Aqueous and Template-Free Synthesis of Meso-Macroporous Polymers for Highly Selective Capture and Conversion of Carbon Dioxide

Huang, Kuan; Liu, Fujian; Jiang, Lilong; Dai, Sheng

doi:10.1002/cssc.201701666

Aqueous and Template-Free Synthesis of Meso-Macroporous Polymers for Highly Selective Capture and Conversion of Carbon Dioxide

Journal Article · Fri Sep 01 00:00:00 EDT 2017 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201701666· OSTI ID:1469891

Huang, Kuan ^[1]; ^[2]; Jiang, Lilong ^[2]; Dai, Sheng ^[3]

Nanchang Univ. (China)
Fuzhou Univ. (China)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Meso–macroporous polymers possessing nitrogen functionality were innovatively synthesized through an aqueous and template-free route herein. In particular, the polymerization of 1-(4-vinylbenzyl)-1,3,5,7-tetraazaadamantan-1-ium chloride in aqueous solution under high temperatures induces the decomposition of the hexamethylenetetramine unit into ammonia and formaldehyde molecules, followed by the cross-linking of benzene rings through “resol chemistry”. During this process, extended meso–macroporous frameworks were constructed, and active nitrogen species were incorporated. Taking the advantage of the meso–macroporosity and nitrogen functionality, the synthesized polymers offer competitive CO₂ capacities (0.37–1.58 mmol g^–1 at 0 °C and 0.15 bar) and outstanding CO₂/N₂ selectivities (155–324 at 0 °C). Moreover, after complexed with metal ions, the synthesized polymers show excellent activity for catalyzing the cycloaddition of propylene oxide with CO2 (yield>98.5 %, turnover frequency: 612.9–761.1 h^–1).

View Accepted Manuscript (DOE)

Research Organization:: Georgia Inst. of Technology, Atlanta, GA (United States). Energy Frontier Research Center (EFRC) Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)

Sponsoring Organization:: National Natural Science Foundation of China (NNSFC); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012577

OSTI ID:: 1469891

Alternate ID(s):: OSTI ID: 1399273

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 21 Vol. 10; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Aqueous and Template-Free Synthesis of Meso-Macroporous Polymers for Highly Selective Capture and Conversion of Carbon Dioxide

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