Compact 3D Copper with Uniform Porous Structure Derived by Electrochemical Dealloying as Dendrite-Free Lithium Metal Anode Current Collector

Zhao, Heng; Lei, Danni; He, Yan -Bing; Yuan, Yifei; Yun, Qinbai; Ni, Bin; Lv, Wei; Li, Baohua; Yang, Quan -Hong; Kang, Feiyu; Lu, Jun

doi:10.1002/aenm.201800266

Title: Compact 3D Copper with Uniform Porous Structure Derived by Electrochemical Dealloying as Dendrite-Free Lithium Metal Anode Current Collector

Journal Article · Fri Mar 30 00:00:00 EDT 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201800266· OSTI ID:1466310

Zhao, Heng ^[1]; Lei, Danni ^[1]; He, Yan -Bing ^[2]; Yuan, Yifei ^[3]; Yun, Qinbai ^[4]; Ni, Bin ^[1]; Lv, Wei ^[2]; Li, Baohua ^[2]; Yang, Quan -Hong ^[5]; Kang, Feiyu ^[1];

^[3]

Tsinghua Univ., Shenzhen (People's Republic of China); Tsinghua Univ., Beijing (People's Republic of China)
Tsinghua Univ., Shenzhen (People's Republic of China)
Argonne National Lab. (ANL), Lemont, IL (United States)
Nanyang Technological Univ. (Singapore)
Tianjin Univ., Tianjin (People's Republic of China)

Here, the development of lithium (Li) metal anodes Li metal batteries faces huge challenges such as uncontrolled Li dendrite growth and large volume change during Li plating/stripping, resulting in severe capacity decay and high safety hazards. A 3D porous copper (Cu) current collector as a host for Li deposition can effectively settle these problems. However, constructing a uniform and compact 3D porous Cu structure is still an enormous challenge. Herein, an electrochemical etching method for Cu–Zinc (Zn) alloy is reported to precisely engrave a 3D Cu structure with uniform, smooth, and compact porous network. Such a continuous structure endows 3D Cu excellent mechanical properties and high electrical conductivity. The uniform and smooth pores with a large internal surface area ensures well dispersed current density for homogeneous Li metal deposition and accommodation. A smooth and stable solid electrolyte interphase is formed and meanwhile Li dendrites and dead Li are effectively suppressed. The Li metal anode conceived 3D Cu current collector can stably cycle for 400 h under an Li plating/stripping capacity of 1 mA h cm^–2 and a current density of 1 mA cm^–2. The Li@3D Cu||LiFePO₄ full cells present excellent cycling and rate performances. The electrochemical dealloying is a robust method to construct 3D Cu current collectors for dendrite–free Li metal anodes.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Key Basic Research Program of China; National Natural Science Foundation of China (NSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1466310

Journal Information:: Advanced Energy Materials, Vol. 8, Issue 19; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 261 works

Citation information provided by
Web of Science

References (54)

Nanostructured Host Materials for Trapping Sulfur in Rechargeable Li-S Batteries: Structure Design and Interfacial Chemistry Zhang, Jun; Huang, Hui; Bae, Jiwoong Small Methods, Vol. 2, Issue 1 https://doi.org/10.1002/smtd.201700279	journal	November 2017
Biological cell derived N-doped hollow porous carbon microspheres for lithium–sulfur batteries Xie, Yanping; Fang, Liang; Cheng, Hongwei Journal of Materials Chemistry A, Vol. 4, Issue 40 https://doi.org/10.1039/C6TA06164H	journal	January 2016
Atomically Thin Transition-Metal Dichalcogenides for Electrocatalysis and Energy Storage Duan, Xiaochuan; Xu, Jiantie; Wei, Zengxi Small Methods, Vol. 1, Issue 11 https://doi.org/10.1002/smtd.201700156	journal	September 2017
Flexible Metal-Air Batteries: Progress, Challenges, and Perspectives Liu, Qingchao; Chang, Zhiwen; Li, Zhongjun Small Methods, Vol. 2, Issue 2 https://doi.org/10.1002/smtd.201700231	journal	November 2017
Recent Progress in Applying In Situ/Operando Characterization Techniques to Probe the Solid/Liquid/Gas Interfaces of Li-O ₂ Batteries Liang, Zhuojian; Zou, Qingli; Wang, Yu Small Methods, Vol. 1, Issue 7 https://doi.org/10.1002/smtd.201700150	journal	June 2017
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.12	journal	March 2017
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries Ji, Liwen; Lin, Zhan; Alcoutlabi, Mataz Energy & Environmental Science, Vol. 4, Issue 8, p. 2682-2699 https://doi.org/10.1039/c0ee00699h	journal	January 2011
Effect of vinylene carbonate as additive to electrolyte for lithium metal anode Ota, Hitoshi; Shima, Kunihisa; Ue, Makoto Electrochimica Acta, Vol. 49, Issue 4 https://doi.org/10.1016/j.electacta.2003.09.010	journal	February 2004
Morphology and Activity Tuning of Cu ₃ Pt/C Ordered Intermetallic Nanoparticles by Selective Electrochemical Dealloying Wang, Deli; Yu, Yingchao; Zhu, Jing Nano Letters, Vol. 15, Issue 2 https://doi.org/10.1021/nl504597j	journal	January 2015
Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries Lin, Zhan; Liu, Zengcai; Fu, Wujun Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200696	journal	June 2012
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504526	journal	December 2015
Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance Lu, Lei-Lei; Ge, Jin; Yang, Jun-Nan Nano Letters, Vol. 16, Issue 7 https://doi.org/10.1021/acs.nanolett.6b01581	journal	June 2016
Alleviating polarization by designing ultrasmall Li ₂ S nanocrystals encapsulated in N-rich carbon as a cathode material for high-capacity, long-life Li–S batteries Hu, Chenji; Chen, Hongwei; Xie, Yanping Journal of Materials Chemistry A, Vol. 4, Issue 47 https://doi.org/10.1039/C6TA08572E	journal	January 2016
Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid Yang, Chunpeng; Fu, Kun; Zhang, Ying Advanced Materials, Vol. 29, Issue 36 https://doi.org/10.1002/adma.201701169	journal	July 2017
Direct growth of 3D host on Cu foil for stable lithium metal anode Shen, Fei; Zhang, Fan; Zheng, Yongjia Energy Storage Materials, Vol. 13 https://doi.org/10.1016/j.ensm.2018.02.005	journal	July 2018
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
A New Type of Multifunctional Polar Binder: Toward Practical Application of High Energy Lithium Sulfur Batteries Chen, Wei; Qian, Tao; Xiong, Jie Advanced Materials, Vol. 29, Issue 12 https://doi.org/10.1002/adma.201605160	journal	February 2017
Dendrite-free Li deposition using trace-amounts of water as an electrolyte additive Qian, Jiangfeng; Xu, Wu; Bhattacharya, Priyanka Nano Energy, Vol. 15 https://doi.org/10.1016/j.nanoen.2015.04.009	journal	July 2015
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
3D Porous Cu Current Collector/Li-Metal Composite Anode for Stable Lithium-Metal Batteries Li, Qi; Zhu, Shoupu; Lu, Yingying Advanced Functional Materials, Vol. 27, Issue 18 https://doi.org/10.1002/adfm.201606422	journal	March 2017
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes Lin, Dingchang; Liu, Yayuan; Liang, Zheng Nature Nanotechnology, Vol. 11, Issue 7 https://doi.org/10.1038/nnano.2016.32	journal	March 2016
Oxygen-deficient anatase TiO ₂ @C nanospindles with pseudocapacitive contribution for enhancing lithium storage Deng, Xiaolan; Wei, Zengxi; Cui, Chunyu Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/C7TA11301C	journal	January 2018
Advances in Lithium-Containing Anodes of Aprotic Li-O ₂ Batteries: Challenges and Strategies for Improvements Song, Hucheng; Deng, Han; Li, Chao Small Methods, Vol. 1, Issue 8 https://doi.org/10.1002/smtd.201700135	journal	July 2017
Direct Observation of the Growth of Lithium Dendrites on Graphite Anodes by Operando EC-AFM Shen, Cai; Hu, Guohong; Cheong, Ling-Zhi Small Methods, Vol. 2, Issue 2 https://doi.org/10.1002/smtd.201700298	journal	December 2017
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth Li, Weiyang; Yao, Hongbin; Yan, Kai Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8436	journal	June 2015
Nanoporous Polymer-Ceramic Composite Electrolytes for Lithium Metal Batteries Tu, Zhengyuan; Kambe, Yu; Lu, Yingying Advanced Energy Materials, Vol. 4, Issue 2, Article No. 1300654 https://doi.org/10.1002/aenm.201300654	journal	September 2013
Recent Progress in the Design of Advanced Cathode Materials and Battery Models for High-Performance Lithium-X (X = O ₂ , S, Se, Te, I ₂ , Br ₂ ) Batteries Xu, Jiantie; Ma, Jianmin; Fan, Qinghua Advanced Materials, Vol. 29, Issue 28 https://doi.org/10.1002/adma.201606454	journal	May 2017
Flexible ReS2 nanosheets/N-doped carbon nanofibers-based paper as a universal anode for alkali (Li, Na, K) ion battery Mao, Minglei; Cui, Chunyu; Wu, Mingguang Nano Energy, Vol. 45 https://doi.org/10.1016/j.nanoen.2018.01.001	journal	March 2018
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J. ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b02166	journal	May 2015
Chemical Dealloying Derived 3D Porous Current Collector for Li Metal Anodes Yun, Qinbai; He, Yan-Bing; Lv, Wei Advanced Materials, Vol. 28, Issue 32 https://doi.org/10.1002/adma.201601409	journal	May 2016
Prestoring Lithium into Stable 3D Nickel Foam Host as Dendrite-Free Lithium Metal Anode Chi, Shang-Sen; Liu, Yongchang; Song, Wei-Li Advanced Functional Materials, Vol. 27, Issue 24 https://doi.org/10.1002/adfm.201700348	journal	May 2017
Sulfurized solid electrolyte interphases with a rapid Li+ diffusion on dendrite-free Li metal anodes Cheng, Xin-Bing; Yan, Chong; Peng, Hong-Jie Energy Storage Materials, Vol. 10 https://doi.org/10.1016/j.ensm.2017.03.008	journal	January 2018
Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9058	journal	August 2015
Metallic anodes for next generation secondary batteries Kim, Hansu; Jeong, Goojin; Kim, Young-Ugk Chemical Society Reviews, Vol. 42, Issue 23 https://doi.org/10.1039/c3cs60177c	journal	January 2013
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism Ding, Fei; Xu, Wu; Graff, Gordon L. Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456 https://doi.org/10.1021/ja312241y	journal	March 2013
Erratum: Corrigendum: The role of nanotechnology in the development of battery materials for electric vehicles Lu, Jun; Chen, Zonghai; Ma, Zifeng Nature Nanotechnology, Vol. 12, Issue 1 https://doi.org/10.1038/nnano.2016.292	journal	January 2017
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook Nature Energy, Vol. 1, Issue 3, Article No. 16010 https://doi.org/10.1038/nenergy.2016.10	journal	February 2016
Nanostructured Carbon Nitride Polymer-Reinforced Electrolyte To Enable Dendrite-Suppressed Lithium Metal Batteries Hu, Jiulin; Tian, Jing; Li, Chilin ACS Applied Materials & Interfaces, Vol. 9, Issue 13 https://doi.org/10.1021/acsami.7b00478	journal	March 2017
Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes Lu, Dongping; Shao, Yuyan; Lozano, Terence Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201400993	journal	September 2014
Fabrication of Nanoporous Nickel by Electrochemical Dealloying Sun, Li; Chien, Chia-Ling; Searson, Peter C. Chemistry of Materials, Vol. 16, Issue 16 https://doi.org/10.1021/cm0497881	journal	August 2004
Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Ultrafine Silver Nanoparticles for Seeded Lithium Deposition toward Stable Lithium Metal Anode Yang, Chunpeng; Yao, Yonggang; He, Shuaiming Advanced Materials, Vol. 29, Issue 38 https://doi.org/10.1002/adma.201702714	journal	August 2017
A carbon-based 3D current collector with surface protection for Li metal anode Zhang, Ying; Liu, Boyang; Hitz, Emily Nano Research, Vol. 10, Issue 4 https://doi.org/10.1007/s12274-017-1461-2	journal	March 2017
Stable Li Metal Anodes via Regulating Lithium Plating/Stripping in Vertically Aligned Microchannels Wang, Shu-Hua; Yin, Ya-Xia; Zuo, Tong-Tong Advanced Materials, Vol. 29, Issue 40 https://doi.org/10.1002/adma.201703729	journal	September 2017
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
History, Evolution, and Future Status of Energy Storage Whittingham, M. S. Proceedings of the IEEE, Vol. 100, Issue Special Centennial Issue https://doi.org/10.1109/JPROC.2012.2190170	journal	May 2012
Promise and reality of post-lithium-ion batteries with high energy densities Choi, Jang Wook; Aurbach, Doron Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.13	journal	March 2016
3D Interconnected Electrode Materials with Ultrahigh Areal Sulfur Loading for Li-S Batteries Fang, Ruopian; Zhao, Shiyong; Hou, Pengxiang Advanced Materials, Vol. 28, Issue 17 https://doi.org/10.1002/adma.201506014	journal	March 2016
Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte Zhou, Weidong; Wang, Shaofei; Li, Yutao Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b05341	journal	July 2016
Nanostructured Anode Material for High-Power Battery System in Electric Vehicles Amine, Khalil; Belharouak, Ilias; Chen, Zonghai Advanced Materials, Vol. 22, Issue 28 https://doi.org/10.1002/adma.201000441	journal	June 2010
The Application of Atomic Force Microscopy for the Study of Li Deposition Processes Aurbach, Doron Journal of The Electrochemical Society, Vol. 143, Issue 11 https://doi.org/10.1149/1.1837248	journal	January 1996
Decoupling the origins of irreversible coulombic efficiency in anode-free lithium metal batteries Huang, Chen-Jui; Thirumalraj, Balamurugan; Tao, Hsien-Chu Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21683-6	journal	March 2021

Cited By (38)

3D Porous Cu Current Collectors Derived by Hydrogen Bubble Dynamic Template for Enhanced Li Metal Anode Performance Qiu, Hailong; Tang, Tianyu; Asif, Muhammad Advanced Functional Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adfm.201808468	journal	March 2019
Ultrafine Titanium Nitride Sheath Decorated Carbon Nanofiber Network Enabling Stable Lithium Metal Anodes Lin, Kui; Qin, Xianying; Liu, Ming Advanced Functional Materials, Vol. 29, Issue 46 https://doi.org/10.1002/adfm.201903229	journal	September 2019
Vertically Aligned Carbon Nanofibers on Cu Foil as a 3D Current Collector for Reversible Li Plating/Stripping toward High‐Performance Li–S Batteries Chen, Yazhou; Elangovan, Ayyappan; Zeng, Danli Advanced Functional Materials, Vol. 30, Issue 4 https://doi.org/10.1002/adfm.201906444	journal	November 2019
Dendrite‐Free Lithium Plating Induced by In Situ Transferring Protection Layer from Separator Hu, Zhiyu; Liu, Fengquan; Gao, Jian Advanced Functional Materials, Vol. 30, Issue 5 https://doi.org/10.1002/adfm.201907020	journal	November 2019
Bulk Nanostructured Materials Design for Fracture‐Resistant Lithium Metal Anodes Liu, Shan; Deng, Lijun; Guo, Wenqing Advanced Materials, Vol. 31, Issue 15 https://doi.org/10.1002/adma.201807585	journal	February 2019
An Autotransferable g‐C ₃ N ₄ Li ⁺ ‐Modulating Layer toward Stable Lithium Anodes Guo, Yanpeng; Niu, Ping; Liu, Yayuan Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201900342	journal	May 2019
Interlayered Dendrite‐Free Lithium Plating for High‐Performance Lithium‐Metal Batteries Xu, Ying; Li, Tao; Wang, Liping Advanced Materials, Vol. 31, Issue 29 https://doi.org/10.1002/adma.201901662	journal	May 2019
A 3D Lithiophilic Mo ₂ N‐Modified Carbon Nanofiber Architecture for Dendrite‐Free Lithium‐Metal Anodes in a Full Cell Luo, Liu; Li, Jianyu; Yaghoobnejad Asl, Hooman Advanced Materials, Vol. 31, Issue 48 https://doi.org/10.1002/adma.201904537	journal	October 2019
Improved Rechargeability of Lithium Metal Anode via Controlling Lithium-Ion Flux Xiang, Jingwei; Yuan, Lixia; Shen, Yue Advanced Energy Materials, Vol. 8, Issue 36 https://doi.org/10.1002/aenm.201802352	journal	October 2018
A Concentrated Ternary‐Salts Electrolyte for High Reversible Li Metal Battery with Slight Excess Li Qiu, Feilong; Li, Xiang; Deng, Han Advanced Energy Materials, Vol. 9, Issue 6 https://doi.org/10.1002/aenm.201803372	journal	December 2018
Efficient Li‐Ion‐Conductive Layer for the Realization of Highly Stable High‐Voltage and High‐Capacity Lithium Metal Batteries Lee, Jung‐In; Shin, Myungsoo; Hong, Dongki Advanced Energy Materials, Vol. 9, Issue 13 https://doi.org/10.1002/aenm.201803722	journal	February 2019
Promoting Highly Reversible Sodium Storage of Iron Sulfide Hollow Polyhedrons via Cobalt Incorporation and Graphene Wrapping Huang, Shaozhuan; Fan, Shuang; Xie, Lixin Advanced Energy Materials, Vol. 9, Issue 33 https://doi.org/10.1002/aenm.201901584	journal	July 2019
Facile Patterning of Laser‐Induced Graphene with Tailored Li Nucleation Kinetics for Stable Lithium‐Metal Batteries Yi, Jingsi; Chen, Jiahua; Yang, Zheng Advanced Energy Materials, Vol. 9, Issue 38 https://doi.org/10.1002/aenm.201901796	journal	August 2019
Plating/Stripping Behavior of Actual Lithium Metal Anode Liu, He; Cheng, Xin‐Bing; Xu, Rui Advanced Energy Materials, Vol. 9, Issue 44 https://doi.org/10.1002/aenm.201902254	journal	October 2019
Marginal Magnesium Doping for High‐Performance Lithium Metal Batteries Choi, Seung Ho; Lee, Seung Jong; Yoo, Dong‐Joo Advanced Energy Materials, Vol. 9, Issue 41 https://doi.org/10.1002/aenm.201902278	journal	September 2019
Self‐Formed Protection Layer on a 3D Lithium Metal Anode for Ultrastable Lithium–Sulfur Batteries Yan, Xinxiu; Zhang, Huan; Huang, Meiling ChemSusChem, Vol. 12, Issue 10 https://doi.org/10.1002/cssc.201900119	journal	April 2019
Controlling Nucleation in Lithium Metal Anodes Guan, Xuze; Wang, Aoxuan; Liu, Shan Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201801423	journal	July 2018
Ultrahigh-Capacity and Long-Life Lithium-Metal Batteries Enabled by Engineering Carbon Nanofiber-Stabilized Graphene Aerogel Film Host Zhao, Changtai; Yu, Chang; Li, Shaofeng Small, Vol. 14, Issue 42 https://doi.org/10.1002/smll.201803310	journal	September 2018
Uniform Lithium Nucleation Guided by Atomically Dispersed Lithiophilic CoN _x Sites for Safe Lithium Metal Batteries Liu, He; Chen, Xiang; Cheng, Xin‐Bing Small Methods, Vol. 3, Issue 9 https://doi.org/10.1002/smtd.201800354	journal	November 2018
Implanting CNT Forest onto Carbon Nanosheets as Multifunctional Hosts for High-Performance Lithium Metal Batteries Zhao, Changtai; Wang, Zhao; Tan, Xinyi Small Methods, Vol. 3, Issue 5 https://doi.org/10.1002/smtd.201800546	journal	February 2019
In situ fluorinated solid electrolyte interphase towards long-life lithium metal anodes Xu, Shan-Min; Duan, Hui; Shi, Ji-Lei Nano Research, Vol. 13, Issue 2 https://doi.org/10.1007/s12274-020-2625-z	journal	January 2020
Favorable lithium deposition behaviors on flexible carbon microtube skeleton enable a high-performance lithium metal anode Sun, Changzhi; Wu, Tian; Wang, Jianing Journal of Materials Chemistry A, Vol. 6, Issue 39 https://doi.org/10.1039/c8ta06828c	journal	January 2018
A 3D flexible and robust HAPs/PVA separator prepared by a freezing-drying method for safe lithium metal batteries Wang, Wei; Liao, Can; Liew, Kim Meow Journal of Materials Chemistry A, Vol. 7, Issue 12 https://doi.org/10.1039/c8ta11795k	journal	January 2019
A nitrogen-doped-carbon/ZnO modified Cu foam current collector for high-performance Li metal batteries Zhou, Ying; Zhao, Kai; Han, Yu Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c8ta12064a	journal	January 2019
Probing the dynamic evolution of lithium dendrites: a review of in situ / operando characterization for lithium metallic batteries Ma, Yue; Li, Shaowen; Wei, Bingqing Nanoscale, Vol. 11, Issue 43 https://doi.org/10.1039/c9nr06544j	journal	January 2019
Lithiophilicity conversion of the Cu surface through facile thermal oxidation: boosting a stable Li–Cu composite anode through melt infusion Wu, Shuilin; Jiao, Tianpeng; Yang, Shaoran Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c9ta00466a	journal	January 2019
Electrochemically induced highly ion conductive porous scaffolds to stabilize lithium deposition for lithium metal anodes Chen, Qiulin; Yang, Yifang; Zheng, Hongfei Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/c9ta01834d	journal	January 2019
Expanded-graphite embedded in lithium metal as dendrite-free anode of lithium metal batteries Zhao, Qiang; Hao, Xiaoge; Su, Shiming Journal of Materials Chemistry A, Vol. 7, Issue 26 https://doi.org/10.1039/c9ta04240g	journal	January 2019
A 3D Cu current collector with a biporous structure derived by a phase inversion tape casting method for stable Li metal anodes Wang, Li-Min; Tang, Zhong-Feng; Lin, Jie Journal of Materials Chemistry A, Vol. 7, Issue 29 https://doi.org/10.1039/c9ta05357c	journal	January 2019
ZnO nanoconfined 3D porous carbon composite microspheres to stabilize lithium nucleation/growth for high-performance lithium metal anodes Tang, Linsheng; Zhang, Rui; Zhang, Xinyue Journal of Materials Chemistry A, Vol. 7, Issue 33 https://doi.org/10.1039/c9ta06401j	journal	January 2019
Mitigating concentration polarization for highly reversible plating/stripping electrochemistry: Li versus Na Tang, Shuai; Zhang, Xia-Guang; Cui, Xue-Yang Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta08312j	journal	January 2019
Efficient and robust lithium metal electrodes enabled by synergistic surface activation–passivation of copper frameworks Yun, Jonghyeok; Won, Eun-Seo; Shin, Hyun-Seop Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta08779f	journal	January 2019
Nano-Cu-embedded carbon for dendrite-free lithium metal anodes Wang, Zhuo; Yu, Zhuo; Wang, Bingliang Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta09232c	journal	January 2019
Employing a T-shirt template and variant of Schweizer's reagent for constructing a low-weight, flexible, hierarchically porous and textile-structured copper current collector for dendrite-suppressed Li metal Zhu, Ruijie; Sheng, Nan; Rao, Zhonghao Journal of Materials Chemistry A, Vol. 7, Issue 47 https://doi.org/10.1039/c9ta10912a	journal	January 2019
A copper-clad lithiophilic current collector for dendrite-free lithium metal anodes Chen, Ke; Pathak, Rajesh; Gurung, Ashim Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta11237e	journal	January 2020
Sodium Storage in Coal/Biomass‐Derived Carbon/Carbon 3D Networks Shen, Hanting; Zhao, Hanqing; Kang, Mengmeng ChemElectroChem, Vol. 6, Issue 17 https://doi.org/10.1002/celc.201901176	journal	August 2019
Simple synthesis of TiNb6O17/C composite toward high-rate lithium storage Sun, Ruixue; Tao, Ying; Sun, Hongxian Journal of Materials Science, Vol. 54, Issue 24 https://doi.org/10.1007/s10853-019-03939-1	journal	September 2019
Rational design of Ni/Ni ₂ P heterostructures encapsulated in 3D porous carbon networks for improved lithium storage He, Jiapeng; Shen, Lu; Wu, Cuiping Dalton Transactions, Vol. 48, Issue 42 https://doi.org/10.1039/c9dt03011e	journal	January 2019

Similar Records

Electrolyte design for Li metal-free Li batteries

Journal Article · Sat Apr 25 00:00:00 EDT 2020 · Materials Today · OSTI ID:1466310

Chen, Ji; Li, Qin; Pollard, Travis P.; +3 more

Electrochemically Dealloyed 3D Porous Copper Nanostructure as Anode Current Collector of Li-Metal Batteries

Journal Article · Fri May 12 00:00:00 EDT 2023 · Small · OSTI ID:1466310

Ma, Yifan; Ma, Xuetian; Bai, Jianming; +6 more

Advanced strategies for the development of porous carbon as a Li host/current collector for lithium metal batteries

Journal Article · Thu Jun 17 00:00:00 EDT 2021 · Energy Storage Materials · OSTI ID:1466310

Pathak, Rajesh; Chen, Ke; Wu, Fan; +5 more

Related Subjects

25 ENERGY STORAGE
3D porous copper
Cu–Zn alloys
Li metal batteries
compact structures
electrochemical etching

Title: Compact 3D Copper with Uniform Porous Structure Derived by Electrochemical Dealloying as Dendrite-Free Lithium Metal Anode Current Collector

Citation Formats

References (54)

Cited By (38)

Similar Records

Related Subjects