Electroplating lithium transition metal oxides

Zhang, Huigang; Ning, Hailong; Busbee, John; Shen, Zihan; Kiggins, Chadd; Hua, Yuyan; Eaves, Janna; Davis, III, Jerome; Shi, Tan; Shao, Yu -Tsun; Zuo, Jian -Min; Hong, Xuhao; Chan, Yanbin; Wang, Shuangbao; Wang, Peng; Sun, Pengcheng; Xu, Sheng; Liu, Jinyun; Braun, Paul V.

doi:10.1126/sciadv.1602427

Title: Electroplating lithium transition metal oxides

Journal Article · Fri May 12 00:00:00 EDT 2017 · Science Advances

DOI:https://doi.org/10.1126/sciadv.1602427· OSTI ID:1466779

^[1]; Ning, Hailong ^[2]; Busbee, John ^[2]; Shen, Zihan ^[1];

^[2]; Hua, Yuyan ^[2];

^[2];

^[2]; Shao, Yu -Tsun ^[3]; Zuo, Jian -Min ^[3]; Hong, Xuhao ^[1]; Chan, Yanbin ^[1]; Wang, Shuangbao ^[1];

^[1]; Sun, Pengcheng ^[3];

^[4]; Liu, Jinyun ^[3]; Braun, Paul V. ^[5]

Nanjing Univ., Nanjing (China)
Xerion Advanced Battery Corp., Champaign, IL (United States)
Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States)
Univ. of California, San Diego, La Jolla, CA (United States)
Xerion Advanced Battery Corp., Champaign, IL (United States); Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States)

Materials synthesis often provides opportunities for innovation. We demonstrate a general low-temperature (260°C) molten salt electrodeposition approach to directly electroplate the important lithium-ion (Li-ion) battery cathode materials LiCoO₂, LiMn₂O₄, and Al-doped LiCoO₂. The crystallinities and electrochemical capacities of the electroplated oxides are comparable to those of the powders synthesized at much higher temperatures (700° to 1000°C). In conclusion, this new growth method significantly broadens the scope of battery form factors and functionalities, enabling a variety of highly desirable battery properties, including high energy, high power, and unprecedented electrode flexibility.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-07ER46471

OSTI ID:: 1466779

Journal Information:: Science Advances, Vol. 3, Issue 5; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 54 works

Citation information provided by
Web of Science

References (82)

Twisted Aligned Carbon Nanotube/Silicon Composite Fiber Anode for Flexible Wire-Shaped Lithium-Ion Battery Lin, Huijuan; Weng, Wei; Ren, Jing Advanced Materials, Vol. 26, Issue 8 https://doi.org/10.1002/adma.201304319	journal	November 2013
On the metastable O2-type LiCoO2 Carlier, D. Solid State Ionics, Vol. 144, Issue 3-4 https://doi.org/10.1016/S0167-2738(01)00982-1	journal	December 2001
Diagrams Er-mKOH for Cobalt at 25-125 °C and at Total Pressure of 1-30 Bar Balej, Jan; Divisek, Jiri Collection of Czechoslovak Chemical Communications, Vol. 62, Issue 11 https://doi.org/10.1135/cccc19971663	journal	January 1997
Electrodeposited Ceramic Single Crystals Switzer, J. A. Science, Vol. 284, Issue 5412 https://doi.org/10.1126/science.284.5412.293	journal	April 1999
Thermal evolution of cobalt hydroxides: a comparative study of their various structural phases Xu, Z. P.; Zeng, H. C. Journal of Materials Chemistry, Vol. 8, Issue 11 https://doi.org/10.1039/a804767g	journal	January 1998
Electrochemical Synthesis and Nonvolatile Resistance Switching of Mn ₃ O ₄ Thin Films Koza, Jakub A.; Schroen, Ian P.; Willmering, Matthew M. Chemistry of Materials, Vol. 26, Issue 15 https://doi.org/10.1021/cm5014027	journal	July 2014
Synthesis and characterization of LiAlyCo1−yO2 and LiAlyNi1−yO2 Jang, Young-Il; Huang, Biying; Wang, Haifeng Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(99)00104-4	journal	September 1999
Analysis of the Polarization in a Li-Ion Battery Cell by Numerical Simulations Nyman, Andreas; Zavalis, Tommy Georgios; Elger, Ragna Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3486161	journal	January 2010
Probing Lithium and Vacancy Ordering in O3 Layered Li[sub x]CoO[sub 2] (x≈0.5) Shao-Horn, Y.; Levasseur, S.; Weill, F. Journal of The Electrochemical Society, Vol. 150, Issue 3 https://doi.org/10.1149/1.1553787	journal	January 2003
Acid-Base Effects in Molten Electrolytes Tremillon, Bernard L. Molten Salt Chemistry https://doi.org/10.1007/978-94-009-3863-2_14	book	January 1987
Potential/pO2− diagrams of iron, cobalt and nickel in molten sodium nitrite Marchiano, S. L.; Arvía, A. J. Electrochimica Acta, Vol. 17, Issue 5 https://doi.org/10.1016/0013-4686(72)90009-6	journal	May 1972
Thermochemical Modeling of Glass: Application to High-Level Nuclear Waste Glass Spear, Karl E.; Besmann, Theodore M.; Beahm, Edward C. MRS Bulletin, Vol. 24, Issue 4 https://doi.org/10.1557/S0883769400052179	journal	April 1999
Enthalpy of formation of LiNiO2, LiCoO2 and their solid solution, LiNi1−xCoxO2 Wang, M. Solid State Ionics, Vol. 166, Issue 1-2 https://doi.org/10.1016/j.ssi.2003.11.004	journal	January 2004
New layered structure obtained by electrochemical deintercalation of the metastable LiCoO2 (O2) variety Mendiboure, A.; Delmas, C.; Hagenmuller, P. Materials Research Bulletin, Vol. 19, Issue 10 https://doi.org/10.1016/0025-5408(84)90204-6	journal	October 1984
Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide Gabrisch, Heike; Yazami, Rachid; Fultz, Brent Journal of The Electrochemical Society, Vol. 151, Issue 6 https://doi.org/10.1149/1.1738677	journal	January 2004
Layered LiCoO[sub 2] with a Different Oxygen Stacking (O2 Structure) as a Cathode Material for Rechargeable Lithium Batteries Paulsen, J. M.; Mueller-Neuhaus, J. R.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 147, Issue 2 https://doi.org/10.1149/1.1393225	journal	January 2000
Structural transformation of sputtered o-LiMnO2 thin-film cathodes induced by electrochemical cycling Fischer, J.; Chang, K.; Ye, J. Thin Solid Films, Vol. 549 https://doi.org/10.1016/j.tsf.2013.08.095	journal	December 2013
Optimizing Areal Capacities through Understanding the Limitations of Lithium-Ion Electrodes Gallagher, Kevin G.; Trask, Stephen E.; Bauer, Christoph Journal of The Electrochemical Society, Vol. 163, Issue 2 https://doi.org/10.1149/2.0321602jes	journal	November 2015
First-Principles Evidence for Stage Ordering in Li[sub x]CoO[sub 2] Van der Ven, Anton Journal of The Electrochemical Society, Vol. 145, Issue 6 https://doi.org/10.1149/1.1838610	journal	January 1998
Thermodynamic rationalization of molten-salt clectrodeposition in oxide-based systems Crouch-Baker, S.; Huggins, R. A. Journal of Materials Research, Vol. 4, Issue 6 https://doi.org/10.1557/JMR.1989.1495	journal	December 1989
The formation of LiCoO2 on a NiO cathode for a molten carbonate fuel cell using electroplating Kuk, Seung Taek; Song, Young Seck; Suh, SungIll Journal of Materials Chemistry, Vol. 11, Issue 2 https://doi.org/10.1039/b003972l	journal	January 2001
Microstructural investigation of LixNi1/3Mn1/3Co1/3O2 (x ≤ 1) and its aged products via magnetic and diffraction study Mohanty, D.; Gabrisch, H. Journal of Power Sources, Vol. 220 https://doi.org/10.1016/j.jpowsour.2012.08.005	journal	December 2012
Thermodynamic determining factors of the positive electrode potential of lithium batteries Yokokawa, H. Solid State Ionics, Vol. 113-115, Issue 1-2 https://doi.org/10.1016/S0167-2738(98)00358-0	journal	December 1998
Flexible graphene-based lithium ion batteries with ultrafast charge and discharge rates Li, N.; Chen, Z.; Ren, W. Proceedings of the National Academy of Sciences, Vol. 109, Issue 43 https://doi.org/10.1073/pnas.1210072109	journal	October 2012
A High Areal Capacity Flexible Lithium-Ion Battery with a Strain-Compliant Design Gaikwad, Abhinav M.; Khau, Brian V.; Davies, Greg Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201401389	journal	September 2014
Direct Electroplating of Lithium Cobalt Oxide Film on Platinum Substrate in 100o-200oC Aqueous Solution Han, Kyoo-Seung; Song, Seung-Wan; Fujita, Hirofumi Journal of the American Ceramic Society, Vol. 85, Issue 10 https://doi.org/10.1111/j.1151-2916.2002.tb00478.x	journal	October 2002
Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C Gummow, R. J.; Thackeray, M. M.; David, W. I. F. Materials Research Bulletin, Vol. 27, Issue 3, p. 327-337 https://doi.org/10.1016/0025-5408(92)90062-5	journal	March 1992
Flexible Energy-Storage Devices: Design Consideration and Recent Progress Wang, Xianfu; Lu, Xihong; Liu, Bin Advanced Materials, Vol. 26, Issue 28 https://doi.org/10.1002/adma.201400910	journal	June 2014
Elastic and Wearable Wire-Shaped Lithium-Ion Battery with High Electrochemical Performance Ren, Jing; Zhang, Ye; Bai, Wenyu Angewandte Chemie International Edition, Vol. 53, Issue 30 https://doi.org/10.1002/anie.201402388	journal	June 2014
Encapsulating Sn _x Sb Nanoparticles in Multichannel Graphene-Carbon Fibers As Flexible Anodes to Store Lithium Ions with High Capacities Tang, Xuan; Yan, Feilong; Wei, Yuehua ACS Applied Materials & Interfaces, Vol. 7, Issue 39 https://doi.org/10.1021/acsami.5b06377	journal	September 2015
Three-dimensional graphene/LiFePO4 nanostructures as cathode materials for flexible lithium-ion batteries Ding, Y. H.; Ren, H. M.; Huang, Y. Y. Materials Research Bulletin, Vol. 48, Issue 10 https://doi.org/10.1016/j.materresbull.2013.05.118	journal	October 2013
Structural and Electrochemical Properties of LiAl[sub y]Co[sub 1−y]O[sub 2] Cathode for Li Rechargeable Batteries Yoon, Won-Sub; Lee, Kyung-Keun; Kim, Kwang-Bum Journal of The Electrochemical Society, Vol. 147, Issue 6 https://doi.org/10.1149/1.1393479	journal	January 2000
Scanning Electron Nanodiffraction and Diffraction Imaging Zuo, Jian -Min; Tao, Jing Scanning Transmission Electron Microscopy https://doi.org/10.1007/978-1-4419-7200-2_9	book	December 2010
LiAl[sub y]Co[sub 1−y]O[sub 2] (R3m) Intercalation Cathode for Rechargeable Lithium Batteries Jang, Young-Il Journal of The Electrochemical Society, Vol. 146, Issue 3 https://doi.org/10.1149/1.1391693	journal	January 1999
High-performance flexible energy storage and harvesting system for wearable electronics Ostfeld, Aminy E.; Gaikwad, Abhinav M.; Khan, Yasser Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep26122	journal	May 2016
Reversible oxygen electrode systems in molten salts Zambonin, Pier Giorgio Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 33, Issue 2 https://doi.org/10.1016/S0022-0728(71)80114-6	journal	December 1971
Phase stability of Li–Mn–O oxides as cathode materials for Li-ion batteries: insights from ab initio calculations Longo, R. C.; Kong, F. T.; Kc, Santosh Phys. Chem. Chem. Phys., Vol. 16, Issue 23 https://doi.org/10.1039/c4cp00937a	journal	January 2014
The standard Gibbs free energy of formation of lithium manganese oxides at the temperatures of (680, 740 and 800) K Róg, G.; Kucza, W.; Kozłowska-Róg, A. The Journal of Chemical Thermodynamics, Vol. 36, Issue 6 https://doi.org/10.1016/j.jct.2004.02.009	journal	June 2004
Three-dimensional electrodes and battery architectures Arthur, Timothy S.; Bates, Daniel J.; Cirigliano, Nicolas MRS Bulletin, Vol. 36, Issue 7 https://doi.org/10.1557/mrs.2011.156	journal	July 2011
Density Functional Investigation on Li ₂ MnO ₃ Xiao, Ruijuan; Li, Hong; Chen, Liquan Chemistry of Materials, Vol. 24, Issue 21 https://doi.org/10.1021/cm3027219	journal	October 2012
New Insight into the Atomic Structure of Electrochemically Delithiated O3-Li _{(1– x )} CoO ₂ (0 ≤ x ≤ 0.5) Nanoparticles Lu, Xia; Sun, Yang; Jian, Zelang Nano Letters, Vol. 12, Issue 12 https://doi.org/10.1021/nl303036e	journal	February 2012
Controlled electrochemical deposition and transformation of hetero-nanoarchitectured electrodes for energy storage Duay, Jonathon; Gillette, Eleanor; Hu, Junkai Physical Chemistry Chemical Physics, Vol. 15, Issue 21 https://doi.org/10.1039/c3cp50724f	journal	January 2013
Experimental and First-Principles Thermodynamic Study of the Formation and Effects of Vacancies in Layered Lithium Nickel Cobalt Oxides Kim, Yongseon; Kim, Doyu; Kang, Shinhoo Chemistry of Materials, Vol. 23, Issue 24 https://doi.org/10.1021/cm202415x	journal	December 2011
Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions Maiyalagan, Thandavarayan; Jarvis, Karalee A.; Therese, Soosairaj Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4949	journal	May 2014
Relationships among Electrochemical, Thermodynamic, and Oxygen Potential Quantities in Lithium-Transition Metal-Oxygen Molten Salt Cells Godshall, N. A. Journal of The Electrochemical Society, Vol. 131, Issue 3 https://doi.org/10.1149/1.2115624	journal	January 1984
Raman Microspectrometry Applied to the Study of Electrode Materials for Lithium Batteries Baddour-Hadjean, Rita; Pereira-Ramos, Jean-Pierre Chemical Reviews, Vol. 110, Issue 3 https://doi.org/10.1021/cr800344k	journal	March 2010
New insight in the behaviour of Co–H2O system at 25–150°C, based on revised Pourbaix diagrams Chivot, J.; Mendoza, L.; Mansour, C. Corrosion Science, Vol. 50, Issue 1 https://doi.org/10.1016/j.corsci.2007.07.002	journal	January 2008
Room-temperature synthesis of crystallized LiCoO2 thin films by electrochemical technique Gao, Daojiang; Li, Yanhong; Lai, Xin Journal of Alloys and Compounds, Vol. 509, Issue 3 https://doi.org/10.1016/j.jallcom.2010.06.167	journal	January 2011
A transmission electron microscopy study of cycled LiCoO2 Gabrisch, H.; Yazami, R.; Fultz, B. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00234-9	journal	June 2003
Photochemical versus Thermal Synthesis of Cobalt Oxyhydroxide Nanocrystals Alvarado, Samuel R.; Guo, Yijun; Ruberu, T. Purnima A. The Journal of Physical Chemistry C, Vol. 116, Issue 18 https://doi.org/10.1021/jp301459s	journal	April 2012
Solid-State CO[sub 2] Sensor with Li[sub 2]CO[sub 3]-Li[sub 3]PO[sub 4]-LiAlO[sub 2] Electrolyte and LiCoO[sub 2]-Co[sub 3]O[sub 4] as Solid Reference Electrode Zhang, Yi Can Journal of The Electrochemical Society, Vol. 144, Issue 12 https://doi.org/10.1149/1.1838190	journal	January 1997
Preparation of nanocrystalline LiMn2O4 thin film by electrodeposition method and its electrochemical performance for lithium battery Quan, Zhen; Ohguchi, Shouya; Kawase, Masayasu Journal of Power Sources, Vol. 244 https://doi.org/10.1016/j.jpowsour.2012.12.087	journal	December 2013
One step synthesis of lamellar R-3m LiCoO2 thin films by an electrochemical–hydrothermal method Porthault, H.; Le Cras, F.; Baddour-Hadjean, R. Electrochimica Acta, Vol. 56, Issue 22 https://doi.org/10.1016/j.electacta.2011.06.083	journal	September 2011
X-ray Diffraction Characterization and Battery Performances of Fiber-type Li-Mn-O Electrode for Li-ion Battery Yao, Jinhan; Takasaki, Tomoaki; Nishimura, Kazuya Electrochemistry, Vol. 82, Issue 2 https://doi.org/10.5796/electrochemistry.82.109	journal	January 2014
Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions Maiyalagan, T. figshare https://doi.org/10.6084/m9.figshare.1291626.v1	dataset	January 2015
Identification of cathode materials for lithium batteries guided by first-principles calculations Ceder, G.; Chiang, Y. -M.; Sadoway, D. R. Nature, Vol. 392, Issue 6677 https://doi.org/10.1038/33647	journal	April 1998
Large-Area Polyimide/SWCNT Nanocable Cathode for Flexible Lithium-Ion Batteries Wu, Haiping; Meng, Qinghai; Yang, Qian Advanced Materials, Vol. 27, Issue 41 https://doi.org/10.1002/adma.201502241	journal	September 2015
Crystal structure studies of thermally aged LiCoO2 and LiMn2O4 cathodes Gabrisch, Heike; Ozawa, Yasunori; Yazami, Rachid Electrochimica Acta, Vol. 52, Issue 4 https://doi.org/10.1016/j.electacta.2006.02.050	journal	December 2006
Elegant design of electrode and electrode/electrolyte interface in lithium-ion batteries by atomic layer deposition Liu, Jian; Sun, Xueliang Nanotechnology, Vol. 26, Issue 2 https://doi.org/10.1088/0957-4484/26/2/024001	journal	December 2014
Electrodeposition of Crystalline Co ₃ O ₄ —A Catalyst for the Oxygen Evolution Reaction Koza, Jakub A.; He, Zhen; Miller, Andrew S. Chemistry of Materials, Vol. 24, Issue 18 https://doi.org/10.1021/cm3012205	journal	September 2012
Studies on oxygen reduction in molten NaOH Hayashi, Hidetaka; Yoshizawa, Shiro; Ito, Yasuhiko Electrochimica Acta, Vol. 28, Issue 2 https://doi.org/10.1016/0013-4686(83)85101-9	journal	February 1983
Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes Zhang, Huigang; Yu, Xindi; Braun, Paul V. Nature Nanotechnology, Vol. 6, Issue 5, p. 277-281 https://doi.org/10.1038/nnano.2011.38	journal	March 2011
Thick Electrodes for High Energy Lithium Ion Batteries Singh, Madhav; Kaiser, Jörg; Hahn, Horst Journal of The Electrochemical Society, Vol. 162, Issue 7 https://doi.org/10.1149/2.0401507jes	journal	January 2015
Designed Construction of a Graphene and Iron Oxide Freestanding Electrode with Enhanced Flexible Energy-Storage Performance Li, Meng; Pan, Feng; Choo, Eugene Shi Guang ACS Applied Materials & Interfaces, Vol. 8, Issue 11 https://doi.org/10.1021/acsami.5b10853	journal	March 2016
Flexible High-Energy Li-Ion Batteries with Fast-Charging Capability Park, Mi-Hee; Noh, Mijung; Lee, Sanghan Nano Letters, Vol. 14, Issue 7 https://doi.org/10.1021/nl501597s	journal	June 2014
LiMO₂ (M=Mn, Fe, and Co): Energetics, polymorphism and phase transformation Wang, Miaojun; Navrotsky, Alexandra Journal of Solid State Chemistry, Vol. 178, Issue 4, p. 1230-1240 https://doi.org/10.1016/j.jssc.2005.01.028	journal	April 2005
Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C Gummow, R. J.; Liles, D. C.; Thackeray, M. M. Materials Research Bulletin, Vol. 28, Issue 3, p. 235-246 https://doi.org/10.1016/0025-5408(93)90157-9	journal	March 1993
Effects of Al doping on the microstructure of LiCoO2 cathode materials Myung, S. Solid State Ionics, Vol. 139, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00828-6	journal	January 2001
Effects of heat-treatment on the spectroscopic and electrochemical properties of a mixed manganese/vanadium oxide film prepared by electrodeposition Nakayama, Masaharu; Tanaka, Akihiro; Konishi, Sayaka Journal of Materials Research, Vol. 19, Issue 5 https://doi.org/10.1557/JMR.2004.0202	journal	May 2004
Atomic Layer Electrodeposition Switzer, J. A. Science, Vol. 338, Issue 6112 https://doi.org/10.1126/science.1231853	journal	December 2012
Progress in flexible lithium batteries and future prospects Zhou, Guangmin; Li, Feng; Cheng, Hui-Ming Energy Environ. Sci., Vol. 7, Issue 4 https://doi.org/10.1039/C3EE43182G	journal	January 2014
Cyclic performances of HT-LiCo0.8M0.2O2 (M=Al, Ni) powders prepared by the molten salt synthesis method Han, C. Solid State Ionics, Vol. 159, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00886-X	journal	April 2003
Holographic patterning of high-performance on-chip 3D lithium-ion microbatteries Ning, Hailong; Pikul, James H.; Zhang, Runyu Proceedings of the National Academy of Sciences, Vol. 112, Issue 21 https://doi.org/10.1073/pnas.1423889112	journal	May 2015
TEM Study of Electrochemical Cycling-Induced Damage and Disorder in LiCoO[sub 2] Cathodes for Rechargeable Lithium Batteries Wang, Haifeng Journal of The Electrochemical Society, Vol. 146, Issue 2 https://doi.org/10.1149/1.1391631	journal	January 1999
Electrochemical studies on molten sodium hydroxide Hayashi, Hidetaka; Yoshizawa, Shiro; Ito, Yasuhiko Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 124, Issue 1-2 https://doi.org/10.1016/S0022-0728(81)80300-2	journal	July 1981
A First-Principles Approach to Studying the Thermal Stability of Oxide Cathode Materials Wang, L.; Maxisch, T.; Ceder, G. Chemistry of Materials, Vol. 19, Issue 3 https://doi.org/10.1021/cm0620943	journal	February 2007
Fabrication of LiCoO2 films for lithium rechargeable microbattery in an aqueous solution by electrochemical reflux method Lee, Jin-Ho; Han, Kyoo-Seung; Lee, Bum-Jae Electrochimica Acta, Vol. 50, Issue 2-3 https://doi.org/10.1016/j.electacta.2004.04.049	journal	November 2004
Electrochemical Synthesis of Metal Oxides and Hydroxides Therese, G. Helen Annal; Kamath, P. Vishnu Chemistry of Materials, Vol. 12, Issue 5 https://doi.org/10.1021/cm990447a	journal	May 2000
MATERIALS SCIENCE: Toward Flexible Batteries Nishide, H.; Oyaizu, K. Science, Vol. 319, Issue 5864 https://doi.org/10.1126/science.1151831	journal	February 2008
Flexible rechargeable lithium ion batteries: advances and challenges in materials and process technologies Hu, Yuhai; Sun, Xueliang J. Mater. Chem. A, Vol. 2, Issue 28 https://doi.org/10.1039/C4TA00716F	journal	January 2014
Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions Maiyalagan, T. figshare https://doi.org/10.6084/m9.figshare.1291626	dataset	January 2015
Self-Terminating Growth of Platinum Films by Electrochemical Deposition Liu, Y.; Gokcen, D.; Bertocci, U. Science, Vol. 338, Issue 6112 https://doi.org/10.1126/science.1228925	journal	December 2012

Cited By (11)

Three-dimensional ordered porous electrode materials for electrochemical energy storage Liu, Zaichun; Yuan, Xinhai; Zhang, Shuaishuai NPG Asia Materials, Vol. 11, Issue 1 https://doi.org/10.1038/s41427-019-0112-3	journal	March 2019
Facile synthesis of CuO nanochains as high-rate anode materials for lithium-ion batteries Wang, Ping; Gou, Xiao-Xia; Xin, Sen New Journal of Chemistry, Vol. 43, Issue 17 https://doi.org/10.1039/c9nj01015g	journal	January 2019
One-step electrodeposition of cerium-doped nickel hydroxide nanosheets for effective oxygen generation Fang, Gang; Cai, Jinhua; Huang, Zhipeng RSC Advances, Vol. 9, Issue 31 https://doi.org/10.1039/c9ra02682g	journal	January 2019
A green electrochemical transformation of inferior coals to crystalline graphite for stable Li-ion storage Zhu, Zhenglu; Zuo, Haibin; Li, Shijie Journal of Materials Chemistry A, Vol. 7, Issue 13 https://doi.org/10.1039/c8ta12412d	journal	January 2019
Li-Rich Li[Li _1/6 Fe _1/6 Ni _1/6 Mn _1/2 ]O ₂ (LFNMO) Cathodes: Atomic Scale Insight on the Mechanisms of Cycling Decay and of the Improvement due to Cobalt Phosphate Surface Modification Li, Xing; Zhang, Kangjia; Mitlin, David Small, Vol. 14, Issue 40 https://doi.org/10.1002/smll.201802570	journal	September 2018
Electrodeposition Technologies for Li‐Based Batteries: New Frontiers of Energy Storage Pu, Jun; Shen, Zihan; Zhong, Chenglin Advanced Materials https://doi.org/10.1002/adma.201903808	journal	September 2019
Rational design and kinetics study of flexible sodium-ion full batteries based on binder-free composite film electrodes Zhang, Keliang; Zhang, Xudong; He, Wen Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta01026b	journal	January 2019
Strategies for Building Robust Traffic Networks in Advanced Energy Storage Devices: A Focus on Composite Electrodes Wang, Yu; Fu, Xuewei; Zheng, Min Advanced Materials https://doi.org/10.1002/adma.201804204	journal	December 2018
Free-standing transition metal oxide electrode architectures for electrochemical energy storage Spencer, Michael A.; Augustyn, Veronica Journal of Materials Science, Vol. 54, Issue 20 https://doi.org/10.1007/s10853-019-03823-y	journal	July 2019
Toward a quantitative theoretical method for infrared and Raman spectroscopic studies on single-crystal electrode/liquid interfaces Fang, Yuan; Dong, Jin-Chao; Ding, Song-Yuan Chemical Science, Vol. 11, Issue 5 https://doi.org/10.1039/c9sc05429d	journal	January 2020
Co ₃ O ₄ @Co/NCNT Nanostructure Derived from a Dicyanamide-Based Metal-Organic Framework as an Efficient Bi-functional Electrocatalyst for Oxygen Reduction and Evolution Reactions Sikdar, Nivedita; Konkena, Bharathi; Masa, Justus Chemistry - A European Journal, Vol. 23, Issue 71 https://doi.org/10.1002/chem.201704211	journal	November 2017

Similar Records

In Situ X-ray Diffraction Studies of Cathode Materials in Lithium Batteries

Conference · Sun Nov 01 00:00:00 EST 1998 · OSTI ID:1466779

Yang, X Q; Sun, X; McBreen, J; +5 more

Characterization of Cathode Materials for Rechargeable Lithium Batteries using Synchrotron Based In Situ X-ray Techniques

Technical Report · Wed May 23 00:00:00 EDT 2007 · OSTI ID:1466779

Yang, Xiao-Qing; Furey, Michael

Lithium and transition metal dissolution due to aqueous processing in lithium-ion battery cathode active materials

Journal Article · Fri May 08 00:00:00 EDT 2020 · Journal of Power Sources · OSTI ID:1466779

Hawley, William Blake; Parejiya, Anand Vasudevbhai; Bai, Yaocai; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
electroplating
lithium transition metal oxides
lithium ion batteries
flexible batteries
cathode

Title: Electroplating lithium transition metal oxides

Citation Formats

References (82)

Cited By (11)

Similar Records

Related Subjects