An Interdisciplinary View of Interfaces: Perspectives Regarding Emergent Phase Formation

Brinkman, Kyle S.

doi:10.1115/1.4037583

An Interdisciplinary View of Interfaces: Perspectives Regarding Emergent Phase Formation

Journal Article · Wed Oct 04 00:00:00 EDT 2017 · Journal of Electrochemical Energy Conversion and Storage

DOI:https://doi.org/10.1115/1.4037583· OSTI ID:1470190

Brinkman, Kyle S. ^[1]

Department of Materials Science and Engineering, Clemson University, Clemson, SC 29634 e-mail:

A perspective on emergent phase formation is presented using an interdisciplinary approach gained by working at the “interface” between diverse application areas, including solid oxide fuel cells (SOFCs) and ionic membrane systems, solid state lithium batteries, and ceramics for nuclear waste immobilization. The grain boundary interfacial characteristics of model single-phase materials in these application areas, including (i) CeO2, (ii) Li7La3Zr2O12 (LLZO), and (iii) hollandite of the form BaxCsyGa2x+yTi8-2x-yO16, as well as the potential for emergent phase formation in composite systems, are discussed. The potential physical properties resulting from emergent phase structure and distribution are discussed, including an overview of existing three-dimensional (3D) imaging techniques recently used for characterization. Finally, an approach for thermodynamic characterization of emergent phases based on melt solution calorimetry is outlined, which may be used to predict the energy landscape including phase formation and stability of complex multiphase systems.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Hierarchical Waste Form Materials (CHWM)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: SC0016574

OSTI ID:: 1470190

Journal Information:: Journal of Electrochemical Energy Conversion and Storage, Journal Name: Journal of Electrochemical Energy Conversion and Storage Journal Issue: 1 Vol. 15; ISSN 2381-6872

Publisher:: ASME

Country of Publication:: United States

Language:: English

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