Understanding Catalytic Activity Trends in the Oxygen Reduction Reaction

Kulkarni, Ambarish; Siahrostami, Samira; Patel, Anjli; Nørskov, Jens K.

doi:10.1021/acs.chemrev.7b00488

Understanding Catalytic Activity Trends in the Oxygen Reduction Reaction

Journal Article · Mon Feb 05 23:00:00 EST 2018 · Chemical Reviews

DOI:https://doi.org/10.1021/acs.chemrev.7b00488· OSTI ID:1471506

Kulkarni, Ambarish ^[1]; ^[1]; Patel, Anjli ^[1]; Nørskov, Jens K. ^[2]

Stanford Univ., CA (United States). SUNCAT Center for Interface Science and Catalysis, Dept. of Chemical Engineering
Stanford Univ., CA (United States). SUNCAT Center for Interface Science and Catalysis, Dept. of Chemical Engineering; SLAC National Accelerator Lab., Menlo Park, CA (United States)

Despite the dedicated search for novel catalysts for fuel cell applications, the intrinsic oxygen reduction reaction (ORR) activity of materials has not improved significantly over the past decade. Here in this paper, we review the role of theory in understanding the ORR mechanism and highlight the descriptor-based approaches that have been used to identify catalysts with increased activity. Specifically, by showing that the performance of the commonly studied materials (e.g., metals, alloys, carbons, etc.) is limited by unfavorable scaling relationships (for binding energies of reaction intermediates), we present a number of alternative strategies that may lead to the design and discovery of more promising materials for ORR.

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1471506

Journal Information:: Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 5 Vol. 118; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Intermetallic Pd ₃ Pb ultrathin nanoplate-constructed flowers with low-coordinated edge sites boost oxygen reduction performance Luo, Sai; Ou, Yang; Li, Lei Nanoscale, Vol. 11, Issue 37 https://doi.org/10.1039/c9nr04021h	journal	January 2019
Synthesis of low- and high-index faceted metal (Pt, Pd, Ru, Ir, Rh) nanoparticles for improved activity and stability in electrocatalysis Poerwoprajitno, Agus R.; Gloag, Lucy; Cheong, Soshan Nanoscale, Vol. 11, Issue 41 https://doi.org/10.1039/c9nr05802h	journal	January 2019
Co/Co ₉ S ₈ nanoparticles coupled with N,S-doped graphene-based mixed-dimensional heterostructures as bifunctional electrocatalysts for the overall oxygen electrode Wang, Zhi-Da; Bai, Cheng-Kun; Chen, Xin-Yu Inorganic Chemistry Frontiers, Vol. 6, Issue 9 https://doi.org/10.1039/c9qi00796b	journal	January 2019
The oxygen reduction reaction catalyzed by Synechocystis sp. PCC 6803 flavodiiron proteins Brown, Katherine A.; Guo, Zhanjun; Tokmina-Lukaszewska, Monika Sustainable Energy & Fuels, Vol. 3, Issue 11 https://doi.org/10.1039/c9se00523d	journal	January 2019
Carbon nanotube-linked hollow carbon nanospheres doped with iron and nitrogen as single-atom catalysts for the oxygen reduction reaction in acidic solutions Li, Jin-Cheng; Cheng, Min; Li, Tao Journal of Materials Chemistry A, Vol. 7, Issue 24 https://doi.org/10.1039/c9ta00508k	journal	January 2019
Pt-embedded in monolayer g-C ₃ N ₄ as a promising single-atom electrocatalyst for ammonia synthesis Yin, Hui; Li, Shu-Long; Gan, Li-Yong Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/c9ta01624d	journal	January 2019
Breaking the volcano-plot limits for Pt-based electrocatalysts by selective tuning adsorption of multiple intermediates Wang, Xuesi; He, Qun; Song, Li Journal of Materials Chemistry A, Vol. 7, Issue 22 https://doi.org/10.1039/c9ta02801c	journal	January 2019
Evidence for interfacial geometric interactions at metal–support interfaces and their influence on the electroactivity and stability of Pt nanoparticles Zhao, Xiao; Gunji, Takao; Kaneko, Takuma Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta12456j	journal	January 2020
Hydrogen peroxide electrochemical synthesis on hybrid double-atom (Pd–Cu) doped N vacancy g-C ₃ N ₄ : a novel design strategy for electrocatalyst screening Cao, Yongyong; Zhao, Chenxia; Fang, Qiaojun Journal of Materials Chemistry A, Vol. 8, Issue 5 https://doi.org/10.1039/c9ta12468c	journal	January 2020
The identification of optimal active boron sites for N ₂ reduction Yin, Hui; Gan, Li-Yong; Wang, Ping Journal of Materials Chemistry A, Vol. 8, Issue 7 https://doi.org/10.1039/c9ta13700a	journal	January 2020
DFT-MD of the (110)-Co 3 O 4 cobalt oxide semiconductor in contact with liquid water, preliminary chemical and physical insights into the electrochemical environment Creazzo, Fabrizio; Galimberti, Daria Ruth; Pezzotti, Simone The Journal of Chemical Physics, Vol. 150, Issue 4 https://doi.org/10.1063/1.5053729	journal	January 2019
Effect of surface-bound sulfide on oxygen reduction reaction on Pt: Breaking the scaling relationship and mechanistic insights Wang, Yan-Yan; Chen, De-Jun; Allison, Thomas C. The Journal of Chemical Physics, Vol. 150, Issue 4 https://doi.org/10.1063/1.5053815	journal	January 2019
ZIF-derived carbons as highly efficient and stable ORR catalyst Lv, Luqiang; Kang, Shuai; Li, Xu Nanotechnology, Vol. 29, Issue 48 https://doi.org/10.1088/1361-6528/aae0ae	journal	October 2018
Cobalt sulfide/N,S-codoped defect-rich carbon nanotubes hybrid as an excellent bi-functional oxygen electrocatalyst Chen, Lulu; Yang, Wenxiu; Liu, Xiangjian Nanotechnology, Vol. 30, Issue 7 https://doi.org/10.1088/1361-6528/aaf457	journal	December 2018
Beyond dealloying: development of nanoporous gold via metal-induced crystallization and its electrochemical properties Zhang, An; Wang, Jiangyong; Schützendübe, Peter Nanotechnology, Vol. 30, Issue 37 https://doi.org/10.1088/1361-6528/ab2616	journal	June 2019
Unravelling electrocatalytic properties of metal porphyrin-like complexes hosted in graphene matrices Risplendi, Francesca; Re Fiorentin, Michele; Cicero, Giancarlo 2D Materials, Vol. 7, Issue 2 https://doi.org/10.1088/2053-1583/ab6a5f	journal	February 2020
Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells Tian, Xinlong; Zhao, Xiao; Su, Ya-Qiong Science, Vol. 366, Issue 6467 https://doi.org/10.1126/science.aaw7493	journal	November 2019
Oxygen Reduction Reaction Mechanisms on Heteroatom-Doped Single-Walled Carbon Nanotube Catalysts: Insights from a Theoretical Study Wang, Ying; Song, Wei; Li, Meiqing Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.1071910jes	journal	January 2019
Core-Shell Polydopamine@Zr-Hemin MOFs Derived Fe-N-Doped Porous Carbon Nanospheres Electrocatalysts for the Oxygen Reduction Wang, Yinling; Wang, Juan; Zhang, Youliang Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.1101810jes	journal	January 2018
Metallosupramolecular Polymer Precursor Design for Multi-Element Co-Doped Carbon Shells with Improved Oxygen Reduction Reaction Catalytic Activity Wu, Yuzhe; Li, Yuntong; Mao, Jie Catalysts, Vol. 9, Issue 1 https://doi.org/10.3390/catal9010102	journal	January 2019
The Challenge of Achieving a High Density of Fe-Based Active Sites in a Highly Graphitic Carbon Matrix Li, Jingkun; Jia, Qingying; Mukerjee, Sanjeev Catalysts, Vol. 9, Issue 2 https://doi.org/10.3390/catal9020144	journal	February 2019
Metal Chalcogenides on Silicon Photocathodes for Efficient Water Splitting: A Mini Overview Joe, Jemee; Yang, Hyunwoo; Bae, Changdeuck Catalysts, Vol. 9, Issue 2 https://doi.org/10.3390/catal9020149	journal	February 2019

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