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Title: An Operando Study of the Initial Discharge of Bi and Bi/Cu Modified MnO 2

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/2.0221813jes· OSTI ID:1471126
ORCiD logo; ; ; ; ; ; ; ; ; ORCiD logo;

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
Grant/Contract Number:
AR0000150; AC02-06CH11357; SC0012704
OSTI ID:
1471126
Alternate ID(s):
OSTI ID: 1477743; OSTI ID: 1480921
Report Number(s):
BNL-209419-2018-JAAM; /jes/165/13/A2935.atom
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Vol. 165 Journal Issue: 13; ISSN 0013-4651
Publisher:
The Electrochemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 15 works
Citation information provided by
Web of Science

References (63)

Synthesis of cryptomelane type α-MnO 2 (K x Mn 8 O 16 ) cathode materials with tunable K + content: the role of tunnel cation concentration on electrochemistry journal January 2017
The Manganese Dioxide Electrode in Alkaline Electrolyte; The Electron-Proton Mechanism for the Discharge Process from MnO[sub 2] to MnO[sub 1.5] journal January 1966
Potassium-Based α-Manganese Dioxide Nanofiber Binder-Free Self-Supporting Electrodes: A Design Strategy for High Energy Density Batteries journal May 2016
Manganese(III) Chemistry in KOH Solutions in the Presence of Bi- or Ba-Containing Compounds and Its Implications on the Rechargeability of γ-MnO[sub 2] in Alkaline Cells journal January 2003
Characterization of the Bismuth-Modified Manganese Dioxide Cathodes in Rechargeable Alkaline Cells journal January 2002
Impact of cathode additives on the cycling performance of rechargeable alkaline manganese dioxide–zinc batteries for energy storage applications journal December 2016
Rechargeability and economic aspects of alkaline zinc–manganese dioxide cells for electrical storage and load leveling journal February 2015
The manganese dioxide electrode part XI: An X-ray diffraction study of materials produced by H insertion into an EMD journal February 1991
Stripping Voltammetry for the Real Time Determination of Zinc Membrane Diffusion Coefficients in High pH: Towards Rapid Screening of Alkaline Battery Separators journal July 2017
Evaluation of a ceramic separator for use in rechargeable alkaline Zn/MnO2 batteries journal August 2018
In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism journal January 2015
General Strategy for Zero-Valent Intercalation into Two-Dimensional Layered Nanomaterials journal March 2014
Structural properties of CuO/TiO2 nanorod in relation to their catalytic activity for simultaneous hydrogen production under solar light journal December 2013
Rapid electrochemical synthesis of δ-MnO2 from γ-MnO2 and unleashing its performance as an energy dense electrode journal December 2017
A Combined SNIFTIRS and XANES Study of Electrically Polarized Copper Electrodes in DMSO and DMF Solutions of Cyanate (NCO − ), Thiocyanate (NCS − ) and Selenocyanate (NCSe − ) Ions journal January 2015
Effect of Multiple Cation Electrolyte Mixtures on Rechargeable Zn–MnO 2 Alkaline Battery journal June 2016
Deposition of Nickel on Electrodeposited Cu 2 O Films at Potentials More Positive than the Nernst Potential of Ni 2+ /Ni 0 journal January 2017
Role of Bismuth and Factors Influencing the Formation of Mn[sub 3]O[sub 4] in Rechargeable Alkaline Batteries Based on Bismuth-Containing Manganese Oxides journal January 2003
The structure and ordering of ε-MnO2 journal March 2006
Cation Vacancies in MnO[sub 2] and Their Influence on Electrochemical Reactivity journal January 1988
Solubilities of Mn(II) and Mn(III) Ions in Concentrated Alkaline Solutions journal January 1966
Structural features of γ-phase Bi2O3 and its place in the sillenite family journal October 1992
A calcium hydroxide interlayer as a selective separator for rechargeable alkaline Zn/MnO2 batteries journal August 2017
Cathodic Reduction Mechanism of MnOOH to Mn(OH)[sub 2] in Alkaline Electrolyte journal January 1968
The electrochemistry of β-MnO2 and γ-MnO2 in alkaline electrolyte journal March 1975
Early science commissioning results of the sub-micron resolution X-ray spectroscopy beamline (SRX) in the field of materials science and engineering
  • Chen-Wiegart, Yu-chen Karen; Williams, Garth; Zhao, Chonghang
  • ICXOM23: International Conference on X-ray Optics and Microanalysis, AIP Conference Proceedings https://doi.org/10.1063/1.4961138
conference January 2016
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions journal April 2016
In situ X-ray absorption spectroscopic studies of copper in a copper-rich sludge during electrokinetic treatments journal February 2010
Energy Dispersive X-ray Diffraction Profiling of Prototype LiMn 2 O 4 -Based Coin Cells journal January 2013
In situ X-ray diffraction of prototype sodium metal halide cells: Time and space electrochemical profiling journal February 2011
Rechargeability of MnO[sub 2] in KOH Media Produced by Decomposition of Dissolved KMnO[sub 4] and Bi(NO[sub 3])[sub 3] Mixtures journal January 1997
Rechargeability of MnO[sub 2] in KOH Media Produced by Decomposition of Dissolved KMnO[sub 4] and Bi(NO[sub 3])[sub 3] Mixtures journal January 1997
Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy journal May 2012
Operando identification of the point of [Mn2]O4 spinel formation during γ-MnO2 discharge within batteries journal July 2016
Water in the interlayer region of birnessite: Importance in cation exchange and structural stability journal April 2006
Nanometer-sized, divalent-Mn, hydrous silicate domains in geothermal brine precipitates journal February 2005
Intercalation and Conversion Reactions of Nanosized β-MnO 2 Cathode in the Secondary Zn/MnO 2 Alkaline Battery journal May 2018
Impact of Triethanolamine as an Additive for Rechargeable Alkaline Zn/MnO 2 Batteries under Limited Depth of Discharge Conditions journal January 2017
Structural and electrochemical properties of the proton / γ-MnO2 system journal January 1995
Energy dispersive X-ray diffraction of lithium–silver vanadium phosphorous oxide cells: in situ cathode depth profiling of an electrochemical reduction–displacement reaction journal January 2013
Controllable synthesis and magnetic property of BiMn2O5 crystals journal July 2008
X-ray absorption edge determination of the oxidation state and coordination number of copper. Application to the type 3 site in Rhus vernicifera laccase and its reaction with oxygen journal October 1987
High-Density Chemical Intercalation of Zero-Valent Copper into Bi 2 Se 3 Nanoribbons journal April 2012
A conversion-based highly energy dense Cu 2+ intercalated Bi-birnessite/Zn alkaline battery journal January 2017
Potential dependence of cuprous/cupric duplex film growth on copper electrode in alkaline media journal November 2006
Rechargeable Cells with Modified MnO[sub 2] Cathodes journal January 1988
Redox Processes at the Manganese Dioxide Electrode journal January 1997
Modeling of Cylindrical Alkaline Cells journal January 1993
Electrochemical Behavior of Electrolytic Manganese Dioxide in Aqueous KOH and LiOH Solutions: A Comparative Study journal December 2015
Hetaerolite Profiles in Alkaline Batteries Measured by High Energy EDXRD journal November 2014
Rechargeable manganese oxide electrodes journal December 1987
Coexistence of several sillenite-like phases in pseudo-binary and pseudo-ternary systems based on Bi2O3 journal November 2013
A Stoichiometric Model for Sillenites journal August 2002
Modeling of Cylindrical Alkaline Cells journal January 1994
Redox Processes at the Manganese Dioxide Electrode journal January 1997
Redox Processes at the Manganese Dioxide Electrode journal January 1997
Rechargeable manganese oxide electrodes journal May 1987
Hydrogen Bonding and Jahn–Teller Distortion in Groutite,α-MnOOH, and Manganite,γ-MnOOH, and Their Relations to the Manganese Dioxides Ramsdellite and Pyrolusite journal November 1997
Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries journal March 2017
Improvements of the Rechargeable Alkaline MnO[sub 2]-Zn Cell journal January 1996
Strain field and scattered intensity profiling with energy dispersive x-ray scattering journal July 2002
Zerovalent Copper Intercalated Birnessite as a Cathode for Lithium Ion Batteries: Extending Cycle Life journal January 2017
Understanding the Second Electron Discharge Plateau in MnO[sub 2]-Based Alkaline Cells journal January 2001

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
alkaline battery
manganese dioxide
operando
36 MATERIALS SCIENCE