Room-temperature ferromagnetism in Ni(ii)-chromia based core–shell nanoparticles: experiment and first principles calculations

Hossain, M. D.; Mayanovic, R. A.; Dey, S.; Sakidja, R.; Benamara, M.

doi:10.1039/c7cp08597d

Title: Room-temperature ferromagnetism in Ni(ii)-chromia based core–shell nanoparticles: experiment and first principles calculations

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/c7cp08597d· OSTI ID:1470636

^[1]; Mayanovic, R. A. ^[1]; Dey, S. ^[1]; Sakidja, R. ^[1]; Benamara, M. ^[2]

Department of Physics; Astronomy & Materials Science; Missouri State University; Springfield; USA
University of Arkansas Nano-Bio Materials Characterization Facility; University of Arkansas; Fayeteville; USA

We have synthesized bimagnetic core–shell nanoparticles containing a first-of-its-kind Ni(ii)-chromia nanophase shell and a well-defined, epitaxial core–shell interface.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001057

OSTI ID:: 1470636

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 15; Related Information: EFree partners with Carnegie Institution of Washington (lead); California Institute of Technology; Colorado School of Mines; Cornell University; Lehigh University; Pennsylvania State University; ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (54)

High Exchange Bias in Fe _3−δ O ₄ @CoO Core Shell Nanoparticles Synthesized by a One-Pot Seed-Mediated Growth Method Baaziz, Walid; Pichon, Benoît P.; Lefevre, Christophe The Journal of Physical Chemistry C, Vol. 117, Issue 21 https://doi.org/10.1021/jp402823h	journal	May 2013
Bimagnetic h-Co/h-CoO nanotetrapods: preparation, nanoscale characterization, three-dimensional architecture and their magnetic properties Deng, Xia; Yang, Dezheng; Tan, Guoguo Nanoscale, Vol. 6, Issue 22 https://doi.org/10.1039/C4NR02287D	journal	January 2014
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
Exchange-coupled magnetic nanoparticles for efficient heat induction Lee, Jae-Hyun; Jang, Jung-tak; Choi, Jin-sil Nature Nanotechnology, Vol. 6, Issue 7 https://doi.org/10.1038/nnano.2011.95	journal	June 2011
Precipitation and Solid Solubility in the System NiO-Cr2O3 Chen, Ching-Hwa; Notis, Michael R.; Williams, David B. Journal of the American Ceramic Society, Vol. 66, Issue 8 https://doi.org/10.1111/j.1151-2916.1983.tb10092.x	journal	August 1983
Density-functional theory and strong interactions: Orbital ordering in Mott-Hubbard insulators Liechtenstein, A. I.; Anisimov, V. I.; Zaanen, J. Physical Review B, Vol. 52, Issue 8 https://doi.org/10.1103/PhysRevB.52.R5467	journal	August 1995
Tuning Exchange Bias in Core/Shell FeO/Fe ₃ O ₄ Nanoparticles Sun, Xiaolian; Frey Huls, Natalie; Sigdel, Aruna Nano Letters, Vol. 12, Issue 1 https://doi.org/10.1021/nl2034514	journal	December 2011
Direct evidence for an interdiffused intermediate layer in bi-magnetic core–shell nanoparticles Juhin, Amélie; López-Ortega, Alberto; Sikora, Marcin Nanoscale, Vol. 6, Issue 20 https://doi.org/10.1039/C4NR02886D	journal	January 2014
Magnetic properties of core–shell nanoparticles possessing a novel Fe( ii )-chromia phase: an experimental and theoretical approach Hossain, Mohammad Delower; Mayanovic, Robert A.; Sakidja, Ridwan Nanoscale, Vol. 10, Issue 4 https://doi.org/10.1039/C7NR04770C	journal	January 2018
Influence of interfacial roughness on exchange bias in core-shell nanoparticles Evans, R. F. L.; Bate, D.; Chantrell, R. W. Physical Review B, Vol. 84, Issue 9 https://doi.org/10.1103/PhysRevB.84.092404	journal	September 2011
Size dependence of the magnetic properties of antiferromagnetic ${Cr}_{2} O_{3}$ nanoparticles Tobia, D.; Winkler, E.; Zysler, R. D. Physical Review B, Vol. 78, Issue 10 https://doi.org/10.1103/PhysRevB.78.104412	journal	September 2008
Applications of exchange coupled bi-magnetic hard/soft and soft/hard magnetic core/shell nanoparticles López-Ortega, Alberto; Estrader, Marta; Salazar-Alvarez, German Physics Reports, Vol. 553 https://doi.org/10.1016/j.physrep.2014.09.007	journal	February 2015
Tuning the magnetic coupling across ultrathin antiferromagnetic films by controlling atomic-scale roughness Kuch, W.; Chelaru, L. I.; Offi, F. Nature Materials, Vol. 5, Issue 2 https://doi.org/10.1038/nmat1548	journal	January 2006
Electronic Properties of Metallic Fine Particles. I. Kubo, Ryogo Journal of the Physical Society of Japan, Vol. 17, Issue 6 https://doi.org/10.1143/JPSJ.17.975	journal	June 1962
Magnetic Proximity Effect Features in Antiferromagnetic/Ferrimagnetic Core-Shell Nanoparticles Golosovsky, I. V.; Salazar-Alvarez, G.; López-Ortega, A. Physical Review Letters, Vol. 102, Issue 24 https://doi.org/10.1103/PhysRevLett.102.247201	journal	June 2009
Correlation between Exchange Bias and Pinned Interfacial Spins Ohldag, H.; Scholl, A.; Nolting, F. Physical Review Letters, Vol. 91, Issue 1 https://doi.org/10.1103/PhysRevLett.91.017203	journal	July 2003
Magnetic Structure of Cr ₂ O ₃ Corliss, L. M.; Hastings, J. M.; Nathans, R. Journal of Applied Physics, Vol. 36, Issue 3 https://doi.org/10.1063/1.1714118	journal	March 1965
NIH Image to ImageJ: 25 years of image analysis Schneider, Caroline A.; Rasband, Wayne S.; Eliceiri, Kevin W. Nature Methods, Vol. 9, Issue 7 https://doi.org/10.1038/nmeth.2089	journal	June 2012
Residual electron density study of chromium sesquioxide by crystal structure and scattering factor refinement Sawada, H. Materials Research Bulletin, Vol. 29, Issue 3 https://doi.org/10.1016/0025-5408(94)90019-1	journal	March 1994
Magnetic ordering and exchange effects in the antiferromagnetic solid solutions ${Mn}_{x} {Ni}_{1 - x} O$ Cheetham, A. K.; Hope, D. A. O. Physical Review B, Vol. 27, Issue 11 https://doi.org/10.1103/PhysRevB.27.6964	journal	June 1983
Room-Temperature Ferromagnetism in Antiferromagnetic Cobalt Oxide Nanooctahedra Fontaíña-Troitiño, Nerio; Liébana-Viñas, Sara; Rodríguez-González, Benito Nano Letters, Vol. 14, Issue 2 https://doi.org/10.1021/nl4038533	journal	January 2014
Classification of chemical bonds based on topological analysis of electron localization functions Silvi, B.; Savin, A. Nature, Vol. 371, Issue 6499 https://doi.org/10.1038/371683a0	journal	October 1994
Linear response approach to the calculation of the effective interaction parameters in the $LDA + U$ method Cococcioni, Matteo; de Gironcoli, Stefano Physical Review B, Vol. 71, Issue 3 https://doi.org/10.1103/PhysRevB.71.035105	journal	January 2005
Surface spin disorder and exchange-bias in hollow maghemite nanoparticles Khurshid, Hafsa; Li, Wanfeng; Phan, Manh-Huong Applied Physics Letters, Vol. 101, Issue 2 https://doi.org/10.1063/1.4733621	journal	July 2012
An experimental and theoretical study of the optical, electronic, and magnetic properties of novel inverted α-Cr ₂ O ₃ @α-Mn _0.35 Cr _1.65 O _2.94 core shell nanoparticles Hossain, Mohammad D.; Mayanovic, Robert A.; Sakidja, Ridwan Journal of Materials Research, Vol. 32, Issue 2 https://doi.org/10.1557/jmr.2016.504	journal	January 2017
CeO2-encapsulated noble metal nanocatalysts: enhanced activity and stability for catalytic application Song, Shuyan; Wang, Xiao; Zhang, Hongjie NPG Asia Materials, Vol. 7, Issue 5 https://doi.org/10.1038/am.2015.27	journal	May 2015
Exchange Bias Effect in CoO@Fe ₃ O ₄ Core–Shell Octahedron-Shaped Nanoparticles Fontaíña Troitiño, Nerio; Rivas-Murias, Beatriz; Rodríguez-González, Benito Chemistry of Materials, Vol. 26, Issue 19 https://doi.org/10.1021/cm501951u	journal	September 2014
Shape-dependent exchange bias effect in magnetic nanoparticles with core-shell morphology Dimitriadis, V.; Kechrakos, D.; Chubykalo-Fesenko, O. Physical Review B, Vol. 92, Issue 6 https://doi.org/10.1103/PhysRevB.92.064420	journal	August 2015
Enhanced UV Emission From Silver/ZnO And Gold/ZnO Core-Shell Nanoparticles: Photoluminescence, Radioluminescence, And Optically Stimulated Luminescence Guidelli, E. J.; Baffa, O.; Clarke, D. R. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep14004	journal	September 2015
Antiferromagnetic MnO nanoparticles with ferrimagnetic ${Mn}_{3} O_{4}$ shells: Doubly inverted core-shell system Berkowitz, A. E.; Rodriguez, G. F.; Hong, J. I. Physical Review B, Vol. 77, Issue 2 https://doi.org/10.1103/PhysRevB.77.024403	journal	January 2008
Enhanced Magnetic Properties in Antiferromagnetic-Core/Ferrimagnetic-Shell Nanoparticles Vasilakaki, Marianna; Trohidou, Kalliopi N.; Nogués, Josep Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep09609	journal	April 2015
Magnetism of chromia from first-principles calculations Shi, Siqi; Wysocki, A. L.; Belashchenko, K. D. Physical Review B, Vol. 79, Issue 10 https://doi.org/10.1103/PhysRevB.79.104404	journal	March 2009
A simple measure of electron localization in atomic and molecular systems Becke, A. D.; Edgecombe, K. E. The Journal of Chemical Physics, Vol. 92, Issue 9 https://doi.org/10.1063/1.458517	journal	May 1990
Spin dynamics and criteria for onset of exchange bias in superspin glass Fe/ $γ$ -Fe $_{2}$ O $_{3}$ core-shell nanoparticles Chandra, Sayan; Khurshid, H.; Li, Wanfeng Physical Review B, Vol. 86, Issue 1 https://doi.org/10.1103/PhysRevB.86.014426	journal	July 2012
From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties Byers, Chad P.; Zhang, Hui; Swearer, Dayne F. Science Advances, Vol. 1, Issue 11 https://doi.org/10.1126/sciadv.1500988	journal	December 2015
Magnetoelectric Switching of Exchange Bias Borisov, Pavel; Hochstrat, Andreas; Chen, Xi Physical Review Letters, Vol. 94, Issue 11 https://doi.org/10.1103/PhysRevLett.94.117203	journal	March 2005
Maximizing Exchange Bias in Co/CoO Core/Shell Nanoparticles by Lattice Matching between the Shell and the Embedding Matrix González, Juan A.; Andrés, Juan P.; López Antón, Ricardo Chemistry of Materials, Vol. 29, Issue 12 https://doi.org/10.1021/acs.chemmater.7b00868	journal	May 2017
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Ab initio calculation of chromium oxide containing Ti dopant Maldonado, Frank; Novillo, Corina; Stashans, Arvids Chemical Physics, Vol. 393, Issue 1 https://doi.org/10.1016/j.chemphys.2011.11.038	journal	January 2012
Synthesis and magnetic properties of core/shell FeO/Fe ₃ O ₄ nano-octopods Khurshid, Hafsa; Chandra, Sayan; Li, Wanfeng Journal of Applied Physics, Vol. 113, Issue 17 https://doi.org/10.1063/1.4794978	journal	May 2013
New Magnetic Anisotropy Meiklejohn, W. H.; Bean, C. P. Physical Review, Vol. 102, Issue 5 https://doi.org/10.1103/PhysRev.102.1413	journal	June 1956
Structural and optical characterization of Cr ₂ O ₃ nanostructures: Evaluation of its dielectric properties Abdullah, M. M.; Rajab, Fahd M.; Al-Abbas, Saleh M. AIP Advances, Vol. 4, Issue 2 https://doi.org/10.1063/1.4867012	journal	February 2014
Exchange bias in nanostructures Nogués, J.; Sort, J.; Langlais, V. Physics Reports, Vol. 422, Issue 3 https://doi.org/10.1016/j.physrep.2005.08.004	journal	December 2005
Novel highly ordered core–shell nanoparticles Dey, Sonal; Hossain, Mohammad D.; Mayanovic, Robert A. Journal of Materials Science, Vol. 52, Issue 4 https://doi.org/10.1007/s10853-016-0495-2	journal	October 2016
Improve the electrochemical performances of Cr2O3 anode for lithium ion batteries Hu, J.; Li, H.; Huang, X. Solid State Ionics, Vol. 177, Issue 26-32 https://doi.org/10.1016/j.ssi.2006.03.043	journal	October 2006
Strongly Exchange Coupled Core\|Shell Nanoparticles with High Magnetic Anisotropy: A Strategy toward Rare-Earth-Free Permanent Magnets Lottini, E.; López-Ortega, A.; Bertoni, G. Chemistry of Materials, Vol. 28, Issue 12 https://doi.org/10.1021/acs.chemmater.6b00623	journal	June 2016
New Magnetic Anisotropy Meiklejohn, W. H.; Bean, C. P. Physical Review, Vol. 105, Issue 3 https://doi.org/10.1103/PhysRev.105.904	journal	February 1957
Structural and Magnetic Properties of Ni Doped CeO<SUB>2</SUB> Nanoparticles Kumar, Shalendra; Kim, Young Joo; Koo, B. H. Journal of Nanoscience and Nanotechnology, Vol. 10, Issue 11 https://doi.org/10.1166/jnn.2010.2751	journal	November 2010
Improved grid-based algorithm for Bader charge allocation Sanville, Edward; Kenny, Steven D.; Smith, Roger Journal of Computational Chemistry, Vol. 28, Issue 5 https://doi.org/10.1002/jcc.20575	journal	January 2007
Core–shell nanoparticles: synthesis and applications in catalysis and electrocatalysis Gawande, Manoj B.; Goswami, Anandarup; Asefa, Tewodros Chemical Society Reviews, Vol. 44, Issue 21 https://doi.org/10.1039/C5CS00343A	journal	January 2015
Self-interaction correction to density-functional approximations for many-electron systems Perdew, J. P.; Zunger, Alex Physical Review B, Vol. 23, Issue 10, p. 5048-5079 https://doi.org/10.1103/PhysRevB.23.5048	journal	May 1981
Sol-gel synthesis and photoluminescence of p-type semiconductor Cr2O3 nanowires Cao, Huaqiang; Qiu, Xianqing; Liang, Yu Applied Physics Letters, Vol. 88, Issue 24 https://doi.org/10.1063/1.2213204	journal	June 2006
Indexing of powder diffraction patterns by iterative use of singular value decomposition Coelho, A. A. Journal of Applied Crystallography, Vol. 36, Issue 1 https://doi.org/10.1107/S0021889802019878	journal	January 2003
Robust antiferromagnetic coupling in hard-soft bi-magnetic core/shell nanoparticles Estrader, M.; López-Ortega, A.; Estradé, S. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3960	journal	December 2013

Similar Records

Room-temperature ferromagnetism in Ni( ii )-chromia based core–shell nanoparticles: experiment and first principles calculations

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1470636

Hossain, M. D.; Mayanovic, R. A.; Dey, S.; +2 more

Novel highly ordered core–shell nanoparticles

Journal Article · Wed Oct 26 00:00:00 EDT 2016 · Journal of Materials Science · OSTI ID:1470636

Dey, Sonal; Hossain, Mohammad D.; Mayanovic, Robert A.; +2 more

Ag@ZnO core-shell nanoparticles study by first principle: The structural, magnetic and optical properties

Journal Article · Thu Dec 15 00:00:00 EST 2016 · Journal of Solid State Chemistry · OSTI ID:1470636

Cheng, Hai-Xia; Wang, Xiao-Xu; Hu, Yao-Wen; +5 more

Related Subjects

catalysis (heterogeneous)
solar (photovoltaic)
phonons
thermoelectric
energy storage (including batteries and capacitors)
hydrogen and fuel cells
superconductivity
charge transport
mesostructured materials
materials and chemistry by design
synthesis (novel materials)

Title: Room-temperature ferromagnetism in Ni(ii)-chromia based core–shell nanoparticles: experiment and first principles calculations

Citation Formats

References (54)

Similar Records

Related Subjects