Calendar and Cycle Life of Lithium-Ion Batteries Containing Silicon Monoxide Anode

Lu, Wenquan; Zhang, Linghong; Qin, Yan; Jansen, Andrew

doi:10.1149/2.0631810jes

Calendar and Cycle Life of Lithium-Ion Batteries Containing Silicon Monoxide Anode

Journal Article · Mon Jan 01 04:00:00 EST 2018 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0631810jes· OSTI ID:1466680

; ; Qin, Yan;

The capacity fading phenomenon of high energy lithium-ion batteries (LIBs) using a silicon monoxide (SiO) anode and a nickel-rich transition metal oxide cathode were investigated during life test. The capacity loss of this electrode couple was found to increase not only with cycles (cycle life), but also with rest time (calendar life). The capacity fading rate for this type of LIB using SiO as the anode is found to be time-dependent, rather than cycle-count-dependent. Further detailed investigation reveals that the capacity loss of this electrode couple during rest was caused by the parasitic reactions on the anode, which consumed the lithium ions and lead to less cyclable lithium in the battery system.

Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technology

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1466680

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 10 Vol. 165; ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

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