Asymmetric K/Li-Ion Battery Based on Intercalation Selectivity

Zheng, Jiaxin; Deng, Wenjun; Hu, Zongxiang; Zhuo, Zengqing; Liu, Fusheng; Chen, Haibiao; Lin, Yuan; Yang, Wanli; Amine, Khalil; Li, Rui; Lu, Jun; Pan, Feng

doi:10.1021/acsenergylett.7b01021

Asymmetric K/Li-Ion Battery Based on Intercalation Selectivity

Journal Article · Sun Nov 26 23:00:00 EST 2017 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.7b01021· OSTI ID:1461414

Zheng, Jiaxin ^[1]; Deng, Wenjun ^[1]; Hu, Zongxiang ^[1]; Zhuo, Zengqing ^[2]; Liu, Fusheng ^[3]; Chen, Haibiao ^[1]; Lin, Yuan ^[1]; Yang, Wanli ^[4]; Amine, Khalil ^[5]; Li, Rui ^[1]; Lu, Jun ^[5]; Pan, Feng ^[1]

Peking Univ., Shenzhen (China)
Peking Univ., Shenzhen (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Shenzhen Univ. (China); Shenzhen Key Lab. of Special Functional Materials (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

In this paper, using ab initio calculations combined with experimental confirmation, we design an asymmetric intercalation battery using K₂NiFe^II(CN)₆ as the cathode, commercial graphite as the anode, and an organic electrolyte containing mixed lithium and potassium salts. It works by reversible K-ion intercalation at the cathode side and reversible Li-ion intercalation at the anode side simultaneously. The π-electron coordination environment in K₂NiFe^II(CN)₆ ensures the preferred reversible intercalation of the K-ion, and the small ionic radius ensures the preferred reversible intercalation of the Li-ion in graphite. Finally, it also shows a high working voltage (~3.6 V) and an ultralong cycling life with no capacity fading even after 5000 cycles.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); Shenzhen Science and Technology Research Grant; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1461414

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 1 Vol. 3; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (57)

Highly Stable Nickel Hexacyanoferrate Nanotubes for Electrically Switched Ion Exchange Chen, W.; Xia, X. H. Advanced Functional Materials, Vol. 17, Issue 15 https://doi.org/10.1002/adfm.200700015	journal	October 2007
Liquid K-Na Alloy Anode Enables Dendrite-Free Potassium Batteries Xue, Leigang; Gao, Hongcai; Zhou, Weidong Advanced Materials, Vol. 28, Issue 43 https://doi.org/10.1002/adma.201602633	journal	September 2016
Carbon-Coated Porous Aluminum Foil Anode for High-Rate, Long-Term Cycling Stability, and High Energy Density Dual-Ion Batteries Tong, Xuefeng; Zhang, Fan; Ji, Bifa Advanced Materials, Vol. 28, Issue 45 https://doi.org/10.1002/adma.201603735	journal	September 2016
High-Capacity Aqueous Potassium-Ion Batteries for Large-Scale Energy Storage Su, Dawei; McDonagh, Andrew; Qiao, Shi-Zhang Advanced Materials, Vol. 29, Issue 1 https://doi.org/10.1002/adma.201604007	journal	October 2016
Bubble-Sheet-Like Interface Design with an Ultrastable Solid Electrolyte Layer for High-Performance Dual-Ion Batteries Qin, Panpan; Wang, Meng; Li, Na Advanced Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adma.201606805	journal	February 2017
A Novel Potassium-Ion-Based Dual-Ion Battery Ji, Bifa; Zhang, Fan; Song, Xiaohe Advanced Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adma.201700519	journal	March 2017
Prussian Blue MgLi Hybrid Batteries Sun, Xiaoqi; Duffort, Victor; Nazar, Linda F. Advanced Science, Vol. 3, Issue 8 https://doi.org/10.1002/advs.201600044	journal	April 2016
Hybrid Mg ²⁺ /Li ⁺ Battery with Long Cycle Life and High Rate Capability Gao, Tao; Han, Fudong; Zhu, Yujie Advanced Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aenm.201401507	journal	November 2014
Reversible Multivalent (Monovalent, Divalent, Trivalent) Ion Insertion in Open Framework Materials Wang, Richard Y.; Shyam, Badri; Stone, Kevin H. Advanced Energy Materials, Vol. 5, Issue 12 https://doi.org/10.1002/aenm.201401869	journal	April 2015
Hard Carbon Microspheres: Potassium-Ion Anode Versus Sodium-Ion Anode Jian, Zelang; Xing, Zhenyu; Bommier, Clement Advanced Energy Materials, Vol. 6, Issue 3 https://doi.org/10.1002/aenm.201501874	journal	November 2015
A Novel Aluminum-Graphite Dual-Ion Battery Zhang, Xiaolong; Tang, Yongbing; Zhang, Fan Advanced Energy Materials, Vol. 6, Issue 11 https://doi.org/10.1002/aenm.201502588	journal	March 2016
A Novel Tin-Graphite Dual-Ion Battery Based on Sodium-Ion Electrolyte with High Energy Density Sheng, Maohua; Zhang, Fan; Ji, Bifa Advanced Energy Materials, Vol. 7, Issue 7 https://doi.org/10.1002/aenm.201601963	journal	December 2016
A Superior Low-Cost Cathode for a Na-Ion Battery Wang, Long; Lu, Yuhao; Liu, Jue Angewandte Chemie International Edition, Vol. 52, Issue 7 https://doi.org/10.1002/anie.201206854	journal	January 2013
Lattice contractions and expansions accompanying the electrochemical conversions of Prussian blue and the reversible and irreversible insertion of rubidium and thallium ions Dostal, Aleš; Kauschka, Günther; Reddy, S. Jayarama Journal of Electroanalytical Chemistry, Vol. 406, Issue 1-2 https://doi.org/10.1016/0022-0728(95)04427-2	journal	April 1996
Lithium intercalation behavior of iron cyanometallates Imanishi, N.; Morikawa, T.; Kondo, J. Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(98)00228-6	journal	September 1999
Efficient calculation of the structural and electronic properties of mixed valence materials: application to Prussian Blue analogues Wojdeł, Jacek C.; Bromley, Stefan T. Chemical Physics Letters, Vol. 397, Issue 1-3 https://doi.org/10.1016/j.cplett.2004.08.107	journal	October 2004
Prussian white analogues as promising cathode for non-aqueous potassium-ion batteries Wu, Xianyong; Jian, Zelang; Li, Zhifei Electrochemistry Communications, Vol. 77 https://doi.org/10.1016/j.elecom.2017.02.012	journal	April 2017
Nickel Hexacyanoferrate Nanoparticles as a Low Cost Cathode Material for Lithium-Ion Batteries Omarova, Marzhana; Koishybay, Aibolat; Yesibolati, Nulati Electrochimica Acta, Vol. 184 https://doi.org/10.1016/j.electacta.2015.10.031	journal	December 2015
Potassium secondary cell based on Prussian blue cathode Eftekhari, Ali Journal of Power Sources, Vol. 126, Issue 1-2, p. 221-228 https://doi.org/10.1016/j.jpowsour.2003.08.007	journal	February 2004
A review of the electrochemical performance of alloy anodes for lithium-ion batteries Zhang, Wei-Jun Journal of Power Sources, Vol. 196, Issue 1 https://doi.org/10.1016/j.jpowsour.2010.07.020	journal	January 2011
A high-voltage rechargeable magnesium-sodium hybrid battery Li, Yifei; An, Qinyou; Cheng, Yingwen Nano Energy, Vol. 34 https://doi.org/10.1016/j.nanoen.2017.02.012	journal	April 2017
Efficient and Inexpensive Sodium–Magnesium Hybrid Battery Walter, Marc; Kravchyk, Kostiantyn V.; Ibáñez, Maria Chemistry of Materials, Vol. 27, Issue 21 https://doi.org/10.1021/acs.chemmater.5b03531	journal	October 2015
AVPO ₄ F (A = Li, K): A 4 V Cathode Material for High-Power Rechargeable Batteries Fedotov, Stanislav S.; Khasanova, Nellie R.; Samarin, Aleksandr Sh. Chemistry of Materials, Vol. 28, Issue 2 https://doi.org/10.1021/acs.chemmater.5b04065	journal	January 2016
Potassium Ion Batteries with Graphitic Materials Luo, Wei; Wan, Jiayu; Ozdemir, Burak Nano Letters, Vol. 15, Issue 11 https://doi.org/10.1021/acs.nanolett.5b03667	journal	October 2015
High Areal Capacity Hybrid Magnesium–Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large-Scale Energy Storage Yoo, Hyun Deog; Liang, Yanliang; Li, Yifei ACS Applied Materials & Interfaces, Vol. 7, Issue 12 https://doi.org/10.1021/acsami.5b01206	journal	March 2015
A High-Performance Rechargeable Mg ²⁺ /Li ⁺ Hybrid Battery Using One-Dimensional Mesoporous TiO ₂ (B) Nanoflakes as the Cathode Su, Shuojian; NuLi, Yanna; Huang, Zhenguo ACS Applied Materials & Interfaces, Vol. 8, Issue 11 https://doi.org/10.1021/acsami.6b00106	journal	March 2016
Potassium Secondary Batteries Eftekhari, Ali; Jian, Zelang; Ji, Xiulei ACS Applied Materials & Interfaces, Vol. 9, Issue 5 https://doi.org/10.1021/acsami.6b07989	journal	October 2016
Electrochemically Expandable Soft Carbon as Anodes for Na-Ion Batteries Luo, Wei; Jian, Zelang; Xing, Zhenyu ACS Central Science, Vol. 1, Issue 9 https://doi.org/10.1021/acscentsci.5b00329	journal	November 2015
Role of Nitrogen-Doped Graphene for Improved High-Capacity Potassium Ion Battery Anodes Share, Keith; Cohn, Adam P.; Carter, Rachel ACS Nano, Vol. 10, Issue 10 https://doi.org/10.1021/acsnano.6b05998	journal	October 2016
Preparation and Characterization of a Stable FeSO ₄ F-Based Framework for Alkali Ion Insertion Electrodes Recham, Nadir; Rousse, Gwenaëlle; Sougrati, Moulay T. Chemistry of Materials, Vol. 24, Issue 22 https://doi.org/10.1021/cm302428w	journal	November 2012
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
π-Back-Donation Effect of the Cyanide Ligands on the Electron Correlation and Charge Transfer in Prussian Blue RbMn[Fe(CN) ₆ ] Tian, Chuan; Kan, Erjun; Lee, Changhoon Inorganic Chemistry, Vol. 49, Issue 7 https://doi.org/10.1021/ic902577r	journal	April 2010
Bimetallic Cyanide-Bridged Coordination Polymers as Lithium Ion Cathode Materials: Core@Shell Nanoparticles with Enhanced Cyclability Asakura, Daisuke; Li, Carissa H.; Mizuno, Yoshifumi Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312160v	journal	February 2013
Controlling the Intercalation Chemistry to Design High-Performance Dual-Salt Hybrid Rechargeable Batteries Cho, Jae-Hyun; Aykol, Muratahan; Kim, Soo Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja508463z	journal	November 2014
Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries Wang, Long; Song, Jie; Qiao, Ruimin Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja510347s	journal	February 2015
Removal of Interstitial H ₂ O in Hexacyanometallates for a Superior Cathode of a Sodium-Ion Battery Song, Jie; Wang, Long; Lu, Yuhao Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja512383b	journal	February 2015
Carbon Electrodes for K-Ion Batteries Jian, Zelang; Luo, Wei; Ji, Xiulei Journal of the American Chemical Society, Vol. 137, Issue 36 https://doi.org/10.1021/jacs.5b06809	journal	September 2015
Low-Cost High-Energy Potassium Cathode Xue, Leigang; Li, Yutao; Gao, Hongcai Journal of the American Chemical Society, Vol. 139, Issue 6 https://doi.org/10.1021/jacs.6b12598	journal	January 2017
Switching Redox-Active Sites by Valence Tautomerism in Prussian Blue Analogues A_xMn_y[Fe(CN)₆]·nH₂O (A: K, Rb): Robust Frameworks for Reversible Li Storage Okubo, M.; Asakura, D.; Mizuno, Y. The Journal of Physical Chemistry Letters, Vol. 1, Issue 14, p. 2063-2071 https://doi.org/10.1021/jz100708b	journal	June 2010
Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries Wessells, Colin D.; Peddada, Sandeep V.; Huggins, Robert A. Nano Letters, Vol. 11, Issue 12, p. 5421-5425 https://doi.org/10.1021/nl203193q	journal	December 2011
Copper hexacyanoferrate battery electrodes with long cycle life and high power Wessells, Colin D.; Huggins, Robert A.; Cui, Yi Nature Communications, Vol. 2, Article No. 550 https://doi.org/10.1038/ncomms1563	journal	November 2011
High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries You, Ya; Wu, Xing-Long; Yin, Ya-Xia Energy Environ. Sci., Vol. 7, Issue 5 https://doi.org/10.1039/C3EE44004D	journal	January 2014
Van der Waals density functional study of the energetics of alkali metal intercalation in graphite Wang, Zhaohui; Selbach, Sverre M.; Grande, Tor RSC Adv., Vol. 4, Issue 8 https://doi.org/10.1039/C3RA47187J	journal	January 2014
High performance batteries based on hybrid magnesium and lithium chemistry Cheng, Yingwen; Shao, Yuyan; Zhang, Ji-Guang Chem. Commun., Vol. 50, Issue 68 https://doi.org/10.1039/C4CC03620D	journal	January 2014
A high performance hybrid battery based on aluminum anode and LiFePO ₄ cathode Sun, Xiao-Guang; Bi, Zhonghe; Liu, Hansan Chemical Communications, Vol. 52, Issue 8 https://doi.org/10.1039/C5CC09019A	journal	January 2016
A magnesium–sodium hybrid battery with high operating voltage Dong, Hui; Li, Yifei; Liang, Yanliang Chemical Communications, Vol. 52, Issue 53 https://doi.org/10.1039/C6CC03081E	journal	January 2016
Rechargeable dual-metal-ion batteries for advanced energy storage Yao, Hu-Rong; You, Ya; Yin, Ya-Xia Physical Chemistry Chemical Physics, Vol. 18, Issue 14 https://doi.org/10.1039/C6CP00586A	journal	January 2016
Novel 1.5 V anode materials, ATiOPO₄(A = NH₄, K, Na), for room-temperature sodium-ion batteries Mu, Linqin; Ben, Liubin; Hu, Yong-Sheng Journal of Materials Chemistry A, Vol. 4, Issue 19 https://doi.org/10.1039/C6TA00891G	journal	January 2016
Prussian blue: a new framework of electrode materials for sodium batteries Lu, Yuhao; Wang, Long; Cheng, Jinguang Chemical Communications, Vol. 48, Issue 52, p. 6544-6546 https://doi.org/10.1039/c2cc31777j	journal	January 2012
Ternary metal Prussian blue analogue nanoparticles as cathode materials for Li-ion batteries Okubo, Masashi; Honma, Itaru Dalton Transactions, Vol. 42, Issue 45 https://doi.org/10.1039/c3dt51369f	journal	January 2013
On the prediction of the crystal and electronic structure of mixed-valence materials by periodic density functional calculations: The case of Prussian Blue Wojdeł, Jacek C.; de P. R. Moreira, Ibério; Bromley, Stefan T. The Journal of Chemical Physics, Vol. 128, Issue 4 https://doi.org/10.1063/1.2824966	journal	January 2008
First principles calculation of a large variation in dielectric tensor through the spin crossover in the CsFe[Cr(CN) ₆ ] Prussian blue analogue Middlemiss, Derek S.; Deeth, Robert J. The Journal of Chemical Physics, Vol. 140, Issue 14 https://doi.org/10.1063/1.4869864	journal	April 2014
Ab initiocalculations on the mechanism of charge transfer in Co-Fe Prussian-blue compounds Kawamoto, T.; Asai, Y.; Abe, S. Physical Review B, Vol. 60, Issue 18 https://doi.org/10.1103/PhysRevB.60.12990	journal	November 1999
Spin crossover in theCsFeII[CrIII(CN)6]Prussian blue analog: Phonons and thermodynamics from hybrid functionals Middlemiss, Derek S.; Portinari, Damiano; Grey, Clare P. Physical Review B, Vol. 81, Issue 18 https://doi.org/10.1103/PhysRevB.81.184410	journal	May 2010
Reversible mechanism for spin crossover in transition-metal cyanides Kabir, Mukul; Van Vliet, Krystyn J. Physical Review B, Vol. 85, Issue 5 https://doi.org/10.1103/PhysRevB.85.054431	journal	February 2012
The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes Wessells, Colin D.; Peddada, Sandeep V.; McDowell, Matthew T. Journal of The Electrochemical Society, Vol. 159, Issue 2, p. A98-A103 https://doi.org/10.1149/2.060202jes	journal	January 2012
Rechargeable Mg–Li hybrid batteries: status and challenges Cheng, Yingwen; Chang, Hee Jung; Dong, Hui Journal of Materials Research, Vol. 31, Issue 20 https://doi.org/10.1557/jmr.2016.331	journal	September 2016

Cited By (1)

Reversible intercalation of methyl viologen as a dicationic charge carrier in aqueous batteries Wei, Zhixuan; Shin, Woochul; Jiang, Heng Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11218-5	journal	July 2019

Similar Records

Solvent-Mediated, Reversible Ternary Graphite Intercalation Compounds for Extreme-Condition Li-Ion Batteries

Journal Article · Fri Jun 07 00:00:00 EDT 2024 · Journal of the American Chemical Society · OSTI ID:2382649

Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite

Journal Article · Wed May 08 00:00:00 EDT 2019 · Nature (London) · OSTI ID:1559969

Related Subjects

25 ENERGY STORAGE
Batteries
Cations
Electrodes
Intercalation
Potassium

Asymmetric K/Li-Ion Battery Based on Intercalation Selectivity

Citation Formats

References (57)

Cited By (1)

Similar Records

Related Subjects