Hydrogen Gas-Mediated Deoxydehydration/Hydrogenation of Sugar Acids: Catalytic Conversion of Glucarates to Adipates

Larson, Reed T.; Samant, Andrew; Chen, Jianbin; Lee, Woojin; Bohn, Martin A.; Ohlmann, Dominik M.; Zuend, Stephan J.; Toste, F. Dean

doi:10.1021/jacs.7b07801

Hydrogen Gas-Mediated Deoxydehydration/Hydrogenation of Sugar Acids: Catalytic Conversion of Glucarates to Adipates

Journal Article · Tue Oct 03 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b07801· OSTI ID:1464155

Larson, Reed T. ^[1]; Samant, Andrew ^[1]; Chen, Jianbin ^[1]; Lee, Woojin ^[2]; Bohn, Martin A. ^[3]; Ohlmann, Dominik M. ^[3]; Zuend, Stephan J. ^[4]; ^[1]

Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; BASF Corporation, Berkeley, CA (United States). California Research Alliance (CARA)
Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
BASF SE, Ludwigshafen (Germany)
BASF Corp., Fremont, CA (United States); BASF Corporation, Berkeley, CA (United States). California Research Alliance (CARA)

The development of a system for the operationally simple, scalable conversion of polyhydroxylated biomass into industrially relevant feedstock chemicals is described. This system includes a bimetallic Pd/Re catalyst in combination with hydrogen gas as a terminal reductant and enables the high-yielding reduction of sugar acids. This procedure has been applied to the synthesis of adipate esters, precursors for the production of Nylon-6,6, in excellent yield from biomass-derived sources.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: BASF Corporation; National Science Foundation (NSF) (United States); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1464155

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 40 Vol. 139; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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