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Title: A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode

Journal Article · · Nature Energy

Although non-aqueous Li-ion batteries possess significantly higher energy density than their aqueous counterparts, the latter can be more feasible for grid-scale applications when cost, safety and cycle life are taken into consideration. Moreover, aqueous Zn-ion batteries have an energy storage advantage over alkali-based batteries as they can employ Zn metal as the negative electrode, dramatically increasing energy density. However, their development is plagued by a limited choice of positive electrodes, which often show poor rate capability and inadequate cycle life. We report a vanadium oxide bronze pillared by interlayer Zn2+ ions and water (Zn0.25V2O5nH2O), as the positive electrode for a Zn cell. A reversible Zn2+ ion (de)intercalation storage process at fast rates, with more than one Zn2+ per formula unit (a capacity up to 300 mAh g-1), is characterized. The Zn cell offers an energy density of ~450 Wh l-1 and exhibits a capacity retention of more than 80% over 1,000 cycles, with no dendrite formation at the Zn electrode.

Research Organization:
Univ. of Waterloo, ON (Canada)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); Natural Resources Canada (NRCan); Natural Sciences and Engineering Research Council of Canada (NSERC)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1469690
Journal Information:
Nature Energy, Vol. 1, Issue 10; ISSN 2058-7546
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 1685 works
Citation information provided by
Web of Science

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