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A Wide Band Gap Polymer with a Deep Highest Occupied Molecular Orbital Level Enables 14.2% Efficiency in Polymer Solar Cells

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.8b02695· OSTI ID:1470933
 [1];  [2];  [1];  [3];  [1];  [4];  [1];  [2];  [1]
  1. Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (People's Republic of China)
  2. North Carolina State Univ., Raleigh, NC (United States)
  3. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  4. Chinese Academy of Sciences (CAS), Beijing (China)
To simultaneously achieve low photon energy loss (Eloss) and broad spectral response, the molecular design of the wide band gap (WBG) donor polymer with a deep HOMO level is of critical importance in fullerene-free polymer solar cells (PSCs). Herein, we developed a new benzodithiophene unit, i.e., DTBDT-EF, and conducted systematic investigations on a WBG DTBDT-EF-based donor polymer, namely, PDTB-EF-T. Due to the synergistic electron-withdrawing effect of the fluorine atom and ester group, PDTB-EF-T exhibits a higher oxidation potential, i.e., a deeper HOMO level (ca. –5.5 eV) than most well-known donor polymers. Hence, a high open-circuit voltage of 0.90 V was obtained when paired with a fluorinated small molecule acceptor (IT-4F), corresponding to a low Eloss of 0.62 eV. Furthermore, side-chain engineering demonstrated that subtle side-chain modulation of the ester greatly influences the aggregation effects and molecular packing of polymer PDTB-EF-T. With the benefits of the stronger interchain π–π interaction, the improved ordering structure, and thus the highest hole mobility, the most symmetric charge transport and reduced recombination are achieved for the linear decyl-substituted PDTB-EF-T (P2)-based PSCs, leading to the highest short-circuit current density and fill factor (FF). Due to the high Flory–Huggins interaction parameter (χ), surface-directed phase separation occurs in the P2:IT-4F blend, which is supported by X-ray photoemission spectroscopy results and cross-sectional transmission electron microscope images. By taking advantage of the vertical phase distribution of the P2:IT-4F blend, a high power conversion efficiency (PCE) of 14.2% with an outstanding FF of 0.76 was recorded for inverted devices. Lastly, these results demonstrate the great potential of the DTBDT-EF unit for future organic photovoltaic applications.
Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1470933
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 23 Vol. 140; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

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Benzo[1,2- b :4,5- b ′]diselenophene-fused nonfullerene acceptors with alternative aromatic ring-based and monochlorinated end groups: a new synergistic strategy to simultaneously achieve highly efficient organic solar cells with the energy loss of 0.49 eV journal January 2019
Stable large area organic solar cells realized by using random terpolymers donors combined with a ternary blend journal January 2019
Strategic end-halogenation of π-conjugated small molecules enabling fine morphological control and enhanced performance of organic solar cells journal January 2019
Design of wide-bandgap polymers with deeper ionization potential enables efficient ternary non-fullerene polymer solar cells with 13% efficiency journal January 2019
All-polymer solar cells based on a novel narrow-bandgap polymer acceptor with power conversion efficiency over 10% journal January 2019
High face-on ratio isoindigo copolymers with extended nano-fibrillar networks in fullerene-based thick (>300 nm) photovoltaics achieving a high efficiency of 10.7% journal January 2019
Enhanced efficiency and stability of PTB7-Th-based multi-non-fullerene solar cells enabled by the working mechanism of the coexisting alloy-like structure and energy transfer model journal January 2019
A non-fullerene acceptor based on alkylphenyl substituted benzodithiophene for high efficiency polymer solar cells with a small voltage loss and excellent stability journal January 2019
Non-halogenated-solvent-processed highly efficient organic solar cells with a record open circuit voltage enabled by noncovalently locked novel polymer donors journal January 2019
High-efficiency ternary nonfullerene polymer solar cells with increased phase purity and reduced nonradiative energy loss journal January 2020
High-performance non-fullerene polymer solar cells based on naphthobistriazole wide bandgap donor copolymers journal January 2019
A novel 9 H -indeno[1,2- b ]pyrazine-2,3-dicarbonitrile end group for an efficient non-fullerene small molecule acceptor journal January 2019
Fullerene-free polymer solar cells enabled with a PhI-based wide band gap donor polymer: promoting efficiencies via acceptor screening and device engineering journal January 2019
Simply planarizing nonfused perylene diimide based acceptors toward promising non-fullerene solar cells journal January 2019
Light manipulating electrode based on high optical haze aluminum-doped zinc oxide for highly efficient indium-tin-oxide free organic solar cells with over 13% efficiency journal January 2019
Side-chain engineering of wide-bandgap polymers based on benzo[1,2- b :4,5- b ′]dithiophene and [2,2′-bithiophene]-4,4′-dicarboxylate for fullerene-free organic solar cells journal January 2019
Thiophene copolymer for 1 V high open-circuit voltage semitransparent photovoltaic devices journal January 2019
Thiazolothienyl imide-based wide bandgap copolymers for efficient polymer solar cells journal January 2019
Improving the photovoltaic performance of fluorinated 2,2′-bithiophene core-based D(A–Ar) 2 type small molecules via strategically end-capped heteroaromatic substitution journal January 2019
A distorted lactam unit with intramolecular hydrogen bonds as the electron donor of polymer solar cells journal January 2019
Optimization of processing solvent and film morphology to achieve efficient non-fullerene polymer solar cells processed in air journal January 2020
Subnaphthalocyanine triimides: potential three-dimensional solution processable acceptors for organic solar cells journal January 2020
A relatively wide-bandgap and air-stable donor polymer for fabrication of efficient semitransparent and tandem organic photovoltaics journal October 2019
The side chain effects on TPD-based copolymers: the linear chain leads to a higher j sc journal May 2019
Performance enhancement of small molecular solar cells via luminescent sensitizer 4,5-bis(carbazol-9-yl)-1,2-dicyanobenzene (2CzPN) journal January 2020
A review of non-fullerene polymer solar cells: from device physics to morphology control journal February 2019
Novel 2D material from AMQS-based defect engineering for efficient and stable organic solar cells journal July 2019
Scalable fabrication of organic solar cells based on non-fullerene acceptors journal January 2020
Effects of Alkoxy and Fluorine Atom Substitution of Donor Molecules on the Morphology and Photovoltaic Performance of All Small Molecule Organic Solar Cells journal September 2018
PffBT4T-2OD Based Solar Cells with Aryl-Substituted N-Methyl-Fulleropyrrolidine Acceptors journal December 2019

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Influence of Donor Polymer on the Molecular Ordering of Small Molecular Acceptors in Nonfullerene Polymer Solar Cells
Journal Article · Tue Oct 03 20:00:00 EDT 2017 · Advanced Energy Materials · OSTI ID:1396413