A thermodynamic investigation of adsorbate-adsorbate interactions of carbon dioxide on nanostructured carbons

Murialdo, Maxwell; Ahn, Channing C.; Fultz, Brent

doi:10.1002/aic.15996

A thermodynamic investigation of adsorbate-adsorbate interactions of carbon dioxide on nanostructured carbons

Journal Article · Tue Oct 10 00:00:00 EDT 2017 · AIChE Journal

DOI:https://doi.org/10.1002/aic.15996· OSTI ID:1470611

Murialdo, Maxwell ^[1]; Ahn, Channing C. ^[1]; Fultz, Brent ^[1]

California Inst. of Technology (CalTech), Pasadena, CA (United States). Dept. of Applied Physics and Materials Science

A thermodynamic study of carbon dioxide adsorption on a zeolite-templated carbon (ZTC), a superactivated carbon (MSC-30), and an activated carbon (CNS-201) was carried out at temperatures from 241 to 478 K and pressures up to 5.5•10⁶ Pa. Excess adsorption isotherms were fitted with generalized Langmuir-type equations, allowing the isosteric heats of adsorption and adsorbed-phase heat capacities to be obtained as a function of absolute adsorption. On MSC-30, a superactivated carbon, the isosteric heat of carbon dioxide adsorption increases with occupancy from 19 to 21 kJ•mol^-1, before decreasing at high loading. This increase is attributed to attractive adsorbate–adsorbate intermolecular interactions as evidenced by the slope and magnitude of the increase in isosteric heat and the adsorbed-phase heat capacities. An analysis of carbon dioxide adsorption on ZTC indicates a high degree of binding-site homogeneity. A generalized Law of Corresponding States analysis indicates lower carbon dioxide adsorption than expected.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001057

OSTI ID:: 1470611

Journal Information:: AIChE Journal, Journal Name: AIChE Journal Journal Issue: 3 Vol. 64; ISSN 0001-1541

Publisher:: American Institute of Chemical EngineersCopyright Statement

Country of Publication:: United States

Language:: English

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A thermodynamic investigation of adsorbate-adsorbate interactions of carbon dioxide on nanostructured carbons

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