skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis, structural analysis, and supramolecular assembly of a series of in situ generated uranyl–peroxide complexes with functionalized 2,2'-bipyridine and varied carboxylic acid ligands

Abstract

Presented herein are eight new binuclear uranyl complexes bridged byin situgenerated peroxide ligands and assembledvianoncovalent interactions.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry; The George Washington University; Washington; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1470046
DOE Contract Number:  
SC0001089
Resource Type:
Journal Article
Journal Name:
New Journal of Chemistry
Additional Journal Information:
Journal Volume: 42; Journal Issue: 3; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; Journal ID: ISSN 1144-0546
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)

Citation Formats

Ridenour, J. August, and Cahill, Christopher L. Synthesis, structural analysis, and supramolecular assembly of a series of in situ generated uranyl–peroxide complexes with functionalized 2,2'-bipyridine and varied carboxylic acid ligands. United States: N. p., 2018. Web. doi:10.1039/C7NJ03828C.
Ridenour, J. August, & Cahill, Christopher L. Synthesis, structural analysis, and supramolecular assembly of a series of in situ generated uranyl–peroxide complexes with functionalized 2,2'-bipyridine and varied carboxylic acid ligands. United States. doi:10.1039/C7NJ03828C.
Ridenour, J. August, and Cahill, Christopher L. Mon . "Synthesis, structural analysis, and supramolecular assembly of a series of in situ generated uranyl–peroxide complexes with functionalized 2,2'-bipyridine and varied carboxylic acid ligands". United States. doi:10.1039/C7NJ03828C.
@article{osti_1470046,
title = {Synthesis, structural analysis, and supramolecular assembly of a series of in situ generated uranyl–peroxide complexes with functionalized 2,2'-bipyridine and varied carboxylic acid ligands},
author = {Ridenour, J. August and Cahill, Christopher L.},
abstractNote = {Presented herein are eight new binuclear uranyl complexes bridged byin situgenerated peroxide ligands and assembledvianoncovalent interactions.},
doi = {10.1039/C7NJ03828C},
journal = {New Journal of Chemistry},
issn = {1144-0546},
number = 3,
volume = 42,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

The Halogen Bond
journal, January 2016


Uranyl−Peroxide Interactions Favor Nanocluster Self-Assembly
journal, November 2009

  • Sigmon, Ginger E.; Ling, Jie; Unruh, Daniel K.
  • Journal of the American Chemical Society, Vol. 131, Issue 46
  • DOI: 10.1021/ja907837u

Mesoporous Silica-Supported Uranyl:  Synthesis and Photoreactivity
journal, August 2005

  • Nieweg, Jennifer A.; Lemma, Kelemu; Trewyn, Brian G.
  • Inorganic Chemistry, Vol. 44, Issue 16
  • DOI: 10.1021/ic050130e

Hierarchy of Pyrophosphate-Functionalized Uranyl Peroxide Nanocluster Synthesis
journal, April 2017


Halogen Bonding in Supramolecular Chemistry
journal, July 2015

  • Gilday, Lydia C.; Robinson, Sean W.; Barendt, Timothy A.
  • Chemical Reviews, Vol. 115, Issue 15
  • DOI: 10.1021/cr500674c

WinGX and ORTEP for Windows : an update
journal, July 2012


Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

  • Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M.
  • Journal of Applied Crystallography, Vol. 48, Issue 1
  • DOI: 10.1107/S1600576714022985

Nuclear Fuel in a Reactor Accident
journal, March 2012

  • Burns, Peter C.; Ewing, Rodney C.; Navrotsky, Alexandra
  • Science, Vol. 335, Issue 6073
  • DOI: 10.1126/science.1211285

A critical account on π–π stacking in metal complexes with aromatic nitrogen-containing ligands †
journal, January 2000

  • Janiak, Christoph
  • Journal of the Chemical Society, Dalton Transactions, Issue 21
  • DOI: 10.1039/b003010o

Expanding the Crystal Chemistry of Uranyl Peroxides: Four Hybrid Uranyl-Peroxide Structures Containing EDTA
journal, October 2014

  • Qiu, Jie; Ling, Jie; Sieradzki, Claire
  • Inorganic Chemistry, Vol. 53, Issue 22
  • DOI: 10.1021/ic5018906

Crystal Structures of Molecular Adducts between Uranyl Nitrate and 2,2  : 6 ,2  -Terpyridine or 2,2′-Bipyridyl
journal, July 2004


Evaluation of true energy of halogen bonding in the crystals of halogen derivatives of trityl alcohol
journal, June 2008


Uranyl-Promoted Peroxide Generation: Synthesis and Characterization of Three Uranyl Peroxo [(UO 2 ) 2 (O 2 )] Complexes
journal, April 2015

  • Thangavelu, Sonia G.; Cahill, Christopher L.
  • Inorganic Chemistry, Vol. 54, Issue 9
  • DOI: 10.1021/ic502767k

van der Waals Volumes and Radii
journal, March 1964

  • Bondi, A.
  • The Journal of Physical Chemistry, Vol. 68, Issue 3, p. 441-451
  • DOI: 10.1021/j100785a001

Studtite, [(UO 2 )(O 2 )(H 2 O) 2 ](H 2 O) 2 : The first structure of a peroxide mineral
journal, July 2003

  • Burns, Peter C.; Hughes, Karrie-Ann
  • American Mineralogist, Vol. 88, Issue 7
  • DOI: 10.2138/am-2003-0725

Halogen Bonds in Crystal Engineering: Like Hydrogen Bonds yet Different
journal, May 2014

  • Mukherjee, Arijit; Tothadi, Srinu; Desiraju, Gautam R.
  • Accounts of Chemical Research, Vol. 47, Issue 8
  • DOI: 10.1021/ar5001555

Experimental and Computational Study of a New Wheel-Shaped {[W 5 O 21 ] 3 [(U VI O 2 ) 2 (μ-O 2 )] 3 } 30– Polyoxometalate
journal, August 2012

  • Miró, Pere; Ling, Jie; Qiu, Jie
  • Inorganic Chemistry, Vol. 51, Issue 16
  • DOI: 10.1021/ic3005536

Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges
journal, October 2012

  • Qiu, Jie; Burns, Peter C.
  • Chemical Reviews, Vol. 113, Issue 2
  • DOI: 10.1021/cr300159x

On the Origin of the Cation Templated Self-Assembly of Uranyl-Peroxide Nanoclusters
journal, December 2010

  • Miró, Pere; Pierrefixe, Simon; Gicquel, Mickaël
  • Journal of the American Chemical Society, Vol. 132, Issue 50
  • DOI: 10.1021/ja1053175

Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres
journal, January 2016

  • Thuéry, Pierre; Harrowfield, Jack
  • CrystEngComm, Vol. 18, Issue 21
  • DOI: 10.1039/C6CE00603E

Stability of Peroxide-Containing Uranyl Minerals
journal, November 2003


Energetics of metastudtite and implications for nuclear waste alteration
journal, November 2014

  • Guo, Xiaofeng; Ushakov, Sergey V.; Labs, Sabrina
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 50
  • DOI: 10.1073/pnas.1421144111

U6+ Minerals and Inorganic Compounds: Insights into an Expanded Structural Hierarchy of Crystal Structures
journal, December 2005


A Uranyl Peroxide Dimer in the Gas Phase
journal, March 2017


Definition of the halogen bond (IUPAC Recommendations 2013)
journal, July 2013

  • Desiraju, Gautam R.; Ho, P. Shing; Kloo, Lars
  • Pure and Applied Chemistry, Vol. 85, Issue 8
  • DOI: 10.1351/PAC-REC-12-05-10

Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures
journal, August 2012

  • Andrews, Michael B.; Cahill, Christopher L.
  • Chemical Reviews, Vol. 113, Issue 2
  • DOI: 10.1021/cr300202a

Cation Templating and Electronic Structure Effects in Uranyl Cage Clusters Probed by the Isolation of Peroxide-Bridged Uranyl Dimers
journal, April 2015


Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds
journal, July 2011

  • Wang, Kai-Xue; Chen, Jie-Sheng
  • Accounts of Chemical Research, Vol. 44, Issue 7
  • DOI: 10.1021/ar200042t

Expanding the Crystal Chemistry of Uranyl Peroxides:  Synthesis and Structures of Di- and Triperoxodioxouranium(VI) Complexes
journal, April 2007

  • Kubatko, Karrie-Ann; Forbes, Tori Z.; Klingensmith, Amanda L.
  • Inorganic Chemistry, Vol. 46, Issue 9
  • DOI: 10.1021/ic070118h

Engaging the Terminal: Promoting Halogen Bonding Interactions with Uranyl Oxo Atoms
journal, August 2017

  • Carter, Korey P.; Kalaj, Mark; Surbella, Robert G.
  • Chemistry - A European Journal, Vol. 23, Issue 61
  • DOI: 10.1002/chem.201702744

Gas-Phase Uranyl, Neptunyl, and Plutonyl: Hydration and Oxidation Studied by Experiment and Theory
journal, June 2012

  • Rios, Daniel; Michelini, Maria C.; Lucena, Ana F.
  • Inorganic Chemistry, Vol. 51, Issue 12
  • DOI: 10.1021/ic3001625

Combining coordination and supramolecular chemistry for the formation of uranyl-organic hybrid materials
journal, January 2011

  • Deifel, Nicholas P.; Cahill, Christopher L.
  • Chemical Communications, Vol. 47, Issue 21
  • DOI: 10.1039/c1cc11116g

Crystal structure refinement with SHELXL
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053229614024218

Lone pair–π interactions: a new supramolecular bond?
journal, January 2008

  • Mooibroek, Tiddo J.; Gamez, Patrick; Reedijk, Jan
  • CrystEngComm, Vol. 10, Issue 11
  • DOI: 10.1039/b812026a

Uranyl peroxide enhanced nuclear fuel corrosion in seawater
journal, January 2012

  • Armstrong, C. R.; Nyman, M.; Shvareva, T.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 6
  • DOI: 10.1073/pnas.1119758109

Precipitation Characteristics of Uranyl Ions at Different pHs Depending on the Presence of Carbonate Ions and Hydrogen Peroxide
journal, April 2009

  • Kim, Kwang-Wook; Kim, Yeon-Hwa; Lee, Se-Yoon
  • Environmental Science & Technology, Vol. 43, Issue 7
  • DOI: 10.1021/es802951b

Aromatic-aromatic interactions: free energy profiles for the benzene dimer in water, chloroform, and liquid benzene
journal, June 1990

  • Jorgensen, William L.; Severance, Daniel L.
  • Journal of the American Chemical Society, Vol. 112, Issue 12
  • DOI: 10.1021/ja00168a022

Single-crystal structure validation with the program PLATON
journal, January 2003


Synthesis, crystal structure, and absorption spectra of 2,2′-bipyridine complexes of benzoates of hexavalent U, Np, and Pu
journal, July 2012


Understanding the Structure and Formation of Uranyl Peroxide Nanoclusters by Quantum Chemical Calculations
journal, October 2010

  • Vlaisavljevich, Bess; Gagliardi, Laura; Burns, Peter C.
  • Journal of the American Chemical Society, Vol. 132, Issue 41
  • DOI: 10.1021/ja104964x

Harnessing uranyl oxo atoms via halogen bonding interactions in molecular uranyl materials featuring 2,5-diiodobenzoic acid and N-donor capping ligands
journal, January 2017

  • Carter, Korey P.; Kalaj, Mark; Cahill, Christopher L.
  • Inorganic Chemistry Frontiers, Vol. 4, Issue 1
  • DOI: 10.1039/C6QI00352D

A metal-organic molecular box obtained from self-assembling around uranyl ions
journal, January 1999

  • Thuéry, Pierre; Nierlich, Martine; Baldwin, Bruce W.
  • Journal of the Chemical Society, Dalton Transactions, Issue 7
  • DOI: 10.1039/a900845d

Combining coordination and supramolecular chemistry to explore uranyl assembly in the solid state
journal, January 2015

  • Carter, Korey P.; Cahill, Christopher L.
  • Inorganic Chemistry Frontiers, Vol. 2, Issue 2
  • DOI: 10.1039/C4QI00183D

A series of Ln-p-chlorobenzoic acid–terpyridine complexes: lanthanide contraction effects, supramolecular interactions and luminescent behavior
journal, January 2014

  • Carter, Korey P.; Pope, Simon J. A.; Cahill, Christopher L.
  • CrystEngComm, Vol. 16, Issue 10
  • DOI: 10.1039/c3ce42267d

The Propensity of Uranium-Peroxide Systems to Preserve Nanosized Assemblies
journal, July 2017


Uranyl Peroxide Oxalate Cage and Core–Shell Clusters Containing 50 and 120 Uranyl Ions
journal, January 2012

  • Ling, Jie; Qiu, Jie; Burns, Peter C.
  • Inorganic Chemistry, Vol. 51, Issue 4
  • DOI: 10.1021/ic202380g

Oxidative leaching of uranium from SIMFUEL using Na2CO3–H2O2 solution
journal, January 2010

  • Chung, Dong-Yong; Seo, Heui-Seung; Lee, Jae-Won
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 284, Issue 1
  • DOI: 10.1007/s10967-009-0443-6