Hydrogenation properties of lithium and sodium hydride – closo -borate, [B 10 H 10 ] 2− and [B 12 H 12 ] 2− , composites

Jensen, Steffen R. H.; Paskevicius, Mark; Hansen, Bjarne R. S.; Jakobsen, Anders S.; Møller, Kasper T.; White, James L.; Allendorf, Mark D.; Stavila, Vitalie; Skibsted, Jørgen; Jensen, Torben R.

doi:10.1039/C7CP07776A

Hydrogenation properties of lithium and sodium hydride – closo -borate, [B ₁₀ H ₁₀ ] ²⁻ and [B ₁₂ H ₁₂ ] ²⁻ , composites

Journal Article · Sun Dec 31 23:00:00 EST 2017 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/C7CP07776A· OSTI ID:1470579

Jensen, Steffen R. H. ^[1]; ^[1]; ^[1]; Jakobsen, Anders S. ^[1]; ^[1]; ^[2]; ^[2]; ^[2]; ^[3]; ^[1]

Center for Materials Crystallography, Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark
Chemistry, Combustion, and Materials Center, Sandia National Laboratories, Livermore, USA
Department of Chemistry and Interdisciplinary Nanoscience Center (iNANO), Aarhus University, 8000 Aarhus C, Denmark

The hydrogen absorption properties of metal closo -borate/metal hydride composites are studied under high hydrogen pressures.

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Sponsoring Organization:: USDOE

OSTI ID:: 1470579

Alternate ID(s):: OSTI ID: 1429663
OSTI ID: 1440264
OSTI ID: 1444088

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 23 Vol. 20; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (52)

Exceptional Superionic Conductivity in Disordered Sodium Decahydro- closo -decaborate Udovic, Terrence J.; Matsuo, Motoaki; Tang, Wan Si Advanced Materials, Vol. 26, Issue 45 https://doi.org/10.1002/adma.201403157	journal	October 2014
Al3Li4(BH4)13: A Complex Double-Cation Borohydride with a New Structure Lindemann, Inge; Domènech Ferrer, Roger; Dunsch, Lothar Chemistry - A European Journal, Vol. 16, Issue 29 https://doi.org/10.1002/chem.201000831	journal	June 2010
Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art Lai, Qiwen; Paskevicius, Mark; Sheppard, Drew A. ChemSusChem, Vol. 8, Issue 17 https://doi.org/10.1002/cssc.201500231	journal	June 2015
Boron-based hydrides for chemical hydrogen storage: Boron-based hydrolytic and thermolytic hydrides Moussa, Georges; Moury, Romain; Demirci, Umit B. International Journal of Energy Research, Vol. 37, Issue 8 https://doi.org/10.1002/er.3027	journal	March 2013
Metal boranes: Progress and applications Hansen, Bjarne R. S.; Paskevicius, Mark; Li, Hai-Wen Coordination Chemistry Reviews, Vol. 323 https://doi.org/10.1016/j.ccr.2015.12.003	journal	September 2016
Metal hydride materials for solid hydrogen storage: A review☆ Sakintuna, B.; Lamaridarkrim, F.; Hirscher, M. International Journal of Hydrogen Energy, Vol. 32, Issue 9 https://doi.org/10.1016/j.ijhydene.2006.11.022	journal	June 2007
Theoretical study of B12HnF(12−n)2− species Sharma, Manish; Sethio, Daniel; D'Anna, Vincenza International Journal of Hydrogen Energy, Vol. 40, Issue 37 https://doi.org/10.1016/j.ijhydene.2015.07.125	journal	October 2015
Intermediate phases observed during decomposition of LiBH4 Mosegaard, Lene; Møller, Bitten; Jørgensen, Jens-Erik Journal of Alloys and Compounds, Vol. 446-447 https://doi.org/10.1016/j.jallcom.2007.03.057	journal	October 2007
A review of catalyst-enhanced magnesium hydride as a hydrogen storage material Webb, C. J. Journal of Physics and Chemistry of Solids, Vol. 84 https://doi.org/10.1016/j.jpcs.2014.06.014	journal	September 2015
Probing the structure, stability and hydrogen storage properties of calcium dodecahydro-closo-dodecaborate Stavila, Vitalie; Her, Jae-Hyuk; Zhou, Wei Journal of Solid State Chemistry, Vol. 183, Issue 5 https://doi.org/10.1016/j.jssc.2010.03.026	journal	May 2010
Complex high-temperature phase transitions in Li2B12H12 and Na2B12H12 Verdal, Nina; Her, Jae-Hyuk; Stavila, Vitalie Journal of Solid State Chemistry, Vol. 212 https://doi.org/10.1016/j.jssc.2014.01.006	journal	April 2014
Complex hydrides for hydrogen storage – new perspectives Ley, Morten B.; Jepsen, Lars H.; Lee, Young-Su Materials Today, Vol. 17, Issue 3 https://doi.org/10.1016/j.mattod.2014.02.013	journal	April 2014
Boron–nitrogen based hydrides and reactive composites for hydrogen storage Jepsen, Lars H.; Ley, Morten B.; Lee, Young-Su Materials Today, Vol. 17, Issue 3 https://doi.org/10.1016/j.mattod.2014.02.015	journal	April 2014
Hydrogen - A sustainable energy carrier Møller, Kasper T.; Jensen, Torben R.; Akiba, Etsuo Progress in Natural Science: Materials International, Vol. 27, Issue 1 https://doi.org/10.1016/j.pnsc.2016.12.014	journal	February 2017
FT-IR spectra of inorganic borohydrides D’Anna, Vincenza; Spyratou, Alexandra; Sharma, Manish Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 128 https://doi.org/10.1016/j.saa.2014.02.130	journal	July 2014
Ammine-Stabilized Transition-Metal Borohydrides of Iron, Cobalt, and Chromium: Synthesis and Characterization Roedern, Elsa; Jensen, Torben R. Inorganic Chemistry, Vol. 54, Issue 21 https://doi.org/10.1021/acs.inorgchem.5b01959	journal	October 2015
Phase Diagram for the NaBH ₄ –KBH ₄ System and the Stability of a Na _{1– x} K _x BH ₄ Solid Solution Jensen, Steffen R. H.; Jepsen, Lars H.; Skibsted, Jørgen The Journal of Physical Chemistry C, Vol. 119, Issue 50 https://doi.org/10.1021/acs.jpcc.5b09851	journal	December 2015
Understanding and Mitigating the Effects of Stable Dodecahydro- closo -dodecaborate Intermediates on Hydrogen-Storage Reactions White, James L.; Newhouse, Rebecca J.; Zhang, Jin Z. The Journal of Physical Chemistry C, Vol. 120, Issue 45 https://doi.org/10.1021/acs.jpcc.6b09789	journal	November 2016
Role of Li ₂ B ₁₂ H ₁₂ for the Formation and Decomposition of LiBH ₄ Friedrichs, O.; Remhof, A.; Hwang, S. -J. Chemistry of Materials, Vol. 22, Issue 10 https://doi.org/10.1021/cm100536a	journal	May 2010
Trimetallic Borohydride Li ₃ MZn ₅ (BH ₄ ) ₁₅ (M = Mg, Mn) Containing Two Weakly Interconnected Frameworks Černý, Radovan; Schouwink, Pascal; Sadikin, Yolanda Inorganic Chemistry, Vol. 52, Issue 17 https://doi.org/10.1021/ic401139k	journal	August 2013
Chemistry of Boranes. VIII. Salts and Acids of B ₁₀ H ₁₀ ^-2 and B ₁₂ ₁₂ ^-2 Muetterties, E. L.; Balthis, J. H.; Chia, Y. T. Inorganic Chemistry, Vol. 3, Issue 3 https://doi.org/10.1021/ic50013a030	journal	March 1964
Chemistry of Boranes. III. ¹ The Infrared and Raman Spectra of B ₁₂ H ₁₂ - and Related Anions Muetterties, E. L.; Merrifield, R. E.; Miller, H. C. Journal of the American Chemical Society, Vol. 84, Issue 13 https://doi.org/10.1021/ja00872a011	journal	July 1962
Metallo Borohydrides. III. Lithium Borohydride Schlesinger, H. I.; Brown, Herbert C. Journal of the American Chemical Society, Vol. 62, Issue 12 https://doi.org/10.1021/ja01869a039	journal	December 1940
Thermal Stability of Li ₂ B ₁₂ H ₁₂ and its Role in the Decomposition of LiBH ₄ Pitt, Mark P.; Paskevicius, Mark; Brown, David H. Journal of the American Chemical Society, Vol. 135, Issue 18 https://doi.org/10.1021/ja400131b	journal	April 2013
First-Principles Prediction of Thermodynamically Reversible Hydrogen Storage Reactions in the Li-Mg-Ca-B-H System Ozolins, V.; Majzoub, E. H.; Wolverton, C. Journal of the American Chemical Society, Vol. 131, Issue 1 https://doi.org/10.1021/ja8066429	journal	January 2009
Thermodynamic Changes in Mechanochemically Synthesized Magnesium Hydride Nanoparticles Paskevicius, Mark; Sheppard, Drew A.; Buckley, Craig E. Journal of the American Chemical Society, Vol. 132, Issue 14 https://doi.org/10.1021/ja908398u	journal	April 2010
Reversible Storage of Hydrogen in Destabilized LiBH ₄ Vajo, John J.; Skeith, Sky L.; Mertens, Florian The Journal of Physical Chemistry B, Vol. 109, Issue 9 https://doi.org/10.1021/jp040769o	journal	March 2005
Bimetallic Borohydrides in the System M (BH ₄ ) ₂ –KBH ₄ ( M = Mg, Mn): On the Structural Diversity Schouwink, Pascal; D’Anna, Vincenza; Ley, Morten Brix The Journal of Physical Chemistry C, Vol. 116, Issue 20 https://doi.org/10.1021/jp212318s	journal	May 2012
Theoretical Prediction of Metastable Intermediates in the Decomposition of Mg(BH ₄ ) ₂ Zhang, Yongsheng; Majzoub, Eric; Ozoliņš, Vidvuds The Journal of Physical Chemistry C, Vol. 116, Issue 19 https://doi.org/10.1021/jp302303z	journal	May 2012
Stability and Decomposition of NaBH ₄ Martelli, Pascal; Caputo, Riccarda; Remhof, Arndt The Journal of Physical Chemistry C, Vol. 114, Issue 15 https://doi.org/10.1021/jp909341z	journal	March 2010
Structure and properties of complex hydride perovskite materials Schouwink, Pascal; Ley, Morten B.; Tissot, Antoine Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6706	journal	December 2014
First-principles calculated decomposition pathways for LiBH4 nanoclusters Huang, Zhi-Quan; Chen, Wei-Chih; Chuang, Feng-Chuan Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep26056	journal	May 2016
Direct hydrogenation of magnesium boride to magnesium borohydride: demonstration of >11 weight percent reversible hydrogenstorage Severa, Godwin; Rönnebro, Ewa; Jensen, Craig M. Chem. Commun., Vol. 46, Issue 3 https://doi.org/10.1039/B921205A	journal	January 2010
Reversible dehydrogenation of magnesium borohydride to magnesium triborane in the solid state under moderate conditions Chong, Marina; Karkamkar, Abhi; Autrey, Tom Chem. Commun., Vol. 47, Issue 4 https://doi.org/10.1039/C0CC03461D	journal	January 2011
The role of MgB ₁₂ H ₁₂ in the hydrogen desorption process of Mg(BH ₄ ) ₂ Yan, Yigang; Remhof, Arndt; Rentsch, Daniel Chemical Communications, Vol. 51, Issue 4 https://doi.org/10.1039/C4CC05266H	journal	January 2015
Hydrogen reversibility of LiBH ₄ –MgH ₂ –Al composites Hansen, Bjarne R. S.; Ravnsbæk, Dorthe B.; Skibsted, Jørgen Phys. Chem. Chem. Phys., Vol. 16, Issue 19 https://doi.org/10.1039/C4CP00651H	journal	January 2014
Novel solvates M(BH ₄ ) ₃ S(CH ₃ ) ₂ and properties of halide-free M(BH ₄ ) ₃ (M = Y or Gd) Ley, Morten B.; Paskevicius, Mark; Schouwink, Pascal Dalton Trans., Vol. 43, Issue 35 https://doi.org/10.1039/C4DT01125B	journal	January 2014
Crystal structure and in situ decomposition of Eu(BH ₄ ) ₂ and Sm(BH ₄ ) ₂ Humphries, Terry D.; Ley, Morten B.; Frommen, Christoph Journal of Materials Chemistry A, Vol. 3, Issue 2 https://doi.org/10.1039/C4TA04080E	journal	January 2015
Metal borohydrides and derivatives – synthesis, structure and properties Paskevicius, Mark; Jepsen, Lars H.; Schouwink, Pascal Chemical Society Reviews, Vol. 46, Issue 5 https://doi.org/10.1039/C6CS00705H	journal	January 2017
The versatile chemistry of the [B20H18]2– ions: novel reactions and structural motifs Hawthorne, M. Frederick; Shelly, Kenneth; Li, Fangbiao Chemical Communications, Issue 6 https://doi.org/10.1039/b110076a	journal	February 2002
In situ solid state 11B MAS-NMR studies of the thermal decomposition of ammonia borane: mechanistic studies of the hydrogen release pathways from a solid state hydrogen storage material Stowe, Ashley C.; Shaw, Wendy J.; Linehan, John C. Physical Chemistry Chemical Physics, Vol. 9, Issue 15 https://doi.org/10.1039/b617781f	journal	January 2007
Using first principles calculations to identify new destabilized metal hydride reactions for reversible hydrogen storage Alapati, Sudhakar V.; Karl Johnson, J.; Sholl, David S. Physical Chemistry Chemical Physics, Vol. 9, Issue 12 https://doi.org/10.1039/b617927d	journal	January 2007
The effect of Al on the hydrogen sorption mechanism of LiBH4 Friedrichs, O.; Kim, J. W.; Remhof, A. Physical Chemistry Chemical Physics, Vol. 11, Issue 10 https://doi.org/10.1039/b814282c	journal	January 2009
Large-scale screening of metal hydrides for hydrogen storage from first-principles calculations based on equilibrium reaction thermodynamics Kim, Ki Chul; Kulkarni, Anant D.; Johnson, J. Karl Physical Chemistry Chemical Physics, Vol. 13, Issue 15 https://doi.org/10.1039/c0cp02950e	journal	January 2011
Eutectic melting in metal borohydrides Paskevicius, Mark; Ley, Morten B.; Sheppard, Drew A. Physical Chemistry Chemical Physics, Vol. 15, Issue 45 https://doi.org/10.1039/c3cp53920b	journal	January 2013
In situ X-ray diffraction environments for high-pressure reactions Hansen, Bjarne R. S.; Møller, Kasper T.; Paskevicius, Mark Journal of Applied Crystallography, Vol. 48, Issue 4 https://doi.org/10.1107/S1600576715011735	journal	July 2015
The crystal chemistry of inorganic metal borohydrides and their relation to metal oxides Černý, Radovan; Schouwink, Pascal Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 71, Issue 6 https://doi.org/10.1107/S2052520615018508	journal	December 2015
A High-Resolution Solid-State ²³ Na NMR Study of Sodium Complexes with Solvents, Small Ligand Molecules, and Ionophores. ²³ Na Chemical Shifts as Means for Identification and Characterization of Ion–Ion, Ion–Solvent, and Ion–Ligand Interactions Tabeta, Ryoko; Aida, Misako; Saitô, Hazime Bulletin of the Chemical Society of Japan, Vol. 59, Issue 6 https://doi.org/10.1246/bcsj.59.1957	journal	June 1986
Amides and borohydrides for high-capacity solid-state hydrogen storage—materials design and kinetic improvements Wang, Jianhui; Li, Hai-Wen; Chen, Ping MRS Bulletin, Vol. 38, Issue 6 https://doi.org/10.1557/mrs.2013.131	journal	June 2013
Recent Progress in Metal Borohydrides for Hydrogen Storage Li, Hai-Wen; Yan, Yigang; Orimo, Shin-ichi Energies, Vol. 4, Issue 1 https://doi.org/10.3390/en4010185	journal	January 2011
Thermal Decomposition of Anhydrous Alkali Metal Dodecaborates M2B12H12 (M = Li, Na, K) He, Liqing; Li, Hai-Wen; Akiba, Etsuo Energies, Vol. 8, Issue 11 https://doi.org/10.3390/en81112326	journal	November 2015
Tetrahydroborates: Development and Potential as Hydrogen Storage Medium Puszkiel, Julián; Garroni, Sebastiano; Milanese, Chiara Inorganics, Vol. 5, Issue 4 https://doi.org/10.3390/inorganics5040074	journal	October 2017

Hydrogenation properties of lithium and sodium hydride – closo -borate, [B ₁₀ H ₁₀ ] ²⁻ and [B ₁₂ H ₁₂ ] ²⁻ , composites

References (52)

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Hydrogenation properties of lithium and sodium hydride – closo -borate, [B 10 H 10 ] 2− and [B 12 H 12 ] 2− , composites

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References (52)

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Hydrogenation properties of lithium and sodium hydride – closo -borate, [B ₁₀ H ₁₀ ] ²⁻ and [B ₁₂ H ₁₂ ] ²⁻ , composites