Dry reforming of methane over CeO2-supported Pt-Co catalysts with enhanced activity

Xie, Zhenhua; Yan, Binhang; Kattel, Shyam; Lee, Ji Hoon; Yao, Siyu; Wu, Qiyuan; Rui, Ning; Gomez, Elaine; Liu, Zongyuan; Xu, Wenqian; Zhang, Li; Chen, Jingguang G.

doi:10.1016/j.apcatb.2018.05.035

Title: Dry reforming of methane over CeO₂-supported Pt-Co catalysts with enhanced activity

Journal Article · Sat May 12 00:00:00 EDT 2018 · Applied Catalysis. B, Environmental

DOI:https://doi.org/10.1016/j.apcatb.2018.05.035· OSTI ID:1466584

Xie, Zhenhua ^[1]; Yan, Binhang ^[2]; Kattel, Shyam ^[3]; Lee, Ji Hoon ^[4]; Yao, Siyu ^[3]; Wu, Qiyuan ^[5]; Rui, Ning ^[3]; Gomez, Elaine ^[4]; Liu, Zongyuan ^[3]; Xu, Wenqian ^[6]; Zhang, Li ^[7]; Chen, Jingguang G. ^[8]

Chongqing Univ., Chongqing (China). College of Power Engineering; Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Tsinghua Univ., Beijing (China). Dept. of Chemical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry
Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering
Stony Brook Univ., NY (United States). Material Science and Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS). X-ray Science Division
Chongqing Univ., Chongqing (China). College of Power Engineering
Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry

Dry reforming of methane provides opportunities of using CH4 and CO2 to produce syngas. The PtCo/CeO2 bimetallic catalyst shows higher activity and H-2/CO ratio than the corresponding monometallic catalysts, mainly attributed to the synergistic effect of Pt-Co. Structural feature of the PtCo/CeO2 catalyst was revealed by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) of adsorbed CO and in situ techniques like X-ray diffraction (XRD), X-ray adsorption fine structure (XAFS) and ambient-pressure X-ray photoelectron spectroscopy (AP-XPS). Pt-Co alloy and separated Co particles co-existed in the bimetallic catalyst, whereas the former was determined as the dominant active structure with a Pt-Co-mixed-surface termination. During reaction, Pt and Co in the alloy structure nearly maintained their metallic state with slight oxygen decoration, yielding oxygen-metal site-pairs (O*-*). Combined kinetic investigations and DFT calculations reveal that the O*-modified catalytic surface of PtCo/CeO2 promotes C-H bond activation with higher entropy contribution (less constraints) to compensate its higher activation barrier. Thermogravimetric analysis (TGA), transmission electron microscope (TEM) and Raman spectroscopy show that the PtCo/CeO2 catalyst is resistant to coke formation as effectively as Pt/CeO2 and can be easily regenerated by a mild CO2 treatment.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: SC0012704; AC02-06CH11357; AC02-05CH11231; 16-045; 21673125

OSTI ID:: 1466584

Alternate ID(s):: OSTI ID: 1481171; OSTI ID: 1591652

Report Number(s):: BNL-207986-2018-JAAM

Journal Information:: Applied Catalysis. B, Environmental, Vol. 236, Issue C; ISSN 0926-3373

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 88 works

Citation information provided by
Web of Science

References (67)

An Introduction of CO ₂ Conversion by Dry Reforming with Methane and New Route of Low-Temperature Methanol Synthesis Shi, Lei; Yang, Guohui; Tao, Kai Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300217j	journal	March 2013
Dry Reforming of Methane Using a Solar-Thermal Aerosol Flow Reactor Dahl, Jaimee K.; Weimer, Alan W.; Lewandowski, Allan Industrial & Engineering Chemistry Research, Vol. 43, Issue 18 https://doi.org/10.1021/ie030307h	journal	October 2003
A review of dry (CO ₂ ) reforming of methane over noble metal catalysts Pakhare, Devendra; Spivey, James Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60395D	journal	January 2014
CO2-Reforming of Methane over Transition Metals Rostrupnielsen, J. R.; Hansen, J. H. B. Journal of Catalysis, Vol. 144, Issue 1 https://doi.org/10.1006/jcat.1993.1312	journal	November 1993
Study of mixed steam and CO2 reforming of CH4 to syngas on MgO-supported metals Qin, D.; Lapszewicz, J. Catalysis Today, Vol. 21, Issue 2-3 https://doi.org/10.1016/0920-5861(94)80179-7	journal	December 1994
The effect of CeO2 structure on the activity of supported Pd catalysts used for methane steam reforming Craciun, Radu; Daniell, Wayne; Knözinger, Helmut Applied Catalysis A: General, Vol. 230, Issue 1-2 https://doi.org/10.1016/S0926-860X(01)01003-1	journal	April 2002
Isotopic and kinetic assessment of the mechanism of methane reforming and decomposition reactions on supported iridium catalysts Wei, Junmei; Iglesia, Enrique Physical Chemistry Chemical Physics, Vol. 6, Issue 13 https://doi.org/10.1039/b400934g	journal	January 2004
Structural and Mechanistic Requirements for Methane Activation and Chemical Conversion on Supported Iridium Clusters Wei, Junmei; Iglesia, Enrique Angewandte Chemie International Edition, Vol. 43, Issue 28 https://doi.org/10.1002/anie.200352703	journal	July 2004
Isotopic and kinetic assessment of the mechanism of reactions of CH4 with CO2 or H2O to form synthesis gas and carbon on nickel catalysts Wei, Junmei; Iglesia, Enrique Journal of Catalysis, Vol. 224, Issue 2 https://doi.org/10.1016/j.jcat.2004.02.032	journal	June 2004
Mechanism and Site Requirements for Activation and Chemical Conversion of Methane on Supported Pt Clusters and Turnover Rate Comparisons among Noble Metals Wei, Junmei; Iglesia, Enrique The Journal of Physical Chemistry B, Vol. 108, Issue 13 https://doi.org/10.1021/jp036985z	journal	April 2004
Catalytic activation and reforming of methane on supported palladium clusters Yamaguchi, Aritomo; Iglesia, Enrique Journal of Catalysis, Vol. 274, Issue 1 https://doi.org/10.1016/j.jcat.2010.06.001	journal	August 2010
First principles calculations and experimental insight into methane steam reforming over transition metal catalysts Jones, G.; Jakobsen, J.; Shim, S. Journal of Catalysis, Vol. 259, Issue 1 https://doi.org/10.1016/j.jcat.2008.08.003	journal	October 2008
Consequences of Surface Oxophilicity of Ni, Ni-Co, and Co Clusters on Methane Activation Tu, Weifeng; Ghoussoub, Mireille; Singh, Chandra Veer Journal of the American Chemical Society, Vol. 139, Issue 20 https://doi.org/10.1021/jacs.7b01632	journal	May 2017
Progresses in the Preparation of Coke Resistant Ni-based Catalyst for Steam and CO2 Reforming of Methane Liu, Chang-jun; Ye, Jingyun; Jiang, Jiaojun ChemCatChem, Vol. 3, Issue 3 https://doi.org/10.1002/cctc.201000358	journal	February 2011
Dry Reforming of Methane Over Cobalt Catalysts: A Literature Review of Catalyst Development Budiman, Anatta Wahyu; Song, Sang-Hoon; Chang, Tae-Sun Catalysis Surveys from Asia, Vol. 16, Issue 4 https://doi.org/10.1007/s10563-012-9143-2	journal	September 2012
Carbon Deposition and Catalytic Deactivation during CO2 Reforming of CH4 over Co/γ-Al2O3 Catalysts Ruckenstein, E.; Wang, H. Y. Journal of Catalysis, Vol. 205, Issue 2 https://doi.org/10.1006/jcat.2001.3458	journal	January 2002
Influence of the reduction temperature on catalytic activity of Co/TiO2 (anatase-type) for high pressure dry reforming of methane Nagaoka, K. Applied Catalysis A: General, Vol. 255, Issue 1 https://doi.org/10.1016/S0926-860X(03)00631-8	journal	November 2003
Effect of preparation methods on the performance of Co/Al ₂ O ₃ catalysts for dry reforming of methane Ewbank, Jessica L.; Kovarik, Libor; Kenvin, Christian C. Green Chem., Vol. 16, Issue 2 https://doi.org/10.1039/C3GC41782D	journal	January 2014
Modification of Co/TiO2 for dry reforming of methane at 2MPa by Pt, Ru or Ni Nagaoka, K. Applied Catalysis A: General, Vol. 268, Issue 1-2 https://doi.org/10.1016/j.apcata.2004.03.029	journal	August 2004
Reforming and oxidative dehydrogenation of ethane with CO2 as a soft oxidant over bimetallic catalysts Myint, MyatNoeZin; Yan, Binhang; Wan, Jie Journal of Catalysis, Vol. 343 https://doi.org/10.1016/j.jcat.2016.02.004	journal	November 2016
Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts Yu, Weiting; Porosoff, Marc D.; Chen, Jingguang G. Chemical Reviews, Vol. 112, Issue 11, p. 5780-5817 https://doi.org/10.1021/cr300096b	journal	August 2012
Catalytic behavior of supported Ru nanoparticles on the {1 0 0}, {1 1 0}, and {1 1 1} facet of CeO2 Wang, Fei; Li, Changming; Zhang, Xiaoyu Journal of Catalysis, Vol. 329 https://doi.org/10.1016/j.jcat.2015.05.014	journal	September 2015
Reaction Pathways and Site Requirements for the Activation and Chemical Conversion of Methane on Ru−Based Catalysts Wei, Junmei; Iglesia, Enrique The Journal of Physical Chemistry B, Vol. 108, Issue 22 https://doi.org/10.1021/jp030783l	journal	June 2004
Structural requirements and reaction pathways in methane activation and chemical conversion catalyzed by rhodium Wei, J. Journal of Catalysis, Vol. 225, Issue 1 https://doi.org/10.1016/j.jcat.2003.09.030	journal	July 2004
Density Functional Theory-Assisted Microkinetic Analysis of Methane Dry Reforming on Ni Catalyst Fan, Chen; Zhu, Yi-An; Yang, Ming-Lei Industrial & Engineering Chemistry Research, Vol. 54, Issue 22 https://doi.org/10.1021/acs.iecr.5b00563	journal	May 2015
Correlating extent of Pt–Ni bond formation with low-temperature hydrogenation of benzene and 1,3-butadiene over supported Pt/Ni bimetallic catalysts Lonergan, William W.; Vlachos, Dionisios G.; Chen, Jingguang G. Journal of Catalysis, Vol. 271, Issue 2 https://doi.org/10.1016/j.jcat.2010.01.019	journal	May 2010
Selection of oxide supports to anchor desirable bimetallic structures for ethanol reforming and 1,3-butadiene hydrogenation Wang, Tiefeng; Lonergan, William; Chen, Jingguang G. Chinese Journal of Catalysis, Vol. 34, Issue 11 https://doi.org/10.1016/S1872-2067(12)60715-3	journal	November 2013
Temperature-programmed Studies of Coke Resistant Ni Catalyst for Carbon Dioxide Reforming of Methane Pan, Yun-Xiang; Liu, Chang-Jun; Cui, Lan Catalysis Letters, Vol. 123, Issue 1-2 https://doi.org/10.1007/s10562-008-9400-1	journal	January 2008
Dry Reforming of Ethane and Butane with CO ₂ over PtNi/CeO ₂ Bimetallic Catalysts Yan, Binhang; Yang, Xiaofang; Yao, Siyu ACS Catalysis, Vol. 6, Issue 11 https://doi.org/10.1021/acscatal.6b02176	journal	September 2016
A versatile sample-environment cell for non-ambient X-ray scattering experiments Chupas, Peter J.; Chapman, Karena W.; Kurtz, Charles Journal of Applied Crystallography, Vol. 41, Issue 4 https://doi.org/10.1107/S0021889808020165	journal	July 2008
In situ studies of CeO2-supported Pt, Ru, and Pt–Ru alloy catalysts for the water–gas shift reaction: Active phases and reaction intermediates Xu, Wenqian; Si, Rui; Senanayake, Sanjaya D. Journal of Catalysis, Vol. 291 https://doi.org/10.1016/j.jcat.2012.04.013	journal	July 2012
Two-dimensional detector software: From real detector to idealised image or two-theta scan Hammersley, A. P.; Svensson, S. O.; Hanfland, M. High Pressure Research, Vol. 14, Issue 4-6, p. 235-248 https://doi.org/10.1080/08957959608201408	journal	January 1996
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Comparison of Methodologies of Activation Barrier Measurements for Reactions with Deactivation Xie, Zhenhua; Yan, Binhang; Zhang, Li Industrial & Engineering Chemistry Research, Vol. 56, Issue 5 https://doi.org/10.1021/acs.iecr.6b04626	journal	January 2017
Self-Consistent Equations Including Exchange and Correlation Effects Kohn, W.; Sham, L. J. Physical Review, Vol. 140, Issue 4A, p. A1133-A1138 https://doi.org/10.1103/PhysRev.140.A1133	journal	November 1965
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
A climbing image nudged elastic band method for finding saddle points and minimum energy paths Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904 https://doi.org/10.1063/1.1329672	journal	December 2000
In Situ Elucidation of the Active State of Co–CeO _x Catalysts in the Dry Reforming of Methane: The Important Role of the Reducible Oxide Support and Interactions with Cobalt Zhang, Feng; Liu, Zongyuan; Zhang, Shuhao ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.7b03640	journal	March 2018
Chemical shifts of Auger lines, and the Auger parameter Wagner, C. D. Faraday Discussions of the Chemical Society, Vol. 60 https://doi.org/10.1039/dc9756000291	journal	January 1975
Low temperature water–gas shift: in situ DRIFTS-reaction study of ceria surface area on the evolution of formates on Pt/CeO2 fuel processing catalysts for fuel cell applications Jacobs, G. Applied Catalysis A: General, Vol. 252, Issue 1 https://doi.org/10.1016/S0926-860X(03)00410-1	journal	October 2003
Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, part I: Oxidation state and surface species on Pt/CeO2 under reaction conditions Pozdnyakova, O.; Teschner, D.; Wootsch, A. Journal of Catalysis, Vol. 237, Issue 1 https://doi.org/10.1016/j.jcat.2005.10.014	journal	January 2006
Infrared studies of CO adsorbed on supported Pt$z.sbnd;Co catalysts Dees, M. Journal of Catalysis, Vol. 124, Issue 2 https://doi.org/10.1016/0021-9517(90)90199-T	journal	August 1990
FT-IR study of CO adsorption on Pt/CeO2: characterisation and structural rearrangement of small Pt particles Bazin, P.; Saur, O.; Lavalley, J. C. Physical Chemistry Chemical Physics, Vol. 7, Issue 1 https://doi.org/10.1039/b414159h	journal	January 2005
Carbon monoxide and carbon dioxide adsorption on cerium oxide studied by Fourier-transform infrared spectroscopy. Part 1.—Formation of carbonate species on dehydroxylated CeO2, at room temperature Li, Can; Sakata, Yoshihisa; Arai, Toru Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 4 https://doi.org/10.1039/f19898500929	journal	January 1989
Influence of Dipole–Dipole Interactions on Coverage-Dependent Adsorption: CO and NO on Pt(111) Deshlahra, Prashant; Conway, Jonathan; Wolf, Eduardo E. Langmuir, Vol. 28, Issue 22 https://doi.org/10.1021/la300975s	journal	May 2012
Coverage‐dependent dipole coupling for carbon monoxide adsorbed at ordered platinum(111)‐aqueous interfaces: Structural and electrochemical implications Chang, Si‐Chung; Weaver, Michael J. The Journal of Chemical Physics, Vol. 92, Issue 7 https://doi.org/10.1063/1.457719	journal	April 1990
Ceria in automotive exhaust catalysts I. Oxygen storage Yao, H. Journal of Catalysis, Vol. 86, Issue 2 https://doi.org/10.1016/0021-9517(84)90371-3	journal	April 1984
Role of redox couples of Rh0/Rhδ+ and Ce4+/Ce3+ in CH4/CO2 reforming over Rh–CeO2/Al2O3 catalyst Wang, R.; Xu, H.; Liu, X. Applied Catalysis A: General, Vol. 305, Issue 2 https://doi.org/10.1016/j.apcata.2006.03.021	journal	May 2006
Infrared and x-ray photoelectron spectroscopy study of carbon monoxide and carbon dioxide on platinum/ceria Jin, T.; Zhou, Y.; Mains, G. J. The Journal of Physical Chemistry, Vol. 91, Issue 23 https://doi.org/10.1021/j100307a023	journal	November 1987
Catalytic steam reforming of ethane and propane over CeO2-doped Ni/Al2O3 at SOFC temperature: Improvement of resistance toward carbon formation by the redox property of doping CeO2 Laosiripojana, N.; Sangtongkitcharoen, W.; Assabumrungrat, S. Fuel, Vol. 85, Issue 3 https://doi.org/10.1016/j.fuel.2005.06.013	journal	February 2006
Ceria reoxidation by CO2: A model study Staudt, T.; Lykhach, Y.; Tsud, N. Journal of Catalysis, Vol. 275, Issue 1 https://doi.org/10.1016/j.jcat.2010.07.032	journal	September 2010
Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles Vayssilov, Georgi N.; Lykhach, Yaroslava; Migani, Annapaola Nature Materials, Vol. 10, Issue 4 https://doi.org/10.1038/nmat2976	journal	March 2011
Probing the interaction of Rh, Co and bimetallic Rh–Co nanoparticles with the CeO ₂ support: catalytic materials for alternative energy generation Varga, E.; Pusztai, P.; Óvári, L. Physical Chemistry Chemical Physics, Vol. 17, Issue 40 https://doi.org/10.1039/C5CP03549J	journal	January 2015
Increasing Oxide Reducibility: The Role of Metal/Oxide Interfaces in the Formation of Oxygen Vacancies Ruiz Puigdollers, Antonio; Schlexer, Philomena; Tosoni, Sergio ACS Catalysis, Vol. 7, Issue 10 https://doi.org/10.1021/acscatal.7b01913	journal	August 2017
Light-off curve of catalytic reaction and kinetics Duprat, Françoise Chemical Engineering Science, Vol. 57, Issue 6 https://doi.org/10.1016/S0009-2509(01)00409-2	journal	March 2002
Evaluating the characteristics of multiwall carbon nanotubes Lehman, John H.; Terrones, Mauricio; Mansfield, Elisabeth Carbon, Vol. 49, Issue 8 https://doi.org/10.1016/j.carbon.2011.03.028	journal	July 2011
Thermogravimetric Analysis of the Oxidation of Multiwalled Carbon Nanotubes: Evidence for the Role of Defect Sites in Carbon Nanotube Chemistry Bom, David; Andrews, Rodney; Jacques, David Nano Letters, Vol. 2, Issue 6 https://doi.org/10.1021/nl020297u	journal	June 2002
Effect of support on acetic acid decomposition over palladium catalysts Brijaldo, María H.; Rojas, Hugo A.; Martínez, José J. Journal of Catalysis, Vol. 331 https://doi.org/10.1016/j.jcat.2015.08.019	journal	November 2015
Temperature-dependent Raman spectra and anomalous Raman phenomenon of highly oriented pyrolytic graphite Tan, PingHeng; Deng, YuanMing; Zhao, Qian Physical Review B, Vol. 58, Issue 9 https://doi.org/10.1103/PhysRevB.58.5435	journal	September 1998
Raman spectroscopy of graphite and carbon materials and its recent application Katagiri, Gen Carbon, Vol. 35, Issue 5 https://doi.org/10.1016/S0008-6223(97)86653-5	journal	January 1997
Fundamentals, overtones, and combinations in the Raman spectrum of graphite Kawashima, Yasushi; Katagiri, Gen Physical Review B, Vol. 52, Issue 14 https://doi.org/10.1103/PhysRevB.52.10053	journal	October 1995
Resonantly enhanced Raman scattering and high-order Raman spectra of single-walled carbon nanotubes Tan, PingHeng; Tang, Yan; Deng, Yuan Ming Applied Physics Letters, Vol. 75, Issue 11 https://doi.org/10.1063/1.124743	journal	September 1999
Loss of single-walled carbon nanotubes selectivity by disruption of the Co–Mo interaction in the catalyst Herrera, José E.; Resasco, Daniel E. Journal of Catalysis, Vol. 221, Issue 2 https://doi.org/10.1016/j.jcat.2003.08.005	journal	January 2004
Catalyst deactivation Forzatti, P. Catalysis Today, Vol. 52, Issue 2-3 https://doi.org/10.1016/S0920-5861(99)00074-7	journal	September 1999
Direct Evidence of Water-Assisted Sintering of Cobalt on Carbon Nanofiber Catalysts during Simulated Fischer−Tropsch Conditions Revealed with in Situ Mössbauer Spectroscopy Bezemer, G. Leendert; Remans, Tom J.; van Bavel, Alexander P. Journal of the American Chemical Society, Vol. 132, Issue 25 https://doi.org/10.1021/ja103002k	journal	June 2010

Cited By (4)

Atomically dispersed nickel as coke-resistant active sites for methane dry reforming Akri, Mohcin; Zhao, Shu; Li, Xiaoyu Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12843-w	journal	November 2019
A highly efficient 2D siloxene coated Ni foam catalyst for methane dry reforming and an effective approach to recycle the spent catalyst for energy storage applications Krishnamoorthy, Karthikeyan; M. S. P., Sudhakaran; Pazhamalai, Parthiban Journal of Materials Chemistry A, Vol. 7, Issue 32 https://doi.org/10.1039/c9ta03584b	journal	January 2019
Influence of Solid Solution Formation on the Activity of CeO2 Supported Ni–Cu Mixed Oxide Catalysts in Dry Reforming of Methane Sagar, T. V.; Padmakar, D.; Lingaiah, N. Catalysis Letters, Vol. 149, Issue 9 https://doi.org/10.1007/s10562-019-02801-y	journal	May 2019
Carbon‐Coated and Interfacial‐Functionalized Mixed‐Phase Mo _x Ti _{1− x} O _2‐δ Nanotubes as Highly Active and Durable PtRu Catalyst Support for Methanol Electrooxidation Li, Jia‐Long; Zhao, Lei; Li, Xi‐Fei Chemistry – An Asian Journal, Vol. 14, Issue 9 https://doi.org/10.1002/asia.201900264	journal	March 2019

Similar Records

Dry Reforming of Ethane and Butane with CO₂ over PtNi/CeO₂ Bimetallic Catalysts

Journal Article · Wed Sep 21 00:00:00 EDT 2016 · ACS Catalysis · OSTI ID:1466584

Yan, Binhang; Yang, Xiaofang; Yao, Siyu; +7 more

Identification of a Pt₃Co Surface Intermetallic Alloy in Pt–Co Propane Dehydrogenation Catalysts

Journal Article · Wed Apr 24 00:00:00 EDT 2019 · ACS Catalysis · OSTI ID:1466584

Cesar, Laryssa Goncalves; Yang, Ce; Lu, Zheng; +3 more

Low Temperature Hydrogenation of Benzene and Cyclohexene: A Comparative Study Between gamma-Al2O3 Supported PtCo and PtNi Bimetallic Catalysts

Journal Article · Tue Jan 01 00:00:00 EST 2008 · Journal of Catalysis · OSTI ID:1466584

Lu, S; Lonergan, W; Bosco, J; +4 more

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
Dry reforming of methane (DRM)
Pt-Co
Kinetics
Density functional theory (DFT)
Regeneration
Density functional theory
Dry reforming of methane

Title: Dry reforming of methane over CeO2-supported Pt-Co catalysts with enhanced activity

Citation Formats

References (67)

Cited By (4)

Similar Records

Related Subjects

Title: Dry reforming of methane over CeO₂-supported Pt-Co catalysts with enhanced activity