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Enabling multi-electron reaction of ε-VOPO4 to reach theoretical capacity for lithium-ion batteries

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/C8CC02386G· OSTI ID:1470488

Synthesizing highly crystalline nano-sized ε-VOPO4particles is the key to achieve theoretical capacity of 2 Li+ intercalation in lithium-ion batteries.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES); Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI ID:
1470488
Journal Information:
ChemComm, Journal Name: ChemComm Journal Issue: 56 Vol. 54; ISSN CHCOFS; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH

References (19)

Optimized LiVOPO4 for cathodes in Li-ion rechargeable batteries journal September 2005
Redox transformations of simple vanadium phosphates: the synthesis of ε-VOPO4 journal April 1996
The crystal structure of δ-VOPO4 and its relationship to ω-VOPO4 journal July 2009
Studies of lithium ion dynamics in paramagnetic cathode materials using 6Li 1D selective inversion methods journal April 2012
Revealing Defects in Crystalline Lithium-Ion Battery Electrodes by Solid-State NMR: Applications to LiVPO 4 F journal July 2015
Thermodynamics, Kinetics and Structural Evolution of ε-LiVOPO 4 over Multiple Lithium Intercalation journal February 2016
Design and Preparation of Materials for Advanced Electrochemical Storage journal June 2012
Phosphates as Lithium-Ion Battery Cathodes: An Evaluation Based on High-Throughput ab Initio Calculations journal August 2011
Chemical and Electrochemical Lithiation of LiVOPO 4 Cathodes for Lithium-Ion Batteries journal June 2014
Surface Effects on the Physical and Electrochemical Properties of Thin LiFePO 4 Particles journal January 2008
What Are Batteries, Fuel Cells, and Supercapacitors? journal October 2004
Lithium Batteries and Cathode Materials journal October 2004
Ultimate Limits to Intercalation Reactions for Lithium Batteries journal October 2014
Multiple phases in the ε-VPO 4 O–LiVPO 4 O–Li 2 VPO 4 O system: a combined solid state electrochemistry and diffraction structural study journal January 2014
Temperature-dependent crystallinity and morphology of LiFePO4 prepared by hydrothermal synthesis journal January 2012
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes journal June 2014
Highly Reversible Li Insertion at 4 V in ɛ-VOPO[sub 4]/α-LiVOPO[sub 4] Cathodes journal January 1999
ε-VOPO[sub 4]: Electrochemical Synthesis and Enhanced Cathode Behavior journal January 2005
Electrochemical Behavior of Nanostructured ɛ-VOPO4 over Two Redox Plateaus journal January 2013

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