Progress in the Physisorption Characterization of Nanoporous Gas Storage Materials

Cychosz, Katie A.; Thommes, Matthias

doi:10.1016/j.eng.2018.06.001

Progress in the Physisorption Characterization of Nanoporous Gas Storage Materials

Journal Article · Tue Jun 12 00:00:00 EDT 2018 · Engineering

DOI:https://doi.org/10.1016/j.eng.2018.06.001· OSTI ID:1460982

Cychosz, Katie A. ^[1]; Thommes, Matthias ^[1]

Quantachrome Instruments, Boynton Beach, FL (United States)

Assessing the adsorption properties of nanoporous materials and determining their structural characterization is critical for progressing the use of such materials for many applications, including gas storage. Gas adsorption can be used for this characterization because it assesses a broad range of pore sizes, from micropore to mesopore. In the past 20 years, key developments have been achieved both in the knowledge of the adsorption and phase behavior of fluids in ordered nanoporous materials and in the creation and advancement of state-of-the-art approaches based on statistical mechanics, such as molecular simulation and density functional theory. Together with high-resolution experimental procedures for the adsorption of subcritical and supercritical fluids, this has led to significant advances in physical adsorption textural characterization. In this short, selective review paper, we discuss a few important and central features of the underlying adsorption mechanisms of fluids in a variety of nanoporous materials with well-defined pore structure. In conclusion, the significance of these features for advancing physical adsorption characterization and gas storage applications is also discussed.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1460982

Journal Information:: Engineering, Journal Name: Engineering Journal Issue: 4 Vol. 4; ISSN 2095-8099

Publisher:: Engineering Sciences PressCopyright Statement

Country of Publication:: United States

Language:: English

References (33)

N-Doped Polypyrrole-Based Porous Carbons for CO ₂ Capture Sevilla, Marta; Valle-Vigón, Patricia; Fuertes, Antonio B. Advanced Functional Materials, Vol. 21, Issue 14 https://doi.org/10.1002/adfm.201100291	journal	May 2011
A Microporous Copper Metal-Organic Framework with High H ₂ and CO ₂ Adsorption Capacity at Ambient Pressure Lässig, Daniel; Lincke, Jörg; Moellmer, Jens Angewandte Chemie International Edition, Vol. 50, Issue 44 https://doi.org/10.1002/anie.201102329	journal	September 2011
Die Absorption. Das Wasser in den Kolloïden, besonders in dem Gel der Kieselsäure van Bemmelen, J. M. Zeitschrift für anorganische Chemie, Vol. 13, Issue 1 https://doi.org/10.1002/zaac.18970130127	journal	January 1897
Characterization of the PSD of activated carbons from peach stones for separation of combustion gas mixtures Soares Maia, Débora A.; de Oliveira, J. C. Alexandre; Toso, Juan Pablo Adsorption, Vol. 17, Issue 5 https://doi.org/10.1007/s10450-011-9344-4	journal	February 2011
Physical adsorption characterization of nanoporous materials: progress and challenges Thommes, Matthias; Cychosz, Katie A. Adsorption, Vol. 20, Issue 2-3 https://doi.org/10.1007/s10450-014-9606-z	journal	February 2014
Sorption and pore condensation behavior of pure fluids in mesoporous MCM-48 silica, MCM-41 silica, SBA-15 silica and controlled-pore glass at temperatures above and below the bulk triple point Thommes, Matthias; Köhn, Ralf; Fröba, Michael Applied Surface Science, Vol. 196, Issue 1-4 https://doi.org/10.1016/S0169-4332(02)00062-4	journal	August 2002
Micelle-templated silicates as a test bed for methods of mesopore size evaluation Galarneau, Anne; Desplantier, Delphine; Dutartre, Roger Microporous and Mesoporous Materials, Vol. 27, Issue 2-3 https://doi.org/10.1016/S1387-1811(98)00263-7	journal	February 1999
Quenched solid density functional theory and pore size analysis of micro-mesoporous carbons Neimark, Alexander V.; Lin, Yangzheng; Ravikovitch, Peter I. Carbon, Vol. 47, Issue 7 https://doi.org/10.1016/j.carbon.2009.01.050	journal	June 2009
Physical characterization of activated carbons with narrow microporosity by nitrogen (77.4K), carbon dioxide (273K) and argon (87.3K) adsorption in combination with immersion calorimetry Silvestre-Albero, J.; Silvestre-Albero, A.; Rodríguez-Reinoso, F. Carbon, Vol. 50, Issue 9 https://doi.org/10.1016/j.carbon.2011.09.005	journal	August 2012
Quenched solid density functional theory method for characterization of mesoporous carbons by nitrogen adsorption Gor, Gennady Yu.; Thommes, Matthias; Cychosz, Katie A. Carbon, Vol. 50, Issue 4 https://doi.org/10.1016/j.carbon.2011.11.037	journal	April 2012
Density functional theory methods for characterization of porous materials Landers, John; Gor, Gennady Yu.; Neimark, Alexander V. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 437 https://doi.org/10.1016/j.colsurfa.2013.01.007	journal	November 2013
Experimental and theoretical studies of scanning adsorption–desorption isotherms Cimino, Richard; Cychosz, Katie A.; Thommes, Matthias Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 437 https://doi.org/10.1016/j.colsurfa.2013.03.025	journal	November 2013
Insights on Adsorption Characterization of Metal-Organic Frameworks: A Benchmark Study on the Novel soc-MOF Moellmer, J.; Celer, E. B.; Luebke, R. Microporous and Mesoporous Materials, Vol. 129, Issue 3 https://doi.org/10.1016/j.micromeso.2009.06.014	journal	April 2010
Understanding adsorption/desorption hysteresis for fluids in mesoporous materials using simple molecular models and classical density functional theory Monson, P. A. Microporous and Mesoporous Materials, Vol. 160 https://doi.org/10.1016/j.micromeso.2012.04.043	journal	September 2012
Effect of temperature on hydrogen and carbon dioxide adsorption hysteresis in an ultramicroporous MOF Wu, Haohan; Thibault, Charles G.; Wang, Hao Microporous and Mesoporous Materials, Vol. 219 https://doi.org/10.1016/j.micromeso.2015.08.005	journal	January 2016
Gaining Insights on the H ₂ –Sorbent Interactions: Robust soc-MOF Platform as a Case Study Cairns, Amy J.; Eckert, Juergen; Wojtas, Lukasz Chemistry of Materials, Vol. 28, Issue 20 https://doi.org/10.1021/acs.chemmater.6b02817	journal	October 2016
CO ₂ -Filling Capacity and Selectivity of Carbon Nanopores: Synthesis, Texture, and Pore-Size Distribution from Quenched-Solid Density Functional Theory (QSDFT) Hu, Xin; Radosz, Maciej; Cychosz, Katie A. Environmental Science & Technology, Vol. 45, Issue 16 https://doi.org/10.1021/es200782s	journal	August 2011
Pore size distribution analysis of microporous carbons: a density functional theory approach Lastoskie, Christian; Gubbins, Keith E.; Quirke, Nicholas The Journal of Physical Chemistry, Vol. 97, Issue 18 https://doi.org/10.1021/j100120a035	journal	May 1993
A Simple Two-Dimensional NLDFT Model of Gas Adsorption in Finite Carbon Pores. Application to Pore Structure Analysis Jagiello, Jacek; Olivier, James P. The Journal of Physical Chemistry C, Vol. 113, Issue 45 https://doi.org/10.1021/jp9082147	journal	October 2009
Stress-Based Model for the Breathing of Metal−Organic Frameworks Neimark, Alexander V.; Coudert, François-Xavier; Boutin, Anne The Journal of Physical Chemistry Letters, Vol. 1, Issue 1 https://doi.org/10.1021/jz9003087	journal	November 2009
The Method of Indeterminate Lagrange Multipliers in Nonlocal Density Functional Theory Neimark, Alexander V. Langmuir, Vol. 11, Issue 10 https://doi.org/10.1021/la00010a090	journal	October 1995
True Surface Areas from Nitrogen Adsorption Experiments Jelinek, Laszlo; sz. Kovats, Ervin Langmuir, Vol. 10, Issue 11 https://doi.org/10.1021/la00023a051	journal	November 1994
Density Functional Theory of Adsorption in Spherical Cavities and Pore Size Characterization of Templated Nanoporous Silicas with Cubic and Three-Dimensional Hexagonal Structures Ravikovitch, Peter I.; Neimark, Alexander V. Langmuir, Vol. 18, Issue 5 https://doi.org/10.1021/la0107594	journal	March 2002
Experimental Confirmation of Different Mechanisms of Evaporation from Ink-Bottle Type Pores: Equilibrium, Pore Blocking, and Cavitation Ravikovitch, Peter I.; Neimark, Alexander V. Langmuir, Vol. 18, Issue 25 https://doi.org/10.1021/la026140z	journal	December 2002
Adsorption Hysteresis of Nitrogen and Argon in Pore Networks and Characterization of Novel Micro- and Mesoporous Silicas Thommes, Matthias; Smarsly, Bernd; Groenewolt, Matthijs Langmuir, Vol. 22, Issue 2 https://doi.org/10.1021/la051686h	journal	January 2006
Characterization of the Pore Structure of Three-Dimensionally Ordered Mesoporous Carbons Using High Resolution Gas Sorption Cychosz, Katie A.; Guo, Xuefeng; Fan, Wei Langmuir, Vol. 28, Issue 34 https://doi.org/10.1021/la302362h	journal	August 2012
New Method for Atomistic Modeling of the Microstructure of Activated Carbons Using Hybrid Reverse Monte Carlo Simulation Nguyen, Thanh X.; Cohaut, Nathalie; Bae, Jun-Seok Langmuir, Vol. 24, Issue 15 https://doi.org/10.1021/la800351d	journal	August 2008
Contact Angles, Pore Condensation, and Hysteresis: Insights from a Simple Molecular Model Monson, P. A. Langmuir, Vol. 24, Issue 21 https://doi.org/10.1021/la801972e	journal	November 2008
Modeling Structural Morphology of Microporous Carbons by Reverse Monte Carlo Thomson, Kendall T.; Gubbins, Keith E. Langmuir, Vol. 16, Issue 13 https://doi.org/10.1021/la991581c	journal	June 2000
Recent advances in the textural characterization of hierarchically structured nanoporous materials Cychosz, Katie A.; Guillet-Nicolas, Rémy; García-Martínez, Javier Chemical Society Reviews, Vol. 46, Issue 2 https://doi.org/10.1039/C6CS00391E	journal	January 2017
A cost-effective synthesis of heteroatom-doped porous carbons as efficient CO ₂ sorbents Ashourirad, Babak; Arab, Pezhman; Islamoglu, Timur Journal of Materials Chemistry A, Vol. 4, Issue 38 https://doi.org/10.1039/C6TA06251B	journal	January 2016
Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications Paraknowitsch, Jens Peter; Thomas, Arne Energy & Environmental Science, Vol. 6, Issue 10 https://doi.org/10.1039/c3ee41444b	journal	January 2013
Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V. Pure and Applied Chemistry, Vol. 87, Issue 9-10 https://doi.org/10.1515/pac-2014-1117	journal	October 2015

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Confined Iron Nanoparticles on Mesoporous Ordered Silica for Fischer–Tropsch Synthesis Toncón-Leal, C. F.; Amaya-Roncancio, S.; García Blanco, A. A. Topics in Catalysis, Vol. 62, Issue 12-16 https://doi.org/10.1007/s11244-019-01201-1	journal	September 2019
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Removal of metal cations by diatomite treated with microemulsion dos Santos Borges, Valdivino Francisco; de Oliveira, Katherine Carrilho; Braga, Tiago Pinheiro Journal of Dispersion Science and Technology https://doi.org/10.1080/01932691.2019.1674153	journal	October 2019
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