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Title: Chlorine dioxide treatment for zebra mussel control

Technical Report ·
OSTI ID:146970
 [1];  [2];  [3]
  1. Dairyland Power Cooperative, La Crosse, WI (United States)
  2. Nalco Chemical Company, Naperville, IL (United States)
  3. Rio Linda Chemical Company, Sacramento, CA (United States)

Chlorine is recognized and commonly used biocide for power plant cooling water and service water treatment programs, including the control of zebra mussels. Chlorine dioxide has recently become a popular method of zebra mussel control because of its economy, safety, environmental acceptability, and effectiveness when compared to other mussel control methods. This control technique was recently demonstrated at Dairyland Power Cooperative`s Alma Generating Station on the east bank of the upper Mississippi River in Alma, Wisconsin. The project was assisted with EPRI Tailored Collaboration Program funds. The Dairyland Power Alam Generating Station consists of five generating units that utilize raw, untreated Mississippi River water for condenser, circulating, and service water supplies. The first units were built in 1947, with the final and largest unit being completed in 1960. Total station generating capacity is 200 MW. Because of recent increases in the zebra mussel density at the station intake, Dairyland Power selected the team of Nalco and Rio Linda to perform a chlorine dioxide treatment of the station`s new water systems to eradicate and control the mussels before their presence created operational difficulties. This paper will present the results of the treatment including treatment theory, design and construction of the treatment system, the method of chlorine dioxide generation, treatment concentration, analytical methods o monitoring chlorine dioxide generation, residuals and trihalomethane (THM) concentrations, protocol for monitoring treatment mortality, and the effects of chlorine dioxide and detoxification on other water chemistry parameters and equipment materials. The goal of this paper is to inform and assist users with establishing consistent and uniform practices for safely utilizing and monitoring chlorine dioxide in the eradication and control of zebra mussels.

Research Organization:
Electric Power Research Inst. (EPRI), Palo Alto, CA (United States)
OSTI ID:
146970
Report Number(s):
EPRI-TR-105116; CONF-9502124-; TRN: 95:007969-0029
Resource Relation:
Conference: 5. international Zebra mussel and other aquatic nuisance organisms conference, Toronto (Canada), 14-21 Feb 1995; Other Information: PBD: Jun 1995; Related Information: Is Part Of Proceedings of the fifth international zebra mussel and other aquatic nuisance organisms conference 1995; Ackerman, J.D. [Univ. of Northern British Columbia, Prince George (Canada)]; PB: 494 p.
Country of Publication:
United States
Language:
English