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Thermodynamics of SmCo5 compound doped with Fe and Ni: An ab initio study

Journal Article · · Journal of Alloys and Compounds
 [1];  [1];  [2];  [1];  [1];  [1];  [1];  [3];  [3];  [4]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Ames Lab., Ames, IA (United States)
  4. Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering
SmCo5 permanent magnets exhibit enormous uniaxial magnetocrystalline anisotropy energy and have a high Curie temperature. Furthermore, their low energy product is a significant deficiency. In this paper, to increase the energy product in SmCo5, we propose substituting cobalt with iron, that has a much larger magnetic moment, in a SmCoNiFe3 magnet where nickel is used as a thermodynamic stabilizer.
Research Organization:
Ames Lab., Ames, IA (United States); Ames Laboratory (AMES), Ames, IA (United States); Iowa State Univ., Ames, IA (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Advanced Manufacturing Office (EE-5A)
Grant/Contract Number:
AC02-07CH11358; AC05-00OR22725; AC52-07NA27344
OSTI ID:
1465276
Alternate ID(s):
OSTI ID: 1545166
OSTI ID: 1478230
Report Number(s):
IS-J--9780; LLNL-JRNL--743621; 898616
Journal Information:
Journal of Alloys and Compounds, Journal Name: Journal of Alloys and Compounds Vol. 765; ISSN 0925-8388
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (28)

Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient journal December 2010
Magnetic Moments in SmCo5 and SmCo5−x Cu x Films journal April 2012
Prospects for Non-Rare Earth Permanent Magnets for Traction Motors and Generators journal June 2012
Formation and magnetic properties of metastable (TM)5Sm and (TM)7Sm2 (TM = Fe,Co) compounds journal November 1988
NMR investigation of Co magnetic anisotropy in RCo5 compounds journal March 1978
Thermal expansion and spontaneous magnetostriction of RCo5 intermetallic compounds journal July 1991
Magnetic moments and exchange interaction in Sm(Co,Fe)5 from first-principles journal January 2011
Charge self-consistent dynamical mean-field theory based on the full-potential linear muffin-tin orbital method: Methodology and applications journal April 2012
The isothermal section phase diagram of the Sm-Fe-Ni ternary system at 800 °C journal March 2016
Permanent magnets: Plugging the gap journal September 2012
Magneto-elastic lattice collapse in YCo5 journal July 2006
Magnetic properties of SmCo5 and YCo5 journal May 2003
RETM 5 and RE 2 TM 1 7 permanent magnets development journal March 1988
Formation of metastable compounds and magnetic properties in rapidly quenched (Fe 1− x Co x ) 5 Sm and (Fe 1− x Co x ) 7 Sm 2 alloy systems journal November 1988
New developments in hard magnetic materials journal September 1991
Meta-magnetism in UCoAl journal June 1989
3d-5d band magnetism in rare earth transition metal intermetallics: LuFe 2 journal August 1989
Ground-state properties of rare-earth metals: an evaluation of density-functional theory journal September 2014
Calculation of orbital magnetism and magnetocrystalline anisotropy energy in YCo 5 journal March 1992
Individual Co site contributions to the magnetic anisotropy of R Co 5 compounds and related structures journal March 1979
Theoretical aspects of the magnetism in the ferromagnetic A Fe 2 systems ( A =U, Np, Pu, and Am) journal May 1990
Magnetic properties of R ions in R Co 5 compounds ( R =Pr, Nd, Sm, Gd, Tb, Dy, Ho, and Er) journal April 1991
Itinerant-electron magnetocrystalline anisotropy energy of YCo 5 and related compounds journal April 2001
Prediction of the new efficient permanent magnet SmCoNiFe 3 journal September 2017
Easy directions of magnetization in ternary R2(Co, Fe)17phases journal September 1972
Neutron diffraction study of the Th(Co1-xFex)5alloys journal September 1973
Different contributions of the two cobalt sites to the magnetocrystalline anisotropy of YCo5and related compounds journal November 1976
Hard Magnetic Materials: A Perspective journal December 2011

Cited By (2)

Low-cost Sm0.7Y0.3Co5 sintered magnet produced by traditional powder metallurgical techniques journal April 2019
Anisotropy and orbital moment in Sm-Co permanent magnets journal July 2019

Figures / Tables (14)


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