Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium

Friedrich, Jochen; Qiao, Yusen; Maichle-Mössmer, Cäcilia; Schelter, Eric J.; Anwander, Reiner

doi:10.1039/C8DT01878B

Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium

Journal Article · Sun Dec 31 23:00:00 EST 2017 · Dalton Transactions

DOI:https://doi.org/10.1039/C8DT01878B· OSTI ID:1460011

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Institut für Anorganische Chemie, Eberhard Karls Universität Tübingen, 72076 Tübingen, Germany
P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, USA

Combined structural/electrochemical/computational studies of ceric Ce[OSi(O t Bu) ₃ ] ₄ and cerous [Ce{OSi(O t Bu) ₃ } ₄ ][K(2.2.2-crypt)] suggest a redox-modulated coordination switch of a tris( tert -butoxy)siloxy ligand.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0017259

OSTI ID:: 1460011

Alternate ID(s):: OSTI ID: 1540032

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 30 Vol. 47; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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