAAM

Journal Information:: Journal of the Electrochemical Society, Vol. 165, Issue 10; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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Progress and Outlook on few Component Composite Solid State Electrolytes Stackhouse, Chavis A.; Abraham, Alyson; Takeuchi, Kenneth J. MRS Advances, Vol. 4, Issue 49 https://doi.org/10.1557/adv.2019.264	journal	January 2019
Interface effects on self-forming rechargeable Li/I2-based solid state batteries Abraham, Alyson; Dunkin, Mikaela R.; Huang, Jianping MRS Communications, Vol. 9, Issue 02 https://doi.org/10.1557/mrc.2019.42	journal	April 2019

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Title: Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)₂ Based Li/I₂ Battery