Scalable slot-die coating of high performance perovskite solar cells

Whitaker, James B.; Kim, Dong Hoe; Larson, Bryon W.; Zhang, Fei; Berry, Joseph J.; van Hest, Maikel F. A. M.; Zhu, Kai

doi:10.1039/C8SE00368H

Title: Scalable slot-die coating of high performance perovskite solar cells

Journal Article · Fri Aug 03 00:00:00 EDT 2018 · Sustainable Energy & Fuels

DOI:https://doi.org/10.1039/C8SE00368H· OSTI ID:1468738

Whitaker, James B. ^[1]; Kim, Dong Hoe ^[1]; Larson, Bryon W. ^[1];

^[1];

^[1]; van Hest, Maikel F. A. M. ^[1];

^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)

Perovskite based photovoltaic devices hold the promise to greatly reduce the cost of solar energy production; however, this potential depends greatly on the ability to deposit perovskite active layers using large scale deposition methods such as slot-die coating without sacrificing efficiency. Using a perovskite precursor ink with long wet-film processing window, we demonstrate efficient perovskite solar cells based on slot-die coated perovskite layer. We found almost no difference in the photophysical and structural details of perovskite films that were deposited by spin coating to films deposited by slot-die coating. Furthermore, we explored various slot-die coating parameters to determine their effect on the performance of the device metrics. In addition to slot-die coating, we demonstrate the versatility of this wide wet-film processing window by fabricating perovskite solar cells with active layers deposited by spin coating, blade coating, and spray coating that all exhibited similar performance.

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Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE National Renewable Energy Laboratory (NREL), Laboratory Directed Research and Development (LDRD) Program; USDOE

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1468738

Alternate ID(s):: OSTI ID: 1464568

Report Number(s):: NREL/JA-5900-71764; SEFUA7

Journal Information:: Sustainable Energy & Fuels, Vol. 2; ISSN 2398-4902

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 115 works

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References (29)

Outlook and Challenges of Perovskite Solar Cells toward Terawatt-Scale Photovoltaic Module Technology Kim, Dong Hoe; Whitaker, James B.; Li, Zhen Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.05.011	journal	August 2018
300% Enhancement of Carrier Mobility in Uniaxial-Oriented Perovskite Films Formed by Topotactic-Oriented Attachment Kim, Dong Hoe; Park, Jaehong; Li, Zhen Advanced Materials, Vol. 29, Issue 23 https://doi.org/10.1002/adma.201606831	journal	April 2017
Vapour-Deposited Cesium Lead Iodide Perovskites: Microsecond Charge Carrier Lifetimes and Enhanced Photovoltaic Performance Hutter, Eline M.; Sutton, Rebecca J.; Chandrashekar, Sanjana ACS Energy Letters, Vol. 2, Issue 8 https://doi.org/10.1021/acsenergylett.7b00591	journal	August 2017
Highly Efficient Perovskite Solar Modules by Scalable Fabrication and Interconnection Optimization Yang, Mengjin; Kim, Dong Hoe; Klein, Talysa R. ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01221	journal	January 2018
Perovskite ink with wide processing window for scalable high-efficiency solar cells Yang, Mengjin; Li, Zhen; Reese, Matthew O. Nature Energy, Vol. 2, Issue 5 https://doi.org/10.1038/nenergy.2017.38	journal	March 2017
A review of the operating limits in slot die coating processes Ding, Xiaoyu; Liu, Jianhua; Harris, Tequila A. L. AIChE Journal, Vol. 62, Issue 7 https://doi.org/10.1002/aic.15268	journal	May 2016
Perovskite Photovoltaics: The Path to a Printable Terawatt-Scale Technology Berry, Joseph J.; van de Lagemaat, Jao; Al-Jassim, Mowafak M. ACS Energy Letters, Vol. 2, Issue 11 https://doi.org/10.1021/acsenergylett.7b00964	journal	October 2017
High-throughput surface preparation for flexible slot die coated perovskite solar cells Remeika, Mikas; Ono, Luis K.; Maeda, Maki Organic Electronics, Vol. 54 https://doi.org/10.1016/j.orgel.2017.12.027	journal	March 2018
Operating windows of slot die coating: Comparison of theoretical predictions with experimental observations Lin, Chi-Feng; Hill Wong, David S.; Liu, Ta-Jo Advances in Polymer Technology, Vol. 29, Issue 1 https://doi.org/10.1002/adv.20173	journal	March 2010
Roll-to-roll fabrication of polymer solar cells Søndergaard, Roar; Hösel, Markus; Angmo, Dechan Materials Today, Vol. 15, Issue 1-2 https://doi.org/10.1016/S1369-7021(12)70019-6	journal	January 2012
Effect of relative humidity on crystal growth, device performance and hysteresis in planar heterojunction perovskite solar cells Gangishetty, Mahesh K.; Scott, Robert W. J.; Kelly, Timothy L. Nanoscale, Vol. 8, Issue 12 https://doi.org/10.1039/C5NR04179A	journal	January 2016
Toward scale-up of perovskite solar cells: Annealing-free perovskite layer by low-cost ultrasonic substrate vibration of wet films Ahmadian-Yazdi, Mohammad-Reza; Eslamian, Morteza Materials Today Communications, Vol. 14 https://doi.org/10.1016/j.mtcomm.2018.01.006	journal	March 2018
Amorphous hole-transporting layer in slot-die coated perovskite solar cells Qin, Tianshi; Huang, Wenchao; Kim, Jueng-Eun Nano Energy, Vol. 31 https://doi.org/10.1016/j.nanoen.2016.11.022	journal	January 2017
Slot-Die Coated Perovskite Films Using Mixed Lead Precursors for Highly Reproducible and Large-Area Solar Cells Lee, Donmin; Jung, Yen-Sook; Heo, Youn-Jung ACS Applied Materials & Interfaces, Vol. 10, Issue 18 https://doi.org/10.1021/acsami.8b02549	journal	April 2018
Unravelling the mechanism of photoinduced charge transfer processes in lead iodide perovskite solar cells Marchioro, Arianna; Teuscher, Joël; Friedrich, Dennis Nature Photonics, Vol. 8, Issue 3 https://doi.org/10.1038/nphoton.2013.374	journal	January 2014
Research Update: Large-area deposition, coating, printing, and processing techniques for the upscaling of perovskite solar cell technology Razza, Stefano; Castro-Hermosa, Sergio; Di Carlo, Aldo APL Materials, Vol. 4, Issue 9 https://doi.org/10.1063/1.4962478	journal	September 2016
Planar versus mesoscopic perovskite microstructures: The influence of CH3NH3PbI3 morphology on charge transport and recombination dynamics Pascoe, Alexander R.; Yang, Mengjin; Kopidakis, Nikos Nano Energy, Vol. 22 https://doi.org/10.1016/j.nanoen.2016.02.031	journal	April 2016
Charge Transfer from Methylammonium Lead Iodide Perovskite to Organic Transport Materials: Efficiencies, Transfer Rates, and Interfacial Recombination Hutter, Eline M.; Hofman, Jan-Jaap; Petrus, Michiel L. Advanced Energy Materials, Vol. 7, Issue 13 https://doi.org/10.1002/aenm.201602349	journal	February 2017
CH ₃ NH ₃ Cl-Assisted One-Step Solution Growth of CH ₃ NH ₃ PbI ₃ : Structure, Charge-Carrier Dynamics, and Photovoltaic Properties of Perovskite Solar Cells Zhao, Yixin; Zhu, Kai The Journal of Physical Chemistry C, Vol. 118, Issue 18 https://doi.org/10.1021/jp502696w	journal	April 2014
Grain engineering by ultrasonic substrate vibration post-treatment of wet perovskite films for annealing-free, high performance, and stable perovskite solar cells Xiong, Hao; Zabihi, Fatemeh; Wang, Hongzhi Nanoscale, Vol. 10, Issue 18 https://doi.org/10.1039/C8NR00540K	journal	January 2018
Slot-die processing of flexible perovskite solar cells in ambient conditions Ciro, John; Mejía-Escobar, Mario Alejandro; Jaramillo, Franklin Solar Energy, Vol. 150 https://doi.org/10.1016/j.solener.2017.04.071	journal	July 2017
Fabrication and processing of polymer solar cells: A review of printing and coating techniques Krebs, Frederik C. Solar Energy Materials and Solar Cells, Vol. 93, Issue 4, p. 394-412 https://doi.org/10.1016/j.solmat.2008.10.004	journal	April 2009
ITO-Free Flexible Perovskite Solar Cells Based on Roll-to-Roll, Slot-Die Coated Silver Nanowire Electrodes Sears, Kallista K.; Fievez, Mathilde; Gao, Mei Solar RRL, Vol. 1, Issue 8 https://doi.org/10.1002/solr.201700059	journal	July 2017
Toward Large Scale Roll-to-Roll Production of Fully Printed Perovskite Solar Cells Hwang, Kyeongil; Jung, Yen-Sook; Heo, Youn-Jung Advanced Materials, Vol. 27, Issue 7 https://doi.org/10.1002/adma.201404598	journal	January 2015
Scalable Deposition of High-Efficiency Perovskite Solar Cells by Spray-Coating Uličná, Soňa; Dou, Benjia; Kim, Dong Hoe ACS Applied Energy Materials, Vol. 1, Issue 5 https://doi.org/10.1021/acsaem.8b00328	journal	April 2018
Slot die coated planar perovskite solar cells via blowing and heating assisted one step deposition Kim, Jueng-Eun; Jung, Yen-Sook; Heo, Youn-Jung Solar Energy Materials and Solar Cells, Vol. 179 https://doi.org/10.1016/j.solmat.2018.02.003	journal	June 2018
One-step deposition by slot-die coating of mixed lead halide perovskite for photovoltaic applications Cotella, Giovanni; Baker, Jenny; Worsley, David Solar Energy Materials and Solar Cells, Vol. 159 https://doi.org/10.1016/j.solmat.2016.09.013	journal	January 2017
Scalable fabrication of perovskite solar cells Li, Zhen; Klein, Talysa R.; Kim, Dong Hoe Nature Reviews Materials, Vol. 3, Issue 4 https://doi.org/10.1038/natrevmats.2018.17	journal	March 2018
Vapour-Deposited Cesium Lead Iodide Perovskites: Microsecond Charge Carrier Lifetimes and Enhanced Photovoltaic Performance. Hutter, Eline M.; Sutton, Rebecca J.; Chandrashekar, Sanjana Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.31868	text	January 2017

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Drying Dynamics of Solution‐Processed Perovskite Thin‐Film Photovoltaics: In Situ Characterization, Modeling, and Process Control Ternes, Simon; Börnhorst, Tobias; Schwenzer, Jonas A. Advanced Energy Materials, Vol. 9, Issue 39 https://doi.org/10.1002/aenm.201901581	journal	August 2019
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Recent progress towards roll-to-roll manufacturing of perovskite solar cells using slot-die processing Li, Hengyue; Zuo, Chuantian; Scully, Andrew D. Flexible and Printed Electronics, Vol. 5, Issue 1 https://doi.org/10.1088/2058-8585/ab639e	journal	January 2020
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Drying Dynamics of Solution‐Processed Perovskite Thin‐Film Photovoltaics: In Situ Characterization, Modeling, and Process Control Ternes, Simon; Börnhorst, Tobias; Schwenzer, Jonas A. Wiley-VCH Verlag https://doi.org/10.5445/ir/1000097909	text	January 2019

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