Real-Time Monitoring of Cation Dissolution/Deintercalation Kinetics from Transition-Metal Oxides in Organic Environments

Lopes, Pietro P.; Zorko, Milena; Hawthorne, Krista L.; Connell, Justin G.; Ingram, Brian. J.; Strmcnik, Dusan; Stamenkovic, Vojislav R.; Markovic, Nenad M.

doi:10.1021/acs.jpclett.8b01936

Title: Real-Time Monitoring of Cation Dissolution/Deintercalation Kinetics from Transition-Metal Oxides in Organic Environments

Journal Article · Mon Jul 30 00:00:00 EDT 2018 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.8b01936· OSTI ID:1473598

^[1]; Zorko, Milena ^[1]; Hawthorne, Krista L. ^[1];

^[1]; Ingram, Brian. J. ^[1]; Strmcnik, Dusan ^[1]; Stamenkovic, Vojislav R. ^[1]; Markovic, Nenad M. ^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)

The future of high-voltage rechargeable batteries is closely tied to the fundamental understanding of the processes that lead to the potential-dependent degradation of electrode materials and organic electrolytes. To date, however, there have been no methods able to provide quantitative, in situ and in real time information about the electrode dissolution kinetics and concomitant electrolyte decomposition during charge/discharge. We describe the development of such a method, which is of both fundamental and technological significance. Our novel approach enables simultaneous and independent measurements of transition-metal cation dissolution rates from different oxide hosts (Co^3+/4+ or Cr^3+/4+), deintercalation kinetics of working cations (Mg²⁺), and the relative rate of electrolyte decomposition.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1473598

Journal Information:: Journal of Physical Chemistry Letters, Vol. 9, Issue 17; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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