Mechanism of iodine release from iodoapatite in aqueous solution

Zhang, Z.; Heath, A.; Valsaraj, K. T.; Ebert, W.  L.; Yao, T.; Lian, J.; Wang, J.

doi:10.1039/C7RA11049A

Mechanism of iodine release from iodoapatite in aqueous solution

Journal Article · Mon Jan 01 04:00:00 EST 2018 · RSC Advances

DOI:https://doi.org/10.1039/C7RA11049A· OSTI ID:1470160

^[1]; Heath, A. ^[2]; Valsaraj, K. T. ^[2]; Ebert, W. L. ^[3]; Yao, T. ^[4]; ^[4]; ^[1]

Department of Geology and Geophysics; Louisiana State University; Baton Rouge; USA
Department of Chemical Engineering; Louisiana State University; Baton Rouge; USA
Nuclear Engineering; Argonne National Lab; Lemont; USA
Department of Mechanical and Nuclear Engineering; Rensselaer Polytechnic Institute; Troy; USA

Incongruent release of iodine from iodoapatite (Pb₅(VO₄)₃I) for immobilization of¹²⁹iodine, controlled by exchange of iodide and hydroxide in solution.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States), Washington, DC (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD).

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

DOE Contract Number:: SC0016584

OSTI ID:: 1470160

Journal Information:: RSC Advances, Journal Name: RSC Advances Journal Issue: 8 Vol. 8; ISSN 2046-2069; ISSN RSCACL

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (28)

Incorporation of iodates into hydroxyapatites: a new approach for the confinement of radioactive iodine Campayo, Lionel; Grandjean, Agnès; Coulon, Antoine Journal of Materials Chemistry, Vol. 21, Issue 44 https://doi.org/10.1039/c1jm14157k	journal	January 2011
Ion exchange equilibria in zeolite minerals Colella, C. Mineralium Deposita, Vol. 31, Issue 6 https://doi.org/10.1007/BF00196136	journal	September 1996
Anion-Exchange Properties of Hydrotalcite-Like Compounds Miyata, Shigeo Clays and Clay Minerals, Vol. 31, Issue 4 https://doi.org/10.1346/CCMN.1983.0310409	journal	January 1983
Some properties of a lead vanado-iodoapatite Pb10(VO4)6I2 Uno, Masayoshi; Shinohara, Makoto; Kurosaki, Ken Journal of Nuclear Materials, Vol. 294, Issue 1-2 https://doi.org/10.1016/S0022-3115(01)00462-7	journal	April 2001
Impact of leach on lead vanado-iodoapatite [Pb5(VO4)3I]: An infrared and Raman spectroscopic study Zhang, Ming; Maddrell, E. R.; Abraitis, P. K. Materials Science and Engineering: B, Vol. 137, Issue 1-3 https://doi.org/10.1016/j.mseb.2006.11.003	journal	February 2007
Kinetics and mechanism of natural fluorapatite dissolution at 25°C and pH from 3 to 12 Chaïrat, Claire; Schott, Jacques; Oelkers, Eric H. Geochimica et Cosmochimica Acta, Vol. 71, Issue 24 https://doi.org/10.1016/j.gca.2007.08.031	journal	December 2007
Synthesis of lead vanadate iodoapatite utilizing dry mechanochemical process Suetsugu, Yasushi Journal of Nuclear Materials, Vol. 454, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2014.07.073	journal	November 2014
Materials and processes for the effective capture and immobilization of radioiodine: A review Riley, Brian J.; Vienna, John D.; Strachan, Denis M. Journal of Nuclear Materials, Vol. 470 https://doi.org/10.1016/j.jnucmat.2015.11.038	journal	March 2016
An evaluation of cement-based waste forms using the results of approximately two years of dynamic leaching Côtê, Pierre L.; Constable, Thomas W.; Moreira, Alan Nuclear and Chemical Waste Management, Vol. 7, Issue 2 https://doi.org/10.1016/0191-815X(87)90007-6	journal	January 1987
Iodine valence and local environments in borosilicate waste glasses using X-ray absorption spectroscopy McKeown, David A.; Muller, Isabelle S.; Pegg, Ian L. Journal of Nuclear Materials, Vol. 456 https://doi.org/10.1016/j.jnucmat.2014.09.033	journal	January 2015
Materials Science of High-Level Nuclear Waste Immobilization Weber, William J.; Navrotsky, Alexandra; Stefanovsky, Sergey MRS Bulletin, Vol. 34, Issue 1 https://doi.org/10.1557/mrs2009.12	journal	January 2009
Nuclear Waste Vitrification in the United States: Recent Developments and Future Options: Nuclear Waste Vitrification in the United States. Vienna, John D. International Journal of Applied Glass Science, Vol. 1, Issue 3 https://doi.org/10.1111/j.2041-1294.2010.00023.x	journal	September 2010
New conditionings for separated long-lived radionuclides Guy, Christophe; Audubert, Fabienne; Lartigue, Jean-Eric Comptes Rendus Physique, Vol. 3, Issue 7-8 https://doi.org/10.1016/S1631-0705(02)01377-4	journal	September 2002
Iodine solubility in a low-activity waste borosilicate glass at 1000°C Riley, Brian J.; Schweiger, Michael J.; Kim, Dong-Sang Journal of Nuclear Materials, Vol. 452, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2014.04.027	journal	September 2014
The dissolution of apatite in the presence of aqueous metal cations at pH 2–7 Valsami-Jones, E.; Ragnarsdottir, K. V.; Putnis, A. Chemical Geology, Vol. 151, Issue 1-4 https://doi.org/10.1016/S0009-2541(98)00081-3	journal	October 1998
French Studies on the Development of Potential Conditioning Matrices for Iodine 129 Campayo, Lionel; Audubert, Fabienne; Lartigue, Jean-Eric MRS Proceedings, Vol. 1744 https://doi.org/10.1557/opl.2015.309	journal	January 2015
Tailoring the radiation tolerance of vanadate–phosphate fluorapatites by chemical composition control Lu, Fengyuan; Dong, Zhili; Zhang, Jiaming RSC Advances, Vol. 3, Issue 35 https://doi.org/10.1039/c3ra42246a	journal	January 2013
Experimental study of igneous and sedimentary apatite dissolution Guidry, Michael W.; Mackenzie, Fred T. Geochimica et Cosmochimica Acta, Vol. 67, Issue 16 https://doi.org/10.1016/S0016-7037(03)00265-5	journal	August 2003
Rapid synthesis of Pb5(VO4)3I, for the immobilisation of iodine radioisotopes, by microwave dielectric heating Stennett, M. C.; Pinnock, I. J.; Hyatt, N. C. Journal of Nuclear Materials, Vol. 414, Issue 3 https://doi.org/10.1016/j.jnucmat.2011.04.041	journal	July 2011
Elaboration of an iodine-bearing apatite Iodine diffusion into a Pb3(VO4)2 matrix Audubert, F. Solid State Ionics, Vol. 95, Issue 1-2 https://doi.org/10.1016/S0167-2738(96)00570-X	journal	February 1997
Durability testing of an iodate-substituted hydroxyapatite designed for the conditioning of 129 I Coulon, Antoine; Grandjean, Agnes; Laurencin, Danielle Journal of Nuclear Materials, Vol. 484 https://doi.org/10.1016/j.jnucmat.2016.10.047	journal	February 2017
Wet chemical synthesis of apatite-based waste forms – A novel room temperature method for the immobilization of radioactive iodine Cao, Charles; Chong, Saehwa; Thirion, Lynn Journal of Materials Chemistry A, Vol. 5, Issue 27 https://doi.org/10.1039/C7TA00230K	journal	January 2017
Bulk Iodoapatite Ceramic Densified by Spark Plasma Sintering with Exceptional Thermal Stability Yao, Tiankai; Lu, Fengyuan; Sun, Hongtao Journal of the American Ceramic Society, Vol. 97, Issue 8 https://doi.org/10.1111/jace.13101	journal	July 2014
Metal ion exchange by natural and modified zeolites Ćurković, L.; Cerjan-Stefanović, Š.; Filipan, T. Water Research, Vol. 31, Issue 6 https://doi.org/10.1016/S0043-1354(96)00411-3	journal	June 1997
MCC-1: A Standard Leach Test for Nuclear Waste Forms Strachan, D. M.; Turcotte, R. P.; Barnes, B. O. Nuclear Technology, Vol. 56, Issue 2 https://doi.org/10.13182/NT82-A32859	journal	February 1982
The dissolution kinetics and apparent solubility of natural apatite in closed reactors at temperatures from 5 to 50 °C and pH from 1 to 6 Harouiya, Najatte; Chaïrat, Claire; Köhler, Stephan J. Chemical Geology, Vol. 244, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2007.07.011	journal	October 2007
Spark plasma sintering of iodine-bearing apatite Le Gallet, S.; Campayo, L.; Courtois, E. Journal of Nuclear Materials, Vol. 400, Issue 3 https://doi.org/10.1016/j.jnucmat.2010.03.011	journal	May 2010
High-temperature breakdown of the synthetic iodine analogue of vanadinite, Pb ₅ (VO ₄ ) ₃ I: an apatite-related compound for iodine radioisotope immobilization? Redfern, S. A. T.; Smith, S. E.; Maddrell, E. R. Mineralogical Magazine, Vol. 76, Issue 4 https://doi.org/10.1180/minmag.2012.076.4.15	journal	August 2012

Similar Records

Mechanism of iodine release from iodoapatite in aqueous solution

Journal Article · Sun Dec 31 19:00:00 EST 2017 · RSC Advances · OSTI ID:1417677

Effect of solution chemistry on the iodine release from iodoapatite in aqueous environments

Journal Article · Fri Jul 26 20:00:00 EDT 2019 · Journal of Nuclear Materials · OSTI ID:1600976

Mechanism of iodine release from iodoapatite in aqueous solution

Citation Formats

References (28)

Similar Records

Related Subjects