A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode

Kundu, Dipan; Adams, Brian D.; Duffort, Victor; Vajargah, Shahrzad Hosseini; Nazar, Linda F.

doi:10.1038/NENERGY.2016.119

A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode

Journal Article · Fri Aug 26 00:00:00 EDT 2016 · Nature Energy

DOI:https://doi.org/10.1038/NENERGY.2016.119· OSTI ID:1469690

Kundu, Dipan ^[1]; Adams, Brian D. ^[2]; Duffort, Victor ^[2]; Vajargah, Shahrzad Hosseini ^[2]; ^[2]

Univ. of Waterloo, ON (Canada). Dept. of Chemistry and Waterloo Inst. for Nanotechnology; University of Waterloo
Univ. of Waterloo, ON (Canada). Dept. of Chemistry and Waterloo Inst. for Nanotechnology

Although non-aqueous Li-ion batteries possess significantly higher energy density than their aqueous counterparts, the latter can be more feasible for grid-scale applications when cost, safety and cycle life are taken into consideration. Moreover, aqueous Zn-ion batteries have an energy storage advantage over alkali-based batteries as they can employ Zn metal as the negative electrode, dramatically increasing energy density. However, their development is plagued by a limited choice of positive electrodes, which often show poor rate capability and inadequate cycle life. We report a vanadium oxide bronze pillared by interlayer Zn²⁺ ions and water (Zn_0.25V₂O₅•nH₂O), as the positive electrode for a Zn cell. A reversible Zn²⁺ ion (de)intercalation storage process at fast rates, with more than one Zn²⁺ per formula unit (a capacity up to 300 mAh g^-1), is characterized. The Zn cell offers an energy density of ~450 Wh l^-1 and exhibits a capacity retention of more than 80% over 1,000 cycles, with no dendrite formation at the Zn electrode.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Waterloo, ON (Canada)

Sponsoring Organization:: Natural Resources Canada (NRCan); Natural Sciences and Engineering Research Council of Canada (NSERC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1469690

Journal Information:: Nature Energy, Journal Name: Nature Energy Journal Issue: 10 Vol. 1; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Hierarchical Metal Sulfide/Carbon Spheres: A Generalized Synthesis and High Sodium‐Storage Performance Shen, Laifa; Wang, Yi; Wu, Feixiang Angewandte Chemie, Vol. 131, Issue 22 https://doi.org/10.1002/ange.201901840	journal	April 2019
Reversible Oxygen Redox Chemistry in Aqueous Zinc‐Ion Batteries Wan, Fang; Zhang, Yan; Zhang, Linlin Angewandte Chemie, Vol. 131, Issue 21 https://doi.org/10.1002/ange.201902679	journal	April 2019
Design Strategies for Vanadium‐based Aqueous Zinc‐Ion Batteries Wan, Fang; Niu, Zhiqiang Angewandte Chemie, Vol. 131, Issue 46 https://doi.org/10.1002/ange.201903941	journal	August 2019
An Electrolytic Zn–MnO ₂ Battery for High‐Voltage and Scalable Energy Storage Chao, Dongliang; Zhou, Wanhai; Ye, Chao Angewandte Chemie, Vol. 131, Issue 23 https://doi.org/10.1002/ange.201904174	journal	May 2019
Inhibiting VOPO ₄ ⋅ x H ₂ O Decomposition and Dissolution in Rechargeable Aqueous Zinc Batteries to Promote Voltage and Capacity Stabilities Shi, Hua‐Yu; Song, Yu; Qin, Zengming Angewandte Chemie, Vol. 131, Issue 45 https://doi.org/10.1002/ange.201908853	journal	September 2019
A Deep‐Cycle Aqueous Zinc‐Ion Battery Containing an Oxygen‐Deficient Vanadium Oxide Cathode Liao, Meng; Wang, Jiawei; Ye, Lei Angewandte Chemie, Vol. 132, Issue 6 https://doi.org/10.1002/ange.201912203	journal	December 2019
Proton Intercalation/De‐Intercalation Dynamics in Vanadium Oxides for Aqueous Aluminum Electrochemical Cells Zhao, Qing; Liu, Luojia; Yin, Jiefu Angewandte Chemie, Vol. 132, Issue 8 https://doi.org/10.1002/ange.201912634	journal	January 2020
A Smart Flexible Zinc Battery with Cooling Recovery Ability Zhao, Jingwen; Sonigara, Keval K.; Li, Jiajia Angewandte Chemie International Edition, Vol. 56, Issue 27 https://doi.org/10.1002/anie.201704373	journal	June 2017
Highly Stable Aqueous Zinc-Ion Storage Using a Layered Calcium Vanadium Oxide Bronze Cathode Xia, Chuan; Guo, Jing; Li, Peng Angewandte Chemie International Edition, Vol. 57, Issue 15 https://doi.org/10.1002/anie.201713291	journal	February 2018
How Water Accelerates Bivalent Ion Diffusion at the Electrolyte/Electrode Interface Wang, Fei; Sun, Wei; Shadike, Zulipiya Angewandte Chemie International Edition, Vol. 57, Issue 37 https://doi.org/10.1002/anie.201806748	journal	August 2018
An Environmentally Friendly and Flexible Aqueous Zinc Battery Using an Organic Cathode Guo, Zhaowei; Ma, Yuanyuan; Dong, Xiaoli Angewandte Chemie International Edition, Vol. 57, Issue 36 https://doi.org/10.1002/anie.201807121	journal	August 2018
A Long-Cycle-Life Self-Doped Polyaniline Cathode for Rechargeable Aqueous Zinc Batteries Shi, Hua-Yu; Ye, Yin-Jian; Liu, Kuan Angewandte Chemie International Edition, Vol. 57, Issue 50 https://doi.org/10.1002/anie.201808886	journal	November 2018
Reversible Oxygen Redox Chemistry in Aqueous Zinc‐Ion Batteries Wan, Fang; Zhang, Yan; Zhang, Linlin Angewandte Chemie International Edition, Vol. 58, Issue 21 https://doi.org/10.1002/anie.201902679	journal	May 2019
Design Strategies for Vanadium-based Aqueous Zinc-Ion Batteries Wan, Fang; Niu, Zhiqiang Angewandte Chemie International Edition, Vol. 58, Issue 46 https://doi.org/10.1002/anie.201903941	journal	August 2019
An Electrolytic Zn–MnO ₂ Battery for High‐Voltage and Scalable Energy Storage Chao, Dongliang; Zhou, Wanhai; Ye, Chao Angewandte Chemie International Edition, Vol. 58, Issue 23 https://doi.org/10.1002/anie.201904174	journal	June 2019
A Four‐Electron Sulfur Electrode Hosting a Cu ²⁺ /Cu ⁺ Redox Charge Carrier Wu, Xianyong; Markir, Aaron; Ma, Lu Angewandte Chemie International Edition, Vol. 58, Issue 36 https://doi.org/10.1002/anie.201905875	journal	September 2019
Inhibiting VOPO ₄ ⋅ x H ₂ O Decomposition and Dissolution in Rechargeable Aqueous Zinc Batteries to Promote Voltage and Capacity Stabilities Shi, Hua‐Yu; Song, Yu; Qin, Zengming Angewandte Chemie International Edition, Vol. 58, Issue 45 https://doi.org/10.1002/anie.201908853	journal	November 2019
A Deep‐Cycle Aqueous Zinc‐Ion Battery Containing an Oxygen‐Deficient Vanadium Oxide Cathode Liao, Meng; Wang, Jiawei; Ye, Lei Angewandte Chemie International Edition, Vol. 59, Issue 6 https://doi.org/10.1002/anie.201912203	journal	February 2020
Free‐Standing Hydrated Sodium Vanadate Papers for High‐Stability Zinc‐Ion Batteries Tan, Huiteng; Chen, Dong; Liu, Weiling Batteries & Supercaps, Vol. 3, Issue 3 https://doi.org/10.1002/batt.201900145	journal	November 2019
Electrodeposited Manganese Oxide on Carbon Paper for Zinc‐Ion Battery Cathodes Dhiman, Arjun; Ivey, Douglas G. Batteries & Supercaps, Vol. 3, Issue 3 https://doi.org/10.1002/batt.201900150	journal	December 2019
An Exceptionally Facile Synthesis of Highly Efficient Oxygen Evolution Electrodes for Zinc-Oxygen Batteries Yan, Zhao; Wang, Erdong; Gao, Jianxin ChemElectroChem, Vol. 4, Issue 9 https://doi.org/10.1002/celc.201700477	journal	June 2017
Carbon-Coated Na _2.2 V _1.2 Ti _0.8 (PO ₄ ) ₃ Cathode with Excellent Cycling Performance for Aqueous Sodium-Ion Batteries Lei, Ping; Wang, Yao; Zhang, Fang ChemElectroChem, Vol. 5, Issue 17 https://doi.org/10.1002/celc.201800379	journal	June 2018
In Situ Growth of a Feather-like MnO ₂ Nanostructure on Carbon Paper for High-Performance Rechargeable Sodium-Ion Batteries Li, Huan; Liu, Anmin; Zhao, Shuai ChemElectroChem, Vol. 5, Issue 21 https://doi.org/10.1002/celc.201800830	journal	August 2018
Fabrication of Zinc Anodes for Aqueous Lithium‐Ion Batteries by Supersonic Cold Spraying Ahmed, Moin; Yazdi, Alireza Z.; Dayani, Siavash B. ChemElectroChem, Vol. 6, Issue 5 https://doi.org/10.1002/celc.201801492	journal	January 2019
A Flexible Quasi‐Solid‐State Bifunctional Device with Zinc‐Ion Microbattery and Photodetector Bi, Songshan; Wan, Fang; Huang, Shuo ChemElectroChem, Vol. 6, Issue 15 https://doi.org/10.1002/celc.201900966	journal	May 2019
Nanocrystal-Assembled Porous Na ₃ MgTi(PO ₄ ) ₃ Aggregates as Highly Stable Anode for Aqueous Sodium-Ion Batteries Zhang, Fang; Li, Wanfeng; Xiang, Xingde Chemistry - A European Journal, Vol. 23, Issue 52 https://doi.org/10.1002/chem.201703044	journal	August 2017
Recent Progress in the Electrolytes of Aqueous Zinc‐Ion Batteries Huang, Shuo; Zhu, Jiacai; Tian, Jinlei Chemistry – A European Journal, Vol. 25, Issue 64 https://doi.org/10.1002/chem.201902660	journal	September 2019
Rational Development of Neutral Aqueous Electrolytes for Zinc-Air Batteries Clark, Simon; Latz, Arnulf; Horstmann, Birger ChemSusChem, Vol. 10, Issue 23 https://doi.org/10.1002/cssc.201701468	journal	November 2017
Water in Rechargeable Multivalent-Ion Batteries: An Electrochemical Pandora's Box Manalastas, William; Kumar, Sonal; Verma, Vivek ChemSusChem, Vol. 12, Issue 2 https://doi.org/10.1002/cssc.201801523	journal	January 2019
Inhibition of Zinc Dendrite Growth in Zinc‐Based Batteries Lu, Wenjing; Xie, Congxin; Zhang, Huamin ChemSusChem, Vol. 11, Issue 23 https://doi.org/10.1002/cssc.201801657	journal	October 2018
Lignin@Nafion Membranes Forming Zn Solid–Electrolyte Interfaces Enhance the Cycle Life for Rechargeable Zinc‐Ion Batteries Yuan, Du; Manalastas, William; Zhang, Liping ChemSusChem, Vol. 12, Issue 21 https://doi.org/10.1002/cssc.201901409	journal	October 2019
Enhancing Zn‐Ion Storage Capability of Hydrated Vanadium Pentoxide by the Strategic Introduction of La ³⁺ He, Jinjun; Liu, Xiaoqing; Zhang, Haozhe ChemSusChem, Vol. 13, Issue 6 https://doi.org/10.1002/cssc.201902659	journal	March 2020
Mechanistic Investigation of a Hybrid Zn/V ₂ O ₅ Rechargeable Battery with a Binary Li ⁺ /Zn ²⁺ Aqueous Electrolyte Batyrbekuly, Dauren; Cajoly, Sabrina; Laïk, Barbara ChemSusChem, Vol. 13, Issue 4 https://doi.org/10.1002/cssc.201903072	journal	January 2020
Highly Reversible Phase Transition Endows V ₆ O ₁₃ with Enhanced Performance as Aqueous Zinc‐Ion Battery Cathode Shan, Lutong; Zhou, Jiang; Zhang, Wanying Energy Technology, Vol. 7, Issue 6 https://doi.org/10.1002/ente.201900022	journal	April 2019
Dendrite Growth Suppression by Zn ²⁺ ‐Integrated Nafion Ionomer Membranes: Beyond Porous Separators toward Aqueous Zn/V ₂ O ₅ Batteries with Extended Cycle Life Ghosh, Meena; Vijayakumar, Vidyanand; Kurungot, Sreekumar Energy Technology, Vol. 7, Issue 9 https://doi.org/10.1002/ente.201900442	journal	May 2019
Lamellar V ₅ O ₁₂ ·6H ₂ O Nanobelts Coupled with Inert Zn(OH) ₂ ·0.5H ₂ O as Cathode for Aqueous Zn ²⁺ /Nonaqueous Na ⁺ Storage Applications Yan, Honglin; Ru, Qiang; Gao, Ping Energy Technology, Vol. 8, Issue 3 https://doi.org/10.1002/ente.201901105	journal	November 2019
Challenges and perspectives for manganese‐based oxides for advanced aqueous zinc‐ion batteries Zhao, Yinlei; Zhu, Yunhai; Zhang, Xinbo InfoMat, Vol. 2, Issue 2 https://doi.org/10.1002/inf2.12042	journal	December 2019
Chevrel Phase Mo ₆ T ₈ (T = S, Se) as Electrodes for Advanced Energy Storage Mei, Lin; Xu, Jiantie; Wei, Zengxi Small, Vol. 13, Issue 34 https://doi.org/10.1002/smll.201701441	journal	July 2017
High-Performance Aqueous Zinc-Ion Battery Based on Layered H ₂ V ₃ O ₈ Nanowire Cathode He, Pan; Quan, Yueli; Xu, Xu Small, Vol. 13, Issue 47 https://doi.org/10.1002/smll.201702551	journal	November 2017
Graphene Scroll-Coated α-MnO ₂ Nanowires as High-Performance Cathode Materials for Aqueous Zn-Ion Battery Wu, Buke; Zhang, Guobin; Yan, Mengyu Small, Vol. 14, Issue 13 https://doi.org/10.1002/smll.201703850	journal	February 2018
A Novel Graphite-Graphite Dual Ion Battery Using an AlCl ₃ -[EMIm]Cl Liquid Electrolyte Li, Zhanyu; Liu, Jian; Niu, Bangbang Small, Vol. 14, Issue 28 https://doi.org/10.1002/smll.201800745	journal	June 2018
Flexible Zn-Ion Batteries: Recent Progresses and Challenges Yu, Peng; Zeng, Yinxiang; Zhang, Haozhe Small, Vol. 15, Issue 7 https://doi.org/10.1002/smll.201804760	journal	January 2019
Langmuir–Blodgett Nanowire Devices for In Situ Probing of Zinc‐Ion Batteries Liu, Qin; Hao, Zhimeng; Liao, Xiaobin Small, Vol. 15, Issue 30 https://doi.org/10.1002/smll.201902141	journal	June 2019
H ⁺ ‐Insertion Boosted α‐MnO ₂ for an Aqueous Zn‐Ion Battery Gao, Xu; Wu, Hanwen; Li, Wenjie Small, Vol. 16, Issue 5 https://doi.org/10.1002/smll.201905842	journal	January 2020
Recent Progress of Rechargeable Batteries Using Mild Aqueous Electrolytes Huang, Jianhang; Guo, Zhaowei; Ma, Yuanyuan Small Methods, Vol. 3, Issue 1 https://doi.org/10.1002/smtd.201800272	journal	September 2018
3D CNTs Networks Enable MnO ₂ Cathodes with High Capacity and Superior Rate Capability for Flexible Rechargeable Zn–MnO ₂ Batteries Zhang, Xiyue; Wu, Shuwei; Deng, Shengjue Small Methods, Vol. 3, Issue 12 https://doi.org/10.1002/smtd.201900525	journal	September 2019
Bio-degradable zinc-ion battery based on a prussian blue analogue cathode and a bio-ionic liquid-based electrolyte Liu, Zhen; Bertram, Philipp; Endres, Frank Journal of Solid State Electrochemistry, Vol. 21, Issue 7 https://doi.org/10.1007/s10008-017-3589-0	journal	April 2017
Synthesis of polyaniline/graphene composite and its application in zinc-rechargeable batteries Wang, Zhen; Han, Jia-Jun; Zhang, Ning Journal of Solid State Electrochemistry, Vol. 23, Issue 12 https://doi.org/10.1007/s10008-019-04435-x	journal	November 2019
A rechargeable Zn/graphite dual-ion battery with an ionic liquid-based electrolyte Fan, Jiaxin; Xiao, Qiangqiang; Fang, Yaobing Ionics, Vol. 25, Issue 3 https://doi.org/10.1007/s11581-018-2644-x	journal	July 2018
Rational design of nitrogen doped hierarchical porous carbon for optimized zinc-ion hybrid supercapacitors Liu, Penggao; Gao, Yang; Tan, Yangyang Nano Research, Vol. 12, Issue 11 https://doi.org/10.1007/s12274-019-2521-6	journal	October 2019
A Perspective: the Technical Barriers of Zn Metal Batteries Ji, Xiulei; Jiang, Heng Chemical Research in Chinese Universities, Vol. 36, Issue 1 https://doi.org/10.1007/s40242-020-9092-7	journal	January 2020
Ultra-High Mass-Loading Cathode for Aqueous Zinc-Ion Battery Based on Graphene-Wrapped Aluminum Vanadate Nanobelts Zhang, Wenyu; Liang, Shuquan; Fang, Guozhao Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0300-2	journal	August 2019
Electrode Materials for Rechargeable Zinc-Ion and Zinc-Air Batteries: Current Status and Future Perspectives Yang, Dan; Tan, Huiteng; Rui, Xianhong Electrochemical Energy Reviews, Vol. 2, Issue 3 https://doi.org/10.1007/s41918-019-00035-5	journal	May 2019
Alkaline earth metal vanadates as sodium-ion battery anodes Xu, Xiaoming; Niu, Chaojiang; Duan, Manyi Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00211-5	journal	September 2017
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities Zhang, Ning; Cheng, Fangyi; Liu, Junxiang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00467-x	journal	September 2017
Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers Wan, Fang; Zhang, Linlin; Dai, Xi Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04060-8	journal	April 2018
Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery Huang, Jianhang; Wang, Zhuo; Hou, Mengyan Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04949-4	journal	July 2018
Sustainability-inspired cell design for a fully recyclable sodium ion battery Liu, Tiefeng; Zhang, Yaping; Chen, Chao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09933-0	journal	April 2019
Dual-phase nanostructuring of layered metal oxides for high-performance aqueous rechargeable potassium ion microbatteries Li, Ying-Qi; Shi, Hang; Wang, Sheng-Bo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12274-7	journal	September 2019
Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries Nam, Kwan Woo; Park, Sarah S.; dos Reis, Roberto Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12857-4	journal	October 2019
Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries Wu, Xianyong; Hong, Jessica J.; Shin, Woochul Nature Energy, Vol. 4, Issue 2 https://doi.org/10.1038/s41560-018-0309-7	journal	January 2019
Rejuvenating zinc batteries Hu, Enyuan; Yang, Xiao-Qing Nature Materials, Vol. 17, Issue 6 https://doi.org/10.1038/s41563-018-0090-9	journal	May 2018
Nanostructured positive electrode materials for post-lithium ion batteries Wang, Faxing; Wu, Xiongwei; Li, Chunyang Energy & Environmental Science, Vol. 9, Issue 12 https://doi.org/10.1039/c6ee02070d	journal	January 2016
Investigation of zinc ion storage of transition metal oxides, sulfides, and borides in zinc ion battery systems Liu, Wenbao; Hao, Jianwu; Xu, Chengjun Chemical Communications, Vol. 53, Issue 51 https://doi.org/10.1039/c7cc01064h	journal	January 2017
Ab initio study of Li, Mg and Al insertion into rutile VO ₂ : fast diffusion and enhanced voltages for multivalent batteries Kulish, Vadym V.; Koch, Daniel; Manzhos, Sergei Physical Chemistry Chemical Physics, Vol. 19, Issue 33 https://doi.org/10.1039/c7cp04360k	journal	January 2017
Comparison of Li, Na, Mg and Al-ion insertion in vanadium pentoxides and vanadium dioxides Kulish, Vadym V.; Manzhos, Sergei RSC Advances, Vol. 7, Issue 30 https://doi.org/10.1039/c7ra02474f	journal	January 2017
Green-low-cost rechargeable aqueous zinc-ion batteries using hollow porous spinel ZnMn ₂ O ₄ as the cathode material Wu, Xianwen; Xiang, Yanhong; Peng, Qingjing Journal of Materials Chemistry A, Vol. 5, Issue 34 https://doi.org/10.1039/c7ta00100b	journal	January 2017
High-performance flexible quasi-solid-state Zn–MnO ₂ battery based on MnO ₂ nanorod arrays coated 3D porous nitrogen-doped carbon cloth Qiu, Wenda; Li, Yu; You, Ao Journal of Materials Chemistry A, Vol. 5, Issue 28 https://doi.org/10.1039/c7ta03274a	journal	January 2017
Encapsulation of zinc hexacyanoferrate nanocubes with manganese oxide nanosheets for high-performance rechargeable zinc ion batteries Lu, Ke; Song, Bin; Zhang, Yuxin Journal of Materials Chemistry A, Vol. 5, Issue 45 https://doi.org/10.1039/c7ta07834j	journal	January 2017
Strategic combination of Grignard reagents and allyl-functionalized ionic liquids as an advanced electrolyte for rechargeable magnesium batteries Lee, Boeun; Cho, Jae-Hyun; Seo, Hyo Ree Journal of Materials Chemistry A, Vol. 6, Issue 7 https://doi.org/10.1039/c7ta09330f	journal	January 2018
High performance, environmentally benign and integratable Zn//MnO ₂ microbatteries Lai, Wenhui; Wang, Yang; Lei, Zhanwu Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/c7ta10936a	journal	January 2018
Aqueous rechargeable Zn-ion batteries: an imperishable and high-energy Zn ₂ V ₂ O ₇ nanowire cathode through intercalation regulation Sambandam, Balaji; Soundharrajan, Vaiyapuri; Kim, Sungjin Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/c7ta11237h	journal	January 2018
Novel layered iron vanadate cathode for high-capacity aqueous rechargeable zinc batteries Peng, Zhuo; Wei, Qiulong; Tan, Shuangshuang Chemical Communications, Vol. 54, Issue 32 https://doi.org/10.1039/c8cc00987b	journal	January 2018
Investigation of V ₂ O ₅ as a low-cost rechargeable aqueous zinc ion battery cathode Zhou, Jiang; Shan, Lutong; Wu, Zhuoxi Chemical Communications, Vol. 54, Issue 35 https://doi.org/10.1039/c8cc02250j	journal	January 2018
Rechargeable aqueous zinc–iodine batteries: pore confining mechanism and flexible device application Li, Yixin; Liu, Luojia; Li, Haixia Chemical Communications, Vol. 54, Issue 50 https://doi.org/10.1039/c8cc02616e	journal	January 2018
Polymer grafted on carbon nanotubes as a flexible cathode for aqueous zinc ion batteries Yue, Xiujun; Liu, Haodong; Liu, Ping Chemical Communications, Vol. 55, Issue 11 https://doi.org/10.1039/c8cc10060h	journal	January 2019
Direct catalytic co-conversion of cellulose and methane to renewable petrochemicals Wang, Aiguo; Austin, Danielle; He, Peng Catalysis Science & Technology, Vol. 8, Issue 21 https://doi.org/10.1039/c8cy01749b	journal	January 2018
Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface Kundu, Dipan; Hosseini Vajargah, Shahrzad; Wan, Liwen Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/c8ee00378e	journal	January 2018
Light-permeable, photoluminescent microbatteries embedded in the color filter of a screen Zhu, Minshen; Wang, Zhenguang; Li, Hongfei Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/c8ee00590g	journal	January 2018
A rechargeable aqueous Zn ²⁺ -battery with high power density and a long cycle-life Wang, Fei; Hu, Enyuan; Sun, Wei Energy & Environmental Science, Vol. 11, Issue 11 https://doi.org/10.1039/c8ee01883a	journal	January 2018
Rational design of nano-architecture composite hydrogel electrode towards high performance Zn-ion hybrid cell Han, Jianwei; Wang, Kai; Liu, Wenhao Nanoscale, Vol. 10, Issue 27 https://doi.org/10.1039/c8nr03889a	journal	January 2018
High-performance rechargeable aqueous Zn-ion batteries with a poly(benzoquinonyl sulfide) cathode Dawut, Gulbahar; Lu, Yong; Miao, Licheng Inorganic Chemistry Frontiers, Vol. 5, Issue 6 https://doi.org/10.1039/c8qi00197a	journal	January 2018
A high-capacity and long-life aqueous rechargeable zinc battery using a porous metal–organic coordination polymer nanosheet cathode Wu, Shan; Wang, Yi-Fan; Liu, Wei-Liang Inorganic Chemistry Frontiers, Vol. 5, Issue 12 https://doi.org/10.1039/c8qi00959g	journal	January 2018
Synthesis of manganese-based complex as cathode material for aqueous rechargeable batteries Qiu, Nan; Chen, Hong; Yang, Zhaoming RSC Advances, Vol. 8, Issue 28 https://doi.org/10.1039/c8ra01982g	journal	January 2018
Fast Li ⁺ diffusion in interlayer-expanded vanadium disulfide nanosheets for Li ⁺ /Mg ²⁺ hybrid-ion batteries Meng, Yuan; Zhao, Yingying; Wang, Dashuai Journal of Materials Chemistry A, Vol. 6, Issue 14 https://doi.org/10.1039/c8ta00418h	journal	January 2018
A flexible rechargeable zinc-ion wire-shaped battery with shape memory function Wang, Zifeng; Ruan, Zhaoheng; Liu, Zhuoxin Journal of Materials Chemistry A, Vol. 6, Issue 18 https://doi.org/10.1039/c8ta01172a	journal	January 2018
Binder-free stainless steel@Mn ₃ O ₄ nanoflower composite: a high-activity aqueous zinc-ion battery cathode with high-capacity and long-cycle-life Zhu, Chuyu; Fang, Guozhao; Zhou, Jiang Journal of Materials Chemistry A, Vol. 6, Issue 20 https://doi.org/10.1039/c8ta01198b	journal	January 2018
K ₂ V ₆ O ₁₆ ·2.7H ₂ O nanorod cathode: an advanced intercalation system for high energy aqueous rechargeable Zn-ion batteries Sambandam, Balaji; Soundharrajan, Vaiyapuri; Kim, Sungjin Journal of Materials Chemistry A, Vol. 6, Issue 32 https://doi.org/10.1039/c8ta02018c	journal	January 2018
An electrochemically induced bilayered structure facilitates long-life zinc storage of vanadium dioxide Wei, Tongye; Li, Qian; Yang, Gongzheng Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/c8ta02090f	journal	January 2018
Pseudocapacitive layered birnessite sodium manganese dioxide for high-rate non-aqueous sodium ion capacitors Jiang, Yalong; Tan, Shuangshuang; Wei, Qiulong Journal of Materials Chemistry A, Vol. 6, Issue 26 https://doi.org/10.1039/c8ta02516a	journal	January 2018
An adaptive and stable bio-electrolyte for rechargeable Zn-ion batteries Zhang, Silan; Yu, Nengsheng; Zeng, Sha Journal of Materials Chemistry A, Vol. 6, Issue 26 https://doi.org/10.1039/c8ta04298e	journal	January 2018
In situ growth of (NH ₄ ) ₂ V ₁₀ O ₂₅ ·8H ₂ O urchin-like hierarchical arrays as superior electrodes for all-solid-state supercapacitors Jiang, Yingchang; Jiang, Le; Wu, Zeyi Journal of Materials Chemistry A, Vol. 6, Issue 34 https://doi.org/10.1039/c8ta05706k	journal	January 2018
Highly reversible and long-life cycling aqueous zinc-ion battery based on ultrathin (NH ₄ ) ₂ V ₁₀ O ₂₅ ·8H ₂ O nanobelts Wei, Tongye; Li, Qian; Yang, Gongzheng Journal of Materials Chemistry A, Vol. 6, Issue 41 https://doi.org/10.1039/c8ta06626d	journal	January 2018
A deeply rechargeable zinc anode with pomegranate-inspired nanostructure for high-energy aqueous batteries Chen, Peng; Wu, Yutong; Zhang, Yamin Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta07809b	journal	January 2018
A high-rate aqueous rechargeable zinc ion battery based on the VS ₄ @rGO nanocomposite Qin, Haigang; Yang, Zhanhong; Chen, Linlin Journal of Materials Chemistry A, Vol. 6, Issue 46 https://doi.org/10.1039/c8ta08133f	journal	January 2018
Durable, flexible self-standing hydrogel electrolytes enabling high-safety rechargeable solid-state zinc metal batteries Han, Qi; Chi, Xiaowei; Zhang, Shuming Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/c8ta08314b	journal	January 2018
Engineering the interplanar spacing of ammonium vanadates as a high-performance aqueous zinc-ion battery cathode Tang, Boya; Zhou, Jiang; Fang, Guozhao Journal of Materials Chemistry A, Vol. 7, Issue 3 https://doi.org/10.1039/c8ta09338e	journal	January 2019
Manganese ion pre-intercalated hydrated vanadium oxide as a high-performance cathode for magnesium ion batteries Deng, Xuanwei; Xu, Yanan; An, Qinyou Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c8ta11236c	journal	January 2019
Unraveling the role of structural water in bilayer V ₂ O ₅ during Zn ²⁺ -intercalation: insights from DFT calculations Wu, Tao; Zhu, Kaiyue; Qin, Changyong Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c8ta12014e	journal	January 2019
A new rechargeable battery based on a zinc anode and a NaV ₆ O ₁₅ nanorod cathode Islam, Saiful; Alfaruqi, Muhammad Hilmy; Sambandam, Balaji Chemical Communications, Vol. 55, Issue 26 https://doi.org/10.1039/c9cc00897g	journal	January 2019
Exploring new hydrated delta type vanadium oxides for lithium intercalation Orive, Joseba; Fernández de Luis, Roberto; Larrea, Edurne S. Dalton Transactions, Vol. 49, Issue 12 https://doi.org/10.1039/c9dt04088a	journal	January 2020
Crystal water for high performance layered manganese oxide cathodes in aqueous rechargeable zinc batteries Nam, Kwan Woo; Kim, Heejin; Choi, Jin Hyeok Energy & Environmental Science, Vol. 12, Issue 6 https://doi.org/10.1039/c9ee00718k	journal	January 2019
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Going beyond Intercalation Capacity of Aqueous Batteries by Exploiting Conversion Reactions of Mn and Zn electrodes for Energy‐Dense Applications

Journal Article · Sun Nov 10 19:00:00 EST 2019 · Advanced Energy Materials · OSTI ID:1573846

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A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode

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