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Title: Aligned van der Waals Coupled Growth of Carbon Nanotubes to Hexagonal Boron Nitride

Journal Article · · Advanced Materials Interfaces

Abstract 1D carbon nanotubes (CNTs) are grown on hexagonal boron nitride (hBN) surfaces. The nanotubes show clear preference to align to specific crystal directions of the hBN substrate. Raman spectra confirm that the nanotubes consist of sp 2 carbon, while nanomanipulation shows that they are van der Waals coupled to the underlying hBN substrate. Scanning conductance and electric force microscopy show that the CNTs have significantly greater electrical conductance compared to the hBN. This integrated aligned growth of materials with similar lattices, yet having dissimilar dimensionality and electrical conducting properties, provides a promising route to achieving intricate nanoscale electrical circuits on high‐quality insulating substrates.

Sponsoring Organization:
USDOE
Grant/Contract Number:
0000223282
OSTI ID:
1469724
Journal Information:
Advanced Materials Interfaces, Journal Name: Advanced Materials Interfaces Vol. 5 Journal Issue: 21; ISSN 2196-7350
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

References (54)

Carbon nanotube quantum dots on hexagonal boron nitride journal July 2014
Boron nitride substrates for high mobility chemical vapor deposited graphene journal June 2011
Epitaxial growth of single-domain graphene on hexagonal boron nitride journal July 2013
Helical microtubules of graphitic carbon journal November 1991
The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper journal October 2013
Superconductivity in Ultrathin Nb Se 2 Layers journal January 1972
Normal Modes in Hexagonal Boron Nitride journal June 1966
Electronic structure of a graphene/hexagonal-BN heterostructure grown on Ru(0001) by chemical vapor deposition and atomic layer deposition: extrinsically doped graphene journal July 2010
A Platform for Large-Scale Graphene Electronics - CVD Growth of Single-Layer Graphene on CVD-Grown Hexagonal Boron Nitride journal April 2013
Graphite and Hexagonal Boron-Nitride have the Same Interlayer Distance. Why? journal February 2012
C60: Buckminsterfullerene journal November 1985
Synthesis of Patched or Stacked Graphene and hBN Flakes: A Route to Hybrid Structure Discovery journal February 2013
What's Next for Low-Dimensional Materials? journal October 2013
Growth of Bilayer Graphene on Insulating Substrates journal October 2011
Seed-Assisted Growth of Single-Crystalline Patterned Graphene Domains on Hexagonal Boron Nitride by Chemical Vapor Deposition journal September 2016
In Situ Formation of Carbon Nanotubes Encapsulated within Boron Nitride Nanotubes via Electron Irradiation journal July 2014
Graphene, hexagonal boron nitride, and their heterostructures: properties and applications journal January 2017
Is hexagonal boron nitride always good as a substrate for carbon nanotube-based devices? journal January 2015
Scanned Conductance Microscopy of Carbon Nanotubes and λ-DNA journal March 2002
Micrometer-Scale Ballistic Transport in Encapsulated Graphene at Room Temperature journal June 2011
Electrostatic force microscopy and electrical isolation of etched few-layer graphene nano-domains journal December 2014
Nucleation and growth of single crystal graphene on hexagonal boron nitride journal January 2012
Boron nitride substrates for high-quality graphene electronics journal August 2010
Light scattering study of boron nitride microcrystals journal June 1981
Electrostatic Doping of Graphene through Ultrathin Hexagonal Boron Nitride Films journal November 2011
Superior Current Carrying Capacity of Boron Nitride Encapsulated Carbon Nanotubes with Zero-Dimensional Contacts journal September 2015
Parallel boron nitride nanoribbons and etch tracks formed through catalytic etching journal April 2018
Atomically thin p–n junctions with van der Waals heterointerfaces journal August 2014
Raman spectroscopy of carbon nanotubes journal March 2005
Two-dimensional gas of massless Dirac fermions in graphene journal November 2005
Integrated Nanotubes, Etch Tracks, and Nanoribbons in Crystallographic Alignment to a Graphene Lattice journal December 2014
Tuning between crystallographically aligned carbon nanotube growth and graphene etching journal October 2014
A hetero-epitaxial-double-atomic-layer system of monolayer graphene/monolayer h-BN on Ni(111) journal August 2000
Quantitative Analysis of Scanning Conductance Microscopy journal May 2004
Hofstadter’s butterfly and the fractal quantum Hall effect in moiré superlattices journal May 2013
Van der Waals heterostructures journal July 2013
Cloning of Dirac fermions in graphene superlattices journal May 2013
Nanometre-scale rolling and sliding of carbon nanotubes journal January 1999
Electric Field Effect in Atomically Thin Carbon Films journal October 2004
Supercurrent in the quantum Hall regime journal May 2016
Chirality dependent surface adhesion of single-walled carbon nanotubes on graphene surfaces journal September 2010
Frictional Characteristics of Atomically Thin Sheets journal April 2010
One-Dimensional Electrical Contact to a Two-Dimensional Material journal October 2013
Tunable Resistance of a Carbon Nanotube-Graphite Interface journal December 2000
Catalytic Directional Cutting of Hexagonal Boron Nitride: The Roles of Interface and Etching Agents journal April 2017
Catalytic Transparency of Hexagonal Boron Nitride on Copper for Chemical Vapor Deposition Growth of Large-Area and High-Quality Graphene journal May 2014
Crystal Size Effects on the Exciton Absorption Spectrum of W Se 2 journal December 1970
Surface Potentials and Layer Charge Distributions in Few-Layer Graphene Films journal January 2009
Helicity-dependent single-walled carbon nanotube alignment on graphite for helical angle and handedness recognition journal July 2013
Oriented graphene nanoribbons embedded in hexagonal boron nitride trenches journal March 2017
Single Crystals of MoS 2 Several Molecular Layers Thick journal March 1966
Crystallographically Aligned Carbon Nanotubes Grown on Few-Layer Graphene Films journal July 2011
Chiral Structure Determination of Aligned Single-Walled Carbon Nanotubes on Graphite Surface journal October 2013
Thin single-wall BN-nanotubes formed inside carbon nanotubes journal March 2013