Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering

Yang, Wanli; Devereaux, Thomas P.

doi:10.1016/j.jpowsour.2018.04.018

Title: Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering

Journal Article · Thu Apr 12 00:00:00 EDT 2018 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2018.04.018· OSTI ID:1601180

^[1]; Devereaux, Thomas P. ^[2]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
SLAC National Accelerator Lab., Menlo Park, CA (United States); Stanford Univ., CA (United States). Stanford Inst. for Materials and Energy Sciences. Geballe Lab. for Advanced Materials

Recent advances in battery science and technology have triggered both the challenges and opportunities on studying the materials and interfaces in batteries. In this paper, we review the recent demonstrations of soft X-ray spectroscopy for studying the interfaces and electrode materials. The focus of this review is on the recently developed mapping of resonant inelastic X-ray scattering (mRIXS) as a powerful probe of battery chemistry with superior sensitivity. Six different channels of soft X-ray absorption spectroscopy (sXAS) are introduced for different experimental purposes. Although conventional sXAS channels remain effective tools for quantitative analysis of the transition-metal states and surface chemistry, we elaborate the limitations of sXAS in both cationic and anionic redox studies. Particularly, based on experimental findings in various electrodes, we show that sXAS is unreliable for studying oxygen redox. We then demonstrate the mRIXS as a reliable technique for fingerprinting oxygen redox and summarize several crucial observations. We conclude that mRIXS is the tool-of-choice to study both the practical issue on reversibility of oxygen redox and the fundamental nature of bulk oxygen states. Finally, we hope this review clarifies the popular misunderstanding on oxygen sXAS results of oxide electrodes, and establishes a reliable technique for detecting oxygen redox through mRIXS.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515; AC02-05CH11231

OSTI ID:: 1601180

Alternate ID(s):: OSTI ID: 1464126; OSTI ID: 1548482

Journal Information:: Journal of Power Sources, Vol. 389, Issue C; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 156 works

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Stabilizing the Oxygen Lattice and Reversible Oxygen Redox Chemistry through Structural Dimensionality in Lithium‐Rich Cathode Oxides Zhao, Enyue; Li, Qinghao; Meng, Fanqi Angewandte Chemie, Vol. 131, Issue 13 https://doi.org/10.1002/ange.201900444	journal	February 2019
Reversible Anionic Redox Activities in Conventional LiNi _1/3 Co _1/3 Mn _1/3 O ₂ Cathodes Lee, Gi‐Hyeok; Wu, Jinpeng; Kim, Duho Angewandte Chemie, Vol. 132, Issue 22 https://doi.org/10.1002/ange.202001349	journal	March 2020

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