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Title: Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media

Abstract

Herein we report on the adsorption and photocatalytic decomposition of organic molecules in aqueous environments containing two-dimensional Ti 3C 2T x, a representative of the MXene family.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Department of Materials Science & Engineering; A.J. Drexel Nanomaterials Institute; Drexel University; Philadelphia, USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1470195
DOE Contract Number:  
ERKCC61
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 2; Journal Issue: 35; Related Information: FIRST partners with Oak Ridge National Laboratory (lead); Argonne National Laboratory; Drexel University; Georgia State University; Northwestern University; Pennsylvania State University; Suffolk University; Vanderbilt University; University of Virginia; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (heterogeneous), solar (fuels), energy storage (including batteries and capacitors), hydrogen and fuel cells, electrodes - solar, mechanical behavior, charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Mashtalir, O., Cook, K. M., Mochalin, V. N., Crowe, M., Barsoum, M. W., and Gogotsi, Y. Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media. United States: N. p., 2014. Web. doi:10.1039/C4TA02638A.
Mashtalir, O., Cook, K. M., Mochalin, V. N., Crowe, M., Barsoum, M. W., & Gogotsi, Y. Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media. United States. doi:10.1039/C4TA02638A.
Mashtalir, O., Cook, K. M., Mochalin, V. N., Crowe, M., Barsoum, M. W., and Gogotsi, Y. Wed . "Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media". United States. doi:10.1039/C4TA02638A.
@article{osti_1470195,
title = {Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media},
author = {Mashtalir, O. and Cook, K. M. and Mochalin, V. N. and Crowe, M. and Barsoum, M. W. and Gogotsi, Y.},
abstractNote = {Herein we report on the adsorption and photocatalytic decomposition of organic molecules in aqueous environments containing two-dimensional Ti3C2Tx, a representative of the MXene family.},
doi = {10.1039/C4TA02638A},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 35,
volume = 2,
place = {United States},
year = {2014},
month = {1}
}

Works referenced in this record:

Removal of methylene blue from colored effluents by adsorption on montmorillonite clay
journal, April 2009

  • Almeida, C. A. P.; Debacher, N. A.; Downs, A. J.
  • Journal of Colloid and Interface Science, Vol. 332, Issue 1
  • DOI: 10.1016/j.jcis.2008.12.012

Adsorption of methylene blue on low-cost adsorbents: A review
journal, May 2010


Graphene-Based Ultracapacitors
journal, October 2008

  • Stoller, Meryl D.; Park, Sungjin; Zhu, Yanwu
  • Nano Letters, Vol. 8, Issue 10
  • DOI: 10.1021/nl802558y

The Importance of Bulk Ti 3+ Defects in the Oxygen Chemistry on Titania Surfaces
journal, May 2011

  • Lira, Estephania; Wendt, Stefan; Huo, Peipei
  • Journal of the American Chemical Society, Vol. 133, Issue 17
  • DOI: 10.1021/ja200884w

Kinetics of Methylene Blue Reduction by Ascorbic Acid
journal, July 1999

  • Mowry, Sarah; Ogren, Paul J.
  • Journal of Chemical Education, Vol. 76, Issue 7
  • DOI: 10.1021/ed076p970

Inorganic materials for photocatalytic water disinfection
journal, January 2010

  • Zhang, Dieqing; Li, Guisheng; Yu, Jimmy C.
  • Journal of Materials Chemistry, Vol. 20, Issue 22
  • DOI: 10.1039/b925342d

Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
journal, August 2011

  • Naguib, Michael; Kurtoglu, Murat; Presser, Volker
  • Advanced Materials, Vol. 23, Issue 37, p. 4248-4253
  • DOI: 10.1002/adma.201102306

Controlling Graphene Properties Through Chemistry
journal, September 2011

  • Gogotsi, Yury
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 19
  • DOI: 10.1021/jz201145a

Photocatalytic degradation pathway of methylene blue in water
journal, May 2001


Intercalation and delamination of layered carbides and carbonitrides
journal, April 2013

  • Mashtalir, Olha; Naguib, Michael; Mochalin, Vadym N.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2664

Adsorption of dyes from aqueous solutions or suspensions with clay nano-adsorbents
journal, December 2007


Oxygen adsorption and dissociation during the oxidation of monolayer Ti2C
journal, January 2013

  • Gan, Li-Yong; Huang, Dan; Schwingenschlögl, Udo
  • Journal of Materials Chemistry A, Vol. 1, Issue 43
  • DOI: 10.1039/c3ta12032e

A Non-Aqueous Asymmetric Cell with a Ti 2 C-Based Two-Dimensional Negative Electrode
journal, January 2012

  • Come, J.; Naguib, M.; Rozier, P.
  • Journal of The Electrochemical Society, Vol. 159, Issue 8
  • DOI: 10.1149/2.003208jes

Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide
journal, September 2013


25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials
journal, December 2013

  • Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W.
  • Advanced Materials, Vol. 26, Issue 7, p. 992-1005
  • DOI: 10.1002/adma.201304138

Two-Dimensional Transition Metal Carbides
journal, January 2012

  • Naguib, Michael; Mashtalir, Olha; Carle, Joshua
  • ACS Nano, Vol. 6, Issue 2
  • DOI: 10.1021/nn204153h

Assembly of chemically modified graphene: methods and applications
journal, January 2011


Delaminated titanate and peroxotitanate photocatalysts
journal, June 2011

  • Stewart, Tom A.; Nyman, May; deBoer, Maarten P.
  • Applied Catalysis B: Environmental, Vol. 105, Issue 1-2, p. 69-76
  • DOI: 10.1016/j.apcatb.2011.03.036

Atomic structure, comparative stability and electronic properties of hydroxylated Ti2C and Ti3C2 nanotubes
journal, June 2012


Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films
journal, March 2014

  • Halim, Joseph; Lukatskaya, Maria R.; Cook, Kevin M.
  • Chemistry of Materials, Vol. 26, Issue 7
  • DOI: 10.1021/cm500641a

Heavy oil sorption using exfoliated graphite
journal, January 2000


New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries
journal, October 2013

  • Naguib, Michael; Halim, Joseph; Lu, Jun
  • Journal of the American Chemical Society, Vol. 135, Issue 43
  • DOI: 10.1021/ja405735d

Crystal-chemistry of the Ti3AlC2 and Ti4AlN3 layered carbide/nitride phases—characterization by XPS
journal, April 2001


TiO2 photocatalysis: Design and applications
journal, September 2012


Unique Lead Adsorption Behavior of Activated Hydroxyl Group in Two-Dimensional Titanium Carbide
journal, March 2014

  • Peng, Qiuming; Guo, Jianxin; Zhang, Qingrui
  • Journal of the American Chemical Society, Vol. 136, Issue 11
  • DOI: 10.1021/ja500506k

Anisotropic Etching of SiC Whiskers
journal, March 2006

  • Cambaz, Goknur Z.; Yushin, Gleb N.; Gogotsi, Yury
  • Nano Letters, Vol. 6, Issue 3
  • DOI: 10.1021/nl051858v

Dye Adsorption on Layered Graphite Oxide
journal, January 2011

  • Bradder, Philip; Ling, Sie King; Wang, Shaobin
  • Journal of Chemical & Engineering Data, Vol. 56, Issue 1
  • DOI: 10.1021/je101049g

Deposition and characterization of ternary thin films within the Ti–Al–C system by DC magnetron sputtering
journal, May 2006


Pore- and Solid-Diffusion Kinetics in Fixed-Bed Adsorption under Constant-Pattern Conditions
journal, May 1966

  • Hall, K. R.; Eagleton, L. C.; Acrivos, Andreas
  • Industrial & Engineering Chemistry Fundamentals, Vol. 5, Issue 2
  • DOI: 10.1021/i160018a011

Using graphite intercalation compounds for producing exfoliated graphite–amorphous carbon–TiO2 composites
journal, May 2006

  • Savoskin, M. V.; Yaroshenko, A. P.; Lazareva, N. I.
  • Journal of Physics and Chemistry of Solids, Vol. 67, Issue 5-6
  • DOI: 10.1016/j.jpcs.2006.01.049

Novel Electronic and Magnetic Properties of Two-Dimensional Transition Metal Carbides and Nitrides
journal, December 2012

  • Khazaei, Mohammad; Arai, Masao; Sasaki, Taizo
  • Advanced Functional Materials, Vol. 23, Issue 17
  • DOI: 10.1002/adfm.201202502

MXene: a promising transition metal carbide anode for lithium-ion batteries
journal, March 2012

  • Naguib, Michael; Come, Jérémy; Dyatkin, Boris
  • Electrochemistry Communications, Vol. 16, Issue 1, p. 61-64
  • DOI: 10.1016/j.elecom.2012.01.002

Kinetics of aluminum extraction from Ti3AlC2 in hydrofluoric acid
journal, April 2013


Adsorption of methylene blue on kaolinite
journal, February 2002


Layered niobate nanosheets: building blocks for advanced materials assembly
journal, January 2009

  • Bizeto, Marcos A.; Shiguihara, Ana L.; Constantino, Vera R. L.
  • Journal of Materials Chemistry, Vol. 19, Issue 17
  • DOI: 10.1039/b821435b