skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion

Journal Article · · Nature Reviews. Materials

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001015
OSTI ID:
1469848
Journal Information:
Nature Reviews. Materials, Vol. 2, Issue 8; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 2058-8437
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English

References (141)

CO2 adsorption and catalytic application of Co-MOF-74 synthesized by microwave heating journal May 2012
A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals journal November 2010
High Uptakes of CO 2 and CH 4 in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101 journal July 2008
Synthesis and CO2/CH4 separation performance of Bio-MOF-1 membranes journal January 2012
Effective visible-light driven CO 2 photoreduction via a promising bifunctional iridium coordination polymer journal January 2014
Fe-Porphyrin-Based Metal–Organic Framework Films as High-Surface Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO 2 journal September 2015
Understanding Small-Molecule Interactions in Metal-Organic Frameworks: Coupling Experiment with Theory journal May 2015
Preliminary Design of a Vacuum Pressure Swing Adsorption Process for Natural Gas Upgrading Based on Amino-Functionalized MIL-53 journal June 2015
An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity journal June 2010
Comparing physisorption and chemisorption solid sorbents for use separating CO2 from flue gas using temperature swing adsorption journal January 2011
Selective Capture of Carbon Dioxide under Humid Conditions by Hydrophobic Chabazite-Type Zeolitic Imidazolate Frameworks journal July 2014
Catalysis for the Valorization of Exhaust Carbon: from CO 2 to Chemicals, Materials, and Fuels. Technological Use of CO 2 journal November 2013
Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO 2 reduction under visible light journal January 2015
Hierarchical metal–organic framework nanoflowers for effective CO 2 transformation driven by visible light journal January 2015
Highly selective electrochemical reduction of carbon dioxide using Cu based metal organic framework as an electrocatalyst journal November 2012
Engineering of coordination polymers for shape selective alkylation of large aromatics and the role of defects journal April 2010
Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites journal November 2009
Gas Separation Properties of Metal Organic Framework (MOF-5) Membranes journal April 2012
Purification of Hydrogen by Pressure Swing Adsorption journal January 2000
Pushing the limits on possibilities for large scale gas separation: which strategies? journal January 2001
Separation of CO 2 from CH 4 Using Mixed-Ligand Metal−Organic Frameworks journal August 2008
Molecular Insight into the Adsorption of H 2 S in the Flexible MIL-53(Cr) and Rigid MIL-47(V) MOFs: Infrared Spectroscopy Combined to Molecular Simulations journal December 2010
Significantly Enhanced CO2/CH4 Separation Selectivity within a 3D Prototype Metal-Organic Framework Functionalized with OH Groups on Pore Surfaces at Room Temperature journal April 2011
Studies on Photocatalytic CO 2 Reduction over NH 2 -Uio-66(Zr) and Its Derivatives: Towards a Better Understanding of Photocatalysis on Metal-Organic Frameworks journal September 2013
Metal–Organic Framework-Based Catalysts: Chemical Fixation of CO2 with Epoxides Leading to Cyclic Organic Carbonates journal January 2015
High and Selective CO 2 Uptake in a Cobalt Adeninate Metal−Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores journal January 2010
Transformation of Carbon Dioxide journal June 2007
Site-Specific CO2 Adsorption and Zero Thermal Expansion in an Anisotropic Pore Network journal December 2011
Enhanced Binding Affinity, Remarkable Selectivity, and High Capacity of CO2 by Dual Functionalization of a rht-Type Metal-Organic Framework journal December 2011
Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF 3 -Terminated Self-Assembled Monolayers on Au(111) journal October 2005
Introduction of a mediator for enhancing photocatalytic performance via post-synthetic metal exchange in metal–organic frameworks (MOFs) journal January 2015
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks journal August 2011
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871 https://doi.org/10.1021/ja8036096
journal August 2008
Porous pcu-type Zn(II) framework material with high adsorption selectivity for CO 2 over N 2 journal March 2016
Methane purification by adsorptive processes on MIL-53(Al) journal March 2015
CO2 recovery from mixtures with nitrogen in a vacuum swing adsorber using metal organic framework adsorbent: A comparative study journal March 2012
Partitioning MOF-5 into Confined and Hydrophobic Compartments for Carbon Capture under Humid Conditions journal August 2016
Confinement of Ultrasmall Cu/ZnO x Nanoparticles in Metal–Organic Frameworks for Selective Methanol Synthesis from Catalytic Hydrogenation of CO 2 journal March 2017
Electrochemical Reduction of Carbon Dioxide Using a Copper Rubeanate Metal Organic Framework journal January 2012
“Heterogeneity within Order” in Metal-Organic Frameworks journal January 2015
Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach journal December 2009
Synthesis and Characterization of Metal–Organic Framework-74 Containing 2, 4, 6, 8, and 10 Different Metals journal May 2014
Influence of the Amide Groups in the CO 2 /N 2 Selectivity of a Series of Isoreticular, Interpenetrated Metal–Organic Frameworks journal September 2016
Metal-organic framework membrane process for high purity CO 2 production journal June 2016
An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction journal February 2012
Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation journal May 2008
Carbon Dioxide Capture in Metal–Organic Frameworks journal September 2011
Metal–organic frameworks to satisfy gas upgrading demands: fine-tuning the soc -MOF platform for the operative removal of H 2 S journal January 2017
Integration of an Inorganic Semiconductor with a Metal-Organic Framework: A Platform for Enhanced Gaseous Photocatalytic Reactions journal May 2014
Highly Selective Carbon Dioxide Uptake by [Cu(bpy- n ) 2 (SiF 6 )] (bpy-1 = 4,4′-Bipyridine; bpy-2 = 1,2-Bis(4-pyridyl)ethene) journal February 2012
A new tetrazolate zeolite-like framework for highly selective CO 2 /CH 4 and CO 2 /N 2 separation journal January 2014
On the development of Vacuum Swing adsorption (VSA) technology for post-combustion CO2 capture journal January 2013
Metal organic framework membranes for carbon dioxide separation journal March 2015
Covalent Chemistry beyond Molecules journal February 2016
A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO 2 Removal and Air Capture Using Physisorption journal July 2016
Photocatalytic CO 2 Reduction to Formate Using a Mn(I) Molecular Catalyst in a Robust Metal–Organic Framework journal July 2015
Metal–Organic Frameworks for Separations journal September 2011
Construction of Interpenetrated Ruthenium Metal–Organic Frameworks as Stable Photocatalysts for CO 2 Reduction journal August 2015
Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc) journal April 2012
Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO 2 capture? journal January 2015
Amide and N-oxide functionalization of T-shaped ligands for isoreticular MOFs with giant enhancements in CO 2 separation journal January 2014
Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation journal February 2013
Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) journal January 2014
Synthesis and characterization of ZIF-69 membranes and separation for CO2/CO mixture journal May 2010
A Highly Porous Metal-Organic Framework with Open Nickel Sites journal September 2010
Amides Do Not Always Work: Observation of Guest Binding in an Amide-Functionalized Porous Metal–Organic Framework journal November 2016
The upper bound revisited journal July 2008
Photoactive Metal–Organic Framework and Its Film for Light-Driven Hydrogen Production and Carbon Dioxide Reduction journal July 2016
Chemical Adsorption Enhanced CO 2 Capture and Photoreduction over a Copper Porphyrin Based Metal Organic Framework journal July 2013
Monodentate hydroxide as a super strong yet reversible active site for CO 2 capture from high-humidity flue gas journal January 2015
Highly efficient visible-light-driven CO 2 reduction to formate by a new anthracene-based zirconium MOF via dual catalytic routes journal January 2016
Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
  • Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
  • Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786 https://doi.org/10.1021/ja903411w
journal July 2009
Removal of Carbon Dioxide from Natural Gas by Vacuum Pressure Swing Adsorption journal November 2006
Fabrication of Gold/Titania Photocatalyst for CO 2 Reduction Based on Pyrolytic Conversion of the Metal–Organic Framework NH 2 -MIL-125(Ti) Loaded with Gold Nanoparticles journal October 2015
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis journal August 2011
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide journal October 2015
Thermodynamics of mixed-gas adsorption journal January 1965
CO2 capture and separation technologies for end-of-pipe applications – A review journal June 2010
Synthesis of continuous MOF-5 membranes on porous α-alumina substrates journal February 2009
Mixed-Linker Metal-Organic Frameworks as Catalysts for the Synthesis of Propylene Carbonate from Propylene Oxide and CO 2 journal August 2009
Fe-Based MOFs for Photocatalytic CO 2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways journal October 2014
Effect of Humidity on the Performance of Microporous Coordination Polymers as Adsorbents for CO 2 Capture journal May 2011
Ultrahigh Porosity in Metal-Organic Frameworks journal July 2010
Post-treatment effect on gas separation property of mixed matrix membranes containing metal organic frameworks journal September 2014
Highly scalable ZIF-based mixed-matrix hollow fiber membranes for advanced hydrocarbon separations journal May 2014
New highly porous aluminium based metal-organic frameworks: Al(OH)(ndc) (ndc=2,6-naphthalene dicarboxylate) and Al(OH)(bpdc) (bpdc=4,4′-biphenyl dicarboxylate) journal June 2009
Zeolitic Imidazole Framework-8 Catalysts in the Conversion of CO 2 to Chloropropene Carbonate journal December 2011
Photocatalytic CO 2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation journal January 2015
MOF-5/n-Bu4NBr: an efficient catalyst system for the synthesis of cyclic carbonates from epoxides and CO2 under mild conditions journal January 2009
Correlation of separation factor versus permeability for polymeric membranes journal October 1991
Control of catenation in CuTATB-n metal–organic frameworks by sonochemical synthesis and its effect on CO2 adsorption journal January 2011
Metal−Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture journal April 2011
The role of metal–organic frameworks in a carbon-neutral energy cycle journal April 2016
Insights into an intriguing gas sorption mechanism in a polar metal–organic framework with open-metal sites and narrow channels journal January 2014
Organosilica functionalized zeolitic imidazolate framework ZIF-90 membrane for CO2/CH4 separation journal July 2014
CO2/N2 separations with mixed-matrix membranes containing Mg2(dobdc) nanocrystals journal January 2013
Polar Group and Defect Engineering in a Metal-Organic Framework: Synergistic Promotion of Carbon Dioxide Sorption and Conversion journal February 2015
Sequestering CO 2 for Short-Term Storage in MOFs: Copolymer Synthesis with Oxiranes journal April 2014
Copper Nanocrystals Encapsulated in Zr-based Metal–Organic Frameworks for Highly Selective CO 2 Hydrogenation to Methanol journal November 2016
Why hybrid porous solids capture greenhouse gases? journal January 2011
Quest for Anionic MOF Membranes: Continuous sod -ZMOF Membrane with CO 2 Adsorption-Driven Selectivity journal January 2015
Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO 2 journal July 2016
Significant enhancement of gas uptake capacity and selectivity via the judicious increase of open metal sites and Lewis basic sites within two polyhedron-based metal–organic frameworks journal January 2016
Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO 2 under Ambient Conditions journal February 2014
Synthesis of highly c-oriented ZIF-69 membranes by secondary growth and their gas permeation properties journal September 2011
Mixed-Metal Zeolitic Imidazolate Frameworks and their Selective Capture of Wet Carbon Dioxide over Methane journal June 2016
Current status and development of membranes for CO2/CH4 separation: A review journal January 2013
Synthesis, Structure, Assembly, and Modulation of the CO 2 Adsorption Properties of a Zinc-Adeninate Macrocycle journal June 2009
Probing the mechanism of CO 2 capture in diamine-appended metal–organic frameworks using measured and simulated X-ray spectroscopy journal January 2015
Metal-organic framework nanosheets as building blocks for molecular sieving membranes journal December 2014
High and selective CO2 uptake, H2 storage and methanol sensing on the amine-decorated 12-connected MOF CAU-1 journal January 2011
Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine journal October 2010
The iron member of the CPO-27 coordination polymer series: Synthesis, characterization, and intriguing redox properties journal July 2012
Post-combustion CO2 capture with the HKUST-1 and MIL-101(Cr) metal–organic frameworks: Adsorption, separation and regeneration investigations journal September 2013
Interfacial Design of Mixed Matrix Membranes for Improved Gas Separation Performance journal March 2016
Alumina-supported cobalt–adeninate MOF membranes for CO 2 /CH 4 separation journal January 2014
Metal-Organic Frameworks for CO 2 Chemical Transformations journal October 2016
Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO 2 , N 2 , and H 2 O journal April 2015
Multipoint Interactions Enhanced CO 2 Uptake: A Zeolite-like Zinc–Tetrazole Framework with 24-Nuclear Zinc Cages journal November 2012
A highly permeable and selective amino-functionalized MOF CAU-1 membrane for CO 2 –N 2 separation journal January 2014
Plasmon-Enhanced Photocatalytic CO 2 Conversion within Metal–Organic Frameworks under Visible Light journal December 2016
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities journal September 2010
Adsorption of CO2 and CH4 on a magnesium-based metal organic framework journal January 2011
Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption journal January 2011
New Prototype Isoreticular Metal−Organic Framework Zn 4 O(FMA) 3 for Gas Storage journal June 2009
Remarkably Enhanced Gas Separation by Partial Self-Conversion of a Laminated Membrane to Metal-Organic Frameworks journal January 2015
Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO 2 under Mild Reaction Conditions journal December 2013
A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
  • Beyzavi, M. Hassan; Klet, Rachel C.; Tussupbayev, Samat
  • Journal of the American Chemical Society, Vol. 136, Issue 45, p. 15861-15864 https://doi.org/10.1021/ja508626n
journal October 2014
Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866 https://doi.org/10.1021/ja503296c
journal June 2014
MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc -MOF for CH 4 , O 2 , and CO 2 Storage journal October 2015
Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature journal December 2005
Metal–Organic Frameworks as a Potential Platform for Selective Treatment of Gaseous Sulfur Compounds journal October 2016
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks journal March 2015
Polymer–Metal–Organic Frameworks (polyMOFs) as Water Tolerant Materials for Selective Carbon Dioxide Separations journal January 2016
A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO 2 Conversion journal February 2016
Metal–organic framework membranes: from synthesis to separation application journal January 2014
Fabrication of a CO2-selective membrane by stepwise liquid-phase deposition of an alkylether functionalized pillared-layered metal-organic framework [Cu2L2P]n on a macroporous support journal March 2012
The Chemistry and Applications of Metal-Organic Frameworks journal August 2013
Enhanced carbon dioxide capture upon incorporation of N,N′-dimethylethylenediamine in the metal–organic framework CuBTTri journal January 2011
Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal−Organic Frameworks at Room Temperature journal July 2009
Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide journal January 2009