Triphase electrode performance adjustment for rechargeable ion batteries

Ma, Hao; Su, Heng; Amine, Khalil; Liu, Xinyu; Jaffer, Saddique; Shang, Tongtong; Gu, Lin; Yu, Haijun

doi:10.1016/j.nanoen.2017.11.006

Title: Triphase electrode performance adjustment for rechargeable ion batteries

Journal Article · Mon Nov 06 00:00:00 EST 2017 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2017.11.006· OSTI ID:1460945

Ma, Hao ^[1]; Su, Heng ^[1]; Amine, Khalil ^[2]; Liu, Xinyu ^[3]; Jaffer, Saddique ^[1]; Shang, Tongtong ^[3]; Gu, Lin ^[3]; Yu, Haijun ^[1]

Beijing Univ. of Technology, Beijing (People's Republic of China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Chinese Academy of Sciences (CAS), Beijing (China)

Rechargeable batteries electrodes are mainly classical oxides with single structure, but their performance is insufficient to meet the growing energy storage needs of modern-society. Recently, composite-structure materials with great improvements in electrochemical performance have been developed. However, little research has been conducted on these materials with regard to adjusting their structures and further controlling their electrochemical performance. Herein, composite-structure Na_2/3Ni_1/3–xFe_xTi_2/3O₂ (0 ≤ x ≤ 1/3) electrodes for sodium-ion batteries were designed on the basis of results from in-situ high-temperature X-ray diffraction. Triphase compositions of P2-Na_2/3Ni_1/3Ti_2/3O₂, tunnel-Na_2.65Ti_3.35Fe_0.65O₉, and tunnel-NaFeTiO₄ were prepared, and Na⁺ insertion/extraction in different structures was observed using in-situ electrochemical X-ray diffraction. An optimum electrode with 46% P2-structure presented the best comprehensive performance: 105 mAh g^–1 initial reversible capacity along with 86.5% capacity-retention after 1500 cycles. As a result, this work opens a new field for designing and adjusting composite electrodes for better electrochemical performance, not limited for sodium-ion batteries but also for other advanced battery-systems.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1460945

Alternate ID(s):: OSTI ID: 1549074

Journal Information:: Nano Energy, Vol. 43, Issue C; ISSN 2211-2855

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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Recent developments of phosphorus-based anodes for sodium ion batteries Li, Zhaolin; Zhao, Hailei Journal of Materials Chemistry A, Vol. 6, Issue 47 https://doi.org/10.1039/c8ta08774a	journal	January 2018
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Title: Triphase electrode performance adjustment for rechargeable ion batteries

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