Hot Hole Collection and Photoelectrochemical CO2 Reduction with Plasmonic Au/p-GaN Photocathodes

DuChene, Joseph S.; Tagliabue, Giulia; Welch, Alex J.; Cheng, Wen-Hui; Atwater, Harry A.

doi:10.1021/acs.nanolett.8b00241

Title: Hot Hole Collection and Photoelectrochemical CO₂ Reduction with Plasmonic Au/p-GaN Photocathodes

Journal Article · Fri Mar 09 00:00:00 EST 2018 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.8b00241· OSTI ID:1469320

^[1]; Tagliabue, Giulia ^[1]; Welch, Alex J. ^[1]; Cheng, Wen-Hui ^[1];

^[1]

California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP) and Thomas J. Watson Lab. of Applied Physics

Harvesting nonequilibrium hot carriers from plasmonic- metal nanostructures offers unique opportunities for driving photo- chemical reactions at the nanoscale. Despite numerous examples of hot electron-driven processes, the realization of plasmonic systems capable of harvesting hot holes from metal nanostructures has eluded the nascent field of plasmonic photocatalysis. In this work, we fabricate gold/p-type gallium nitride (Au/p-GaN) Schottky junctions tailored for photoelectrochemical studies of plasmon-induced hot-hole capture and conversion. Despite the presence of an interfacial Schottky barrier to hot-hole injection of more than 1 eV across the Au/p-GaN heterojunction, plasmonic Au/p-GaN photocathodes exhibit photoelectrochemical properties consistent with the injection of hot holes from Au nanoparticles into p- GaN upon plasmon excitation. The photocurrent action spectrum of the plasmonic photocathodes faithfully follows the surface plasmon resonance absorption spectrum of the Au nanoparticles and open-circuit voltage studies demonstrate a sustained photovoltage during plasmon excitation. Comparison with Ohmic Au/p-NiO heterojunctions confirms that the vast majority of hot holes generated via interband transitions in Au are sufficiently hot to inject above the 1.1 eV interfacial Schottky barrier at the Au/p-GaN heterojunction. We further investigated plasmon-driven photoelectrochemical CO₂ reduction with the Au/p-GaN photocathodes and observed improved selectivity for CO production over H₂ evolution in aqueous electrolytes. Taken together, our results offer experimental validation of photoexcited hot holes more than 1 eV below the Au Fermi level and demonstrate a photoelectrochemical platform for harvesting hot carriers to drive solar-to-fuel energy conversion.

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Research Organization:: California Institute of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Swiss National Science Foundation (SNSF)

Grant/Contract Number:: SC0004993; P2EZP2_159101; P300P2_171417

OSTI ID:: 1469320

Journal Information:: Nano Letters, Vol. 18, Issue 4; Related Information: 10.1021/acs.nanolett.8b00241; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 240 works

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References (59)

Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy Linic, Suljo; Christopher, Phillip; Ingram, David B. Nature Materials, Vol. 10, Issue 12 https://doi.org/10.1038/nmat3151	journal	November 2011
Plasmon-induced hot-electron generation at nanoparticle/metal-oxide interfaces for photovoltaic and photocatalytic devices Clavero, César Nature Photonics, Vol. 8, Issue 2 https://doi.org/10.1038/nphoton.2013.238	journal	January 2014
Plasmon-induced hot carrier science and technology Brongersma, Mark L.; Halas, Naomi J.; Nordlander, Peter Nature Nanotechnology, Vol. 10, Issue 1 https://doi.org/10.1038/nnano.2014.311	journal	January 2015
Hot Charge Carrier Transmission from Plasmonic Nanostructures Christopher, Phillip; Moskovits, Martin Annual Review of Physical Chemistry, Vol. 68, Issue 1 https://doi.org/10.1146/annurev-physchem-052516-044948	journal	May 2017
Photochemical transformations on plasmonic metal nanoparticles Linic, Suljo; Aslam, Umar; Boerigter, Calvin Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4281	journal	May 2015
What’s so Hot about Electrons in Metal Nanoparticles? Hartland, Gregory V.; Besteiro, Lucas V.; Johns, Paul ACS Energy Letters, Vol. 2, Issue 7 https://doi.org/10.1021/acsenergylett.7b00333	journal	June 2017
Plasmon-Induced Hot Carriers in Metallic Nanoparticles Manjavacas, Alejandro; Liu, Jun G.; Kulkarni, Vikram ACS Nano, Vol. 8, Issue 8 https://doi.org/10.1021/nn502445f	journal	July 2014
Nonradiative Plasmon Decay and Hot Carrier Dynamics: Effects of Phonons, Surfaces, and Geometry Brown, Ana M.; Sundararaman, Ravishankar; Narang, Prineha ACS Nano, Vol. 10, Issue 1 https://doi.org/10.1021/acsnano.5b06199	journal	December 2015
Theoretical predictions for hot-carrier generation from surface plasmon decay Sundararaman, Ravishankar; Narang, Prineha; Jermyn, Adam S. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6788	journal	December 2014
Theory and computation of hot carriers generated by surface plasmon polaritons in noble metals Bernardi, Marco; Mustafa, Jamal; Neaton, Jeffrey B. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8044	journal	June 2015
Theory of Photoinjection of Hot Plasmonic Carriers from Metal Nanostructures into Semiconductors and Surface Molecules Govorov, Alexander O.; Zhang, Hui; Gun’ko, Yurii K. The Journal of Physical Chemistry C, Vol. 117, Issue 32 https://doi.org/10.1021/jp405430m	journal	July 2013
Relaxation of Plasmon-Induced Hot Carriers Liu, Jun G.; Zhang, Hui; Link, Stephan ACS Photonics, Vol. 5, Issue 7 https://doi.org/10.1021/acsphotonics.7b00881	journal	December 2017
Anomalous ultrafast dynamics of hot plasmonic electrons in nanostructures with hot spots Harutyunyan, Hayk; Martinson, Alex B. F.; Rosenmann, Daniel Nature Nanotechnology, Vol. 10, Issue 9 https://doi.org/10.1038/nnano.2015.165	journal	August 2015
Optical Studies of Dynamics in Noble Metal Nanostructures Hartland, Gregory V. Chemical Reviews, Vol. 111, Issue 6 https://doi.org/10.1021/cr1002547	journal	June 2011
Photodetection with Active Optical Antennas Knight, M. W.; Sobhani, H.; Nordlander, P. Science, Vol. 332, Issue 6030, p. 702-704 https://doi.org/10.1126/science.1203056	journal	May 2011
Distinguishing between plasmon-induced and photoexcited carriers in a device geometry Zheng, Bob Y.; Zhao, Hangqi; Manjavacas, Alejandro Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8797	journal	July 2015
Metamaterial Perfect Absorber Based Hot Electron Photodetection Li, Wei; Valentine, Jason Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl501090w	journal	May 2014
Locally Oxidized Silicon Surface-Plasmon Schottky Detector for Telecom Regime Goykhman, Ilya; Desiatov, Boris; Khurgin, Jacob Nano Letters, Vol. 11, Issue 6 https://doi.org/10.1021/nl200187v	journal	June 2011
Hot-Electron Photodetection with a Plasmonic Nanostripe Antenna Chalabi, Hamidreza; Schoen, David; Brongersma, Mark L. Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl4044373	journal	February 2014
Circularly polarized light detection with hot electrons in chiral plasmonic metamaterials Li, Wei; Coppens, Zachary J.; Besteiro, Lucas V. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9379	journal	September 2015
Plasmonic Photosensitization of a Wide Band Gap Semiconductor: Converting Plasmons to Charge Carriers Mubeen, Syed; Hernandez-Sosa, Gerardo; Moses, Daniel Nano Letters, Vol. 11, Issue 12 https://doi.org/10.1021/nl203457v	journal	December 2011
An autonomous photosynthetic device in which all charge carriers derive from surface plasmons Mubeen, Syed; Lee, Joun; Singh, Nirala Nature Nanotechnology, Vol. 8, Issue 4 https://doi.org/10.1038/nnano.2013.18	journal	February 2013
Panchromatic Photoproduction of H ₂ with Surface Plasmons Mubeen, Syed; Lee, Joun; Liu, Deyu Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00111	journal	February 2015
Plasmon-induced selective carbon dioxide conversion on earth-abundant aluminum-cuprous oxide antenna-reactor nanoparticles Robatjazi, Hossein; Zhao, Hangqi; Swearer, Dayne F. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00055-z	journal	June 2017
Heterometallic antenna−reactor complexes for photocatalysis Swearer, Dayne F.; Zhao, Hangqi; Zhou, Linan Proceedings of the National Academy of Sciences, Vol. 113, Issue 32 https://doi.org/10.1073/pnas.1609769113	journal	July 2016
Hot-Electron-Induced Dissociation of H ₂ on Gold Nanoparticles Supported on SiO ₂ Mukherjee, Shaunak; Zhou, Linan; Goodman, Amanda M. Journal of the American Chemical Society, Vol. 136, Issue 1 https://doi.org/10.1021/ja411017b	journal	December 2013
Aluminum Nanocrystals as a Plasmonic Photocatalyst for Hydrogen Dissociation Zhou, Linan; Zhang, Chao; McClain, Michael J. Nano Letters, Vol. 16, Issue 2 https://doi.org/10.1021/acs.nanolett.5b05149	journal	January 2016
Al–Pd Nanodisk Heterodimers as Antenna–Reactor Photocatalysts Zhang, Chao; Zhao, Hangqi; Zhou, Linan Nano Letters, Vol. 16, Issue 10 https://doi.org/10.1021/acs.nanolett.6b03582	journal	September 2016
Product selectivity in plasmonic photocatalysis for carbon dioxide hydrogenation Zhang, Xiao; Li, Xueqian; Zhang, Du Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14542	journal	February 2017
Controlling energy flow in multimetallic nanostructures for plasmonic catalysis Aslam, Umar; Chavez, Steven; Linic, Suljo Nature Nanotechnology, Vol. 12, Issue 10 https://doi.org/10.1038/nnano.2017.131	journal	July 2017
Plasmon-Assisted Water Splitting Using Two Sides of the Same SrTiO ₃ Single-Crystal Substrate: Conversion of Visible Light to Chemical Energy Zhong, Yuqing; Ueno, Kosei; Mori, Yuko Angewandte Chemie International Edition, Vol. 53, Issue 39 https://doi.org/10.1002/anie.201404926	journal	July 2014
Direct observation of charge separation on Au localized surface plasmons Sá, Jacinto; Tagliabue, Giulia; Friedli, Peter Energy & Environmental Science, Vol. 6, Issue 12 https://doi.org/10.1039/c3ee42731e	journal	January 2013
The Role of Photon Energy and Semiconductor Substrate in the Plasmon-Mediated Photooxidation of Citrate by Silver Nanoparticles Thrall, Elizabeth S.; Preska Steinberg, Asher; Wu, Xiaomu The Journal of Physical Chemistry C, Vol. 117, Issue 49 https://doi.org/10.1021/jp409586z	journal	November 2013
Plasmon-Mediated Syntheses of Metallic Nanostructures Langille, Mark R.; Personick, Michelle L.; Mirkin, Chad A. Angewandte Chemie International Edition, Vol. 52, Issue 52 https://doi.org/10.1002/anie.201301875	journal	November 2013
Photovoltage Mechanism for Room Light Conversion of Citrate Stabilized Silver Nanocrystal Seeds to Large Nanoprisms Wu, Xiaomu; Redmond, Peter L.; Liu, Haitao Journal of the American Chemical Society, Vol. 130, Issue 29 https://doi.org/10.1021/ja8018669	journal	July 2008
Hot Hole Photoelectrochemistry on Au@SiO ₂ @Au Nanoparticles Schlather, Andrea E.; Manjavacas, Alejandro; Lauchner, Adam The Journal of Physical Chemistry Letters, Vol. 8, Issue 9 https://doi.org/10.1021/acs.jpclett.7b00563	journal	April 2017
Plasmon Induced Photovoltage and Charge Separation in Citrate-Stabilized Gold Nanoparticles Wu, Xiaomu; Thrall, Elizabeth S.; Liu, Haitao The Journal of Physical Chemistry C, Vol. 114, Issue 30 https://doi.org/10.1021/jp102720r	journal	July 2010
Polyvinylpyrrolidone-induced anisotropic growth of gold nanoprisms in plasmon-driven synthesis Zhai, Yueming; DuChene, Joseph S.; Wang, Yi-Chung Nature Materials, Vol. 15, Issue 8 https://doi.org/10.1038/nmat4683	journal	July 2016
A Comparison of Photocatalytic Activities of Gold Nanoparticles Following Plasmonic and Interband Excitation and a Strategy for Harnessing Interband Hot Carriers for Solution Phase Photocatalysis Zhao, Jie; Nguyen, Son C.; Ye, Rong ACS Central Science, Vol. 3, Issue 5 https://doi.org/10.1021/acscentsci.7b00122	journal	April 2017
Activation Energies of Plasmonic Catalysts Kim, Youngsoo; Dumett Torres, Daniel; Jain, Prashant K. Nano Letters, Vol. 16, Issue 5 https://doi.org/10.1021/acs.nanolett.6b01373	journal	April 2016
The case for plasmon-derived hot carrier devices Moskovits, Martin Nature Nanotechnology, Vol. 10, Issue 1 https://doi.org/10.1038/nnano.2014.280	journal	January 2015
Properties of Plasmon-Induced Photoelectric Conversion on a TiO ₂ /NiO p–n Junction with Au Nanoparticles Nakamura, Keisuke; Oshikiri, Tomoya; Ueno, Kosei The Journal of Physical Chemistry Letters, Vol. 7, Issue 6 https://doi.org/10.1021/acs.jpclett.6b00291	journal	March 2016
Direct Plasmon-Driven Photoelectrocatalysis Robatjazi, Hossein; Bahauddin, Shah Mohammad; Doiron, Chloe Nano Letters, Vol. 15, Issue 9 https://doi.org/10.1021/acs.nanolett.5b02453	journal	August 2015
Band-Edge Potentials of n-Type and p-Type GaN Beach, J. D.; Collins, R. T.; Turner, J. A. Journal of The Electrochemical Society, Vol. 150, Issue 7 https://doi.org/10.1149/1.1577542	journal	January 2003
Artificial photosynthesis using metal/nonmetal-nitride semiconductors: current status, prospects, and challenges Kibria, M. G.; Mi, Z. Journal of Materials Chemistry A, Vol. 4, Issue 8 https://doi.org/10.1039/C5TA07364B	journal	January 2016
p-Type Doping of GaN Nanowires Characterized by Photoelectrochemical Measurements Kamimura, Jumpei; Bogdanoff, Peter; Ramsteiner, Manfred Nano Letters, Vol. 17, Issue 3 https://doi.org/10.1021/acs.nanolett.6b04560	journal	February 2017
Visible light-driven efficient overall water splitting using p-type metal-nitride nanowire arrays Kibria, M. G.; Chowdhury, F. A.; Zhao, S. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7797	journal	April 2015
Low-resistance ohmic contacts to p -type GaN achieved by the oxidation of Ni/Au films Ho, Jin-Kuo; Jong, Charng-Shyang; Chiu, Chien C. Journal of Applied Physics, Vol. 86, Issue 8 https://doi.org/10.1063/1.371392	journal	October 1999
Mechanism for Ohmic contact formation of oxidized Ni/Au on p -type GaN Jang, Ho Won; Kim, Soo Young; Lee, Jong-Lam Journal of Applied Physics, Vol. 94, Issue 3 https://doi.org/10.1063/1.1586983	journal	August 2003
Investigation of the chemistry and electronic properties of metal/gallium nitride interfaces Wu, C. I. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 16, Issue 4 https://doi.org/10.1116/1.590151	journal	July 1998
Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures Christopher, Phillip; Xin, Hongliang; Linic, Suljo Nature Chemistry, Vol. 3, Issue 6 https://doi.org/10.1038/nchem.1032	journal	May 2011
Wafer-Level Artificial Photosynthesis for CO ₂ Reduction into CH ₄ and CO Using GaN Nanowires AlOtaibi, Bandar; Fan, Shizhao; Wang, Defa ACS Catalysis, Vol. 5, Issue 9 https://doi.org/10.1021/acscatal.5b00776	journal	August 2015
Energy-Conversion Properties of Vapor-Liquid-Solid-Grown Silicon Wire-Array Photocathodes Boettcher, S. W.; Spurgeon, J. M.; Putnam, M. C. Science, Vol. 327, Issue 5962, p. 185-187 https://doi.org/10.1126/science.1180783	journal	January 2010
Enhanced absorption and carrier collection in Si wire arrays for photovoltaic applications Kelzenberg, Michael D.; Boettcher, Shannon W.; Petykiewicz, Jan A. Nature Materials, Vol. 9, Issue 3, p. 239-244 https://doi.org/10.1038/nmat2635	journal	February 2010
Wafer-Level Photocatalytic Water Splitting on GaN Nanowire Arrays Grown by Molecular Beam Epitaxy Wang, Defa; Pierre, Adrien; Kibria, Md Golam Nano Letters, Vol. 11, Issue 6 https://doi.org/10.1021/nl2006802	journal	June 2011
Highly Stable Photoelectrochemical Water Splitting and Hydrogen Generation Using a Double-Band InGaN/GaN Core/Shell Nanowire Photoanode AlOtaibi, B.; Nguyen, H. P. T.; Zhao, S. Nano Letters, Vol. 13, Issue 9 https://doi.org/10.1021/nl402156e	journal	August 2013
Plasmon-Enhanced Photocurrent Generation and Water Oxidation with a Gold Nanoisland-Loaded Titanium Dioxide Photoelectrode Shi, Xu; Ueno, Kosei; Takabayashi, Naoki The Journal of Physical Chemistry C, Vol. 117, Issue 6 https://doi.org/10.1021/jp3064036	journal	October 2012
Near-Infrared Plasmon-Assisted Water Oxidation Nishijima, Yoshiaki; Ueno, Kosei; Kotake, Yuki The Journal of Physical Chemistry Letters, Vol. 3, Issue 10 https://doi.org/10.1021/jz3003316	journal	April 2012
Positioning the Water Oxidation Reaction Sites in Plasmonic Photocatalysts Wang, Shengyang; Gao, Yuying; Miao, Shu Journal of the American Chemical Society, Vol. 139, Issue 34 https://doi.org/10.1021/jacs.7b04470	journal	August 2017

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Journal Article · Thu Aug 23 00:00:00 EDT 2018 · Nature Communications · OSTI ID:1469320

Tagliabue, Giulia; Jermyn, Adam S.; Sundararaman, Ravishankar; +6 more

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
36 MATERIALS SCIENCE
CO2 reduction
hot carriers
hot holes
Photoelectrochemistry
plasmonic photocathode
Schottky barrier

Title: Hot Hole Collection and Photoelectrochemical CO2 Reduction with Plasmonic Au/p-GaN Photocathodes

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