Electrochemical Properties of Electrodes Derived from NaTi3O6OH·2H2O in Sodium and Lithium Cells

Seshadri, Dhruv; Shirpour, Mona; Doeff, Marca

doi:10.1149/2.0391501jes

Title: Electrochemical Properties of Electrodes Derived from NaTi₃O₆OH·2H₂O in Sodium and Lithium Cells

Journal Article · Wed Nov 12 00:00:00 EST 2014 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0391501jes· OSTI ID:1469152

Seshadri, Dhruv ^[1]; Shirpour, Mona ^[1]; Doeff, Marca ^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division

Materials derived from the layered compound NaTi₃O₆OH·2H₂O, also known as “sodium nonatitanate” or NNT, have recently been found to undergo reversible sodium or lithium intercalation processes at very low potentials. While practical discharge capacities in lithium cells can be above 200 mAh/g, making them of interest for high-energy applications, the presence of mobile sodium in the materials complicates the cycling behavior. A simple ion-exchange process prior to incorporation in electrochemical cells removes all sodium ions, producing the lithiated form of the material. The lithiated material (LNT) performs similarly to NNT in lithium cells, although coulombic inefficiencies are somewhat higher. A comparison is made between the behavior of NNT in sodium cells and that of NNT and the lithiated analog in lithium cells.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC); LBNL Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1469152

Report Number(s):: LBNL-181397; ir:181397

Journal Information:: Journal of the Electrochemical Society, Vol. 162, Issue 1; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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The State and Challenges of Anode Materials Based on Conversion Reactions for Sodium Storage Wu, Chao; Dou, Shi-Xue; Yu, Yan Small, Vol. 14, Issue 22 https://doi.org/10.1002/smll.201703671	journal	March 2018
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Dual anode materials for lithium- and sodium-ion batteries Luo, Yuqing; Tang, Yijian; Zheng, Shasha Journal of Materials Chemistry A, Vol. 6, Issue 10 https://doi.org/10.1039/c8ta00107c	journal	January 2018
Sodium-based batteries: from critical materials to battery systems Li, Fang; Wei, Zengxi; Manthiram, Arumugam Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c8ta11999f	journal	January 2019

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