Foundations and strategies of the construction of hybrid catalysts for optimized performances

Ye, Rong; Zhao, Jie; Wickemeyer, Brent B.; Toste, F. Dean; Somorjai, Gabor A.

doi:10.1038/s41929-018-0052-2

Foundations and strategies of the construction of hybrid catalysts for optimized performances

Journal Article · Mon Apr 09 00:00:00 EDT 2018 · Nature Catalysis

DOI:https://doi.org/10.1038/s41929-018-0052-2· OSTI ID:1464166

^[1]; Zhao, Jie ^[2]; Wickemeyer, Brent B. ^[2]; Toste, F. Dean ^[3]; ^[1]

Univ. of California, Berkeley, CA (United States). Kavli Energy NanoScience Inst.; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Catalysts are generally classified into three categories: homogeneous, heterogeneous and enzyme, each evolved as an independent field. Efforts to bridge these fields are scarce but desirable. In this paper, we first describe how numerous classes of reactions can be achieved by all three categories of catalysts. Examples are given based on a selective survey of the literature. Next, a selection of important approaches, the benefits and challenges of constructing heterogeneous–homogeneous, heterogeneous–enzyme and homogeneous–enzyme hybrid catalysts are discussed based on published researches. Hybrid catalysts not only increase the performance, including activity, selectivity, lifetime and recyclability compared to one of the components, but also offer extra functions such as a microenvironment for different reaction pathways, and cascade catalysis for products that are challenging to produce. Finally, we expect future tailor-made hybrid catalysts will combine the advantages of the components and be optimized for industrial applications.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1464166

Journal Information:: Nature Catalysis, Journal Name: Nature Catalysis Journal Issue: 5 Vol. 1; ISSN 2520-1158

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

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