Periodic Trends from Metal Substitution in Bimetallic Mo-Based Phosphides for Hydrodeoxygenation and Hydrogenation Reactions

Bonita, Yolanda; Hicks, Jason C.

doi:10.1021/acs.jpcc.7b09363

Periodic Trends from Metal Substitution in Bimetallic Mo-Based Phosphides for Hydrodeoxygenation and Hydrogenation Reactions

Journal Article · Wed Jan 03 00:00:00 EST 2018 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.7b09363· OSTI ID:1459981

Bonita, Yolanda ^[1]; ^[1]

Univ. of Notre Dame, IN (United States)

Bimetallic phosphides are promising materials for biomass valorization, yet many metal combinations are understudied as catalysts and require further analysis to realize their superior properties. Herein, we provide the synthesis, characterization, and catalytic performance of a variety of period 4 and 5 solid solutions of molybdenum-based bimetallic phosphides (MMoP, M = Fe, Co, Ni, Ru). From the results, the charge sharing between the metals and phosphorus control the relative oxidation of Mo and reduction of P in the lattice, which were both indirectly observed in binding energy shifts in X-ray photoelectron spectroscopy (XPS) and absorption energy shifts in X-ray absorption near-edge spectroscopy (XANES). For MMoP (M = Fe, Co, Ni), the more oxidized the Mo in the bimetallic phosphide, the higher the selectivity to benzene from phenol via direct deoxygenation at 400 °C and 750 psig. This phenomenon was observed in the bimetallic materials synthesized across period 4, where aromatic selectivity and degree of Mo oxidation both decreased in the following order FeMoP >> CoMoP > NiMoP. Alternatively, in the case of MMoP (M = Fe, Ru), the P in RuMoP is more oxidized compared to that in FeMoP, and the selectivity toward the hydrogenation pathway increased due to the interaction between the aromatic rings and the P species on the surface. For RuMoP and NiMoP, cyclohexanol was selectively produced from phenol with >99% selectivity when the reaction temperature was lowered to 125 °C at 750 psig, whereas FeMoP and CoMoP were not active under these conditions. Last, complete deoxygenation of phenol to benzene, cyclohexane, and cyclohexene was accomplished using mixtures of RuMoP and FeMoP in flow and batch experiments. Furthermore, these results highlight the versatility and wide applicability of transition metal phosphides for biomass conversions.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1459981

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 25 Vol. 122; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

References (69)

Bonding and Electronic Structure of Phosphides, Arsenides, and Antimonides by X-Ray Photoelectron and Absorption Spectroscopies Grosvenor, Andrew P.; Cavell, Ronald G.; Mar, Arthur Controlled Assembly and Modification of Inorganic Systems https://doi.org/10.1007/430_2008_14	book	January 2009
A scale of electronegativity based on electrostatic force Allred, A. L.; Rochow, E. G. Journal of Inorganic and Nuclear Chemistry, Vol. 5, Issue 4 https://doi.org/10.1016/0022-1902(58)80003-2	journal	January 1958
Hydrodesulfurization of dibenzothiophene over alumina-supported nickel molybdenum phosphide catalysts Nagai, Masatoshi; Fukiage, Tomokazu; Kurata, Shoji Catalysis Today, Vol. 106, Issue 1-4 https://doi.org/10.1016/j.cattod.2005.07.130	journal	October 2005
Many-electron singularity in X-ray photoemission and X-ray line spectra from metals Doniach, S.; Sunjic, M. Journal of Physics C: Solid State Physics, Vol. 3, Issue 2 https://doi.org/10.1088/0022-3719/3/2/010	journal	February 1970
Sandwiched Ruthenium/Carbon Nanostructures for Highly Active Heterogeneous Hydrogenation Su, F.; Lee, F. Y.; Lv, L. Advanced Functional Materials, Vol. 17, Issue 12 https://doi.org/10.1002/adfm.200700067	journal	June 2007
Selective Hydrodeoxygenation of Biomass-Derived Oxygenates to Unsaturated Hydrocarbons using Molybdenum Carbide Catalysts Ren, Hui; Yu, Weiting; Salciccioli, Michael ChemSusChem, Vol. 6, Issue 5 https://doi.org/10.1002/cssc.201200991	journal	April 2013
Molybdenum Carbide as a Highly Selective Deoxygenation Catalyst for Converting Furfural to 2-Methylfuran Xiong, Ke; Lee, Wen-Sheng; Bhan, Aditya ChemSusChem, Vol. 7, Issue 8 https://doi.org/10.1002/cssc.201402033	journal	April 2014
Bifunctional Molybdenum Polyoxometalates for the Combined Hydrodeoxygenation and Alkylation of Lignin-Derived Model Phenolics Anderson, Eric; Crisci, Anthony; Murugappan, Karthick ChemSusChem, Vol. 10, Issue 10 https://doi.org/10.1002/cssc.201700297	journal	April 2017
Influence of the Support of CoMo Sulfide Catalysts and of the Addition of Potassium and Platinum on the Catalytic Performances for the Hydrodeoxygenation of Carbonyl, Carboxyl, and Guaiacol-Type Molecules Centeno, A.; Laurent, E.; Delmon, B. Journal of Catalysis, Vol. 154, Issue 2 https://doi.org/10.1006/jcat.1995.1170	journal	July 1995
Binary and Ternary Transition-Metal Phosphides as HDN Catalysts Stinner, C.; Prins, R.; Weber, Th Journal of Catalysis, Vol. 202, Issue 1 https://doi.org/10.1006/jcat.2001.3283	journal	August 2001
Synthesis, Characterization, and Hydrodesulfurization Properties of Silica-Supported Molybdenum Phosphide Catalysts Phillips, Diana C.; Sawhill, Stephanie J.; Self, Randy Journal of Catalysis, Vol. 207, Issue 2 https://doi.org/10.1006/jcat.2002.3524	journal	April 2002
Bulk Structural Investigation of the Reduction of MoO3 with Propene and the Oxidation of MoO2 with Oxygen Ressler, T. Journal of Catalysis, Vol. 210, Issue 1 https://doi.org/10.1006/jcat.2002.3659	journal	August 2002
Bonding and Electronic Structure of Phosphides, Arsenides, and Antimonides by X-Ray Photoelectron and Absorption Spectroscopies Grosvenor, Andrew P.; Cavell, Ronald G.; Mar, Arthur Controlled Assembly and Modification of Inorganic Systems https://doi.org/10.1007/978-3-642-01562-5_2	book	January 2009
Carbon monoxide adsorption and hydrogen-oxygen titration on Ru/Al2O3 Corro, G.; Gómez, R. Reaction Kinetics and Catalysis Letters, Vol. 12, Issue 2 https://doi.org/10.1007/BF02071902	journal	June 1979
Preparation of Unsupported NiMoP Catalysts for 4,6-Dimethyldibenzothiophene Hydrodesulfurization Wang, Rui; Smith, Kevin J. Catalysis Letters, Vol. 144, Issue 9 https://doi.org/10.1007/s10562-014-1290-9	journal	June 2014
Role of Oxophilic Supports in the Selective Hydrodeoxygenation of m-Cresol on Pd Catalysts de Souza, Priscilla M.; Nie, Lei; Borges, Luiz E. P. Catalysis Letters, Vol. 144, Issue 12 https://doi.org/10.1007/s10562-014-1337-y	journal	September 2014
The Effect of Metal Type on Hydrodeoxygenation of Phenol Over Silica Supported Catalysts Teles, Camila A.; Rabelo-Neto, Raimundo C.; de Lima, Jerusa R. Catalysis Letters, Vol. 146, Issue 10 https://doi.org/10.1007/s10562-016-1815-5	journal	July 2016
Hydrodesulfurization of Dibenzothiophene and its Hydrogenated Intermediates Over Bulk Ni2P Li, Xiang; Bai, Jin; Wang, Anjie Topics in Catalysis, Vol. 54, Issue 5-7 https://doi.org/10.1007/s11244-011-9663-4	journal	February 2011
Ligand and Ensemble Effects in Bimetallic NiFe Phosphide Catalysts for the Hydrodeoxygenation of 2-Methyltetrahydrofuran Cho, Ara; Shin, Jieun; Takagaki, Atsushi Topics in Catalysis, Vol. 55, Issue 14-15 https://doi.org/10.1007/s11244-012-9882-3	journal	September 2012
Hydrodeoxygenation of hydroxy, methoxy and methyl phenols with molybdenum oxide/nickel oxide/alumina catalyst Kallury, R. Journal of Catalysis, Vol. 96, Issue 2 https://doi.org/10.1016/0021-9517(85)90321-5	journal	December 1985
Catalytic functionalities of supported sulfides IV. C$z.sbnd;O hydrogenolysis selectivity as a function of promoter type Shabtai, J. Journal of Catalysis, Vol. 104, Issue 2 https://doi.org/10.1016/0021-9517(87)90373-3	journal	April 1987
Novel catalysts for advanced hydroprocessing: transition metal phosphides Oyama, S. Ted Journal of Catalysis, Vol. 216, Issue 1-2, p. 343-352 https://doi.org/10.1016/S0021-9517(02)00069-6	journal	May 2003
Synthesis and characterization of silica-supported transition-metal phosphides as HDN catalysts Zuzaniuk, V.; Prins, R. Journal of Catalysis, Vol. 219, Issue 1 https://doi.org/10.1016/S0021-9517(03)00149-0	journal	October 2003
Structure of molybdenum-phosphate glasses by X-ray photoelectron spectroscopy (XPS) Khattak, G. D.; Salim, M. A.; Al-Harthi, A. S. Journal of Non-Crystalline Solids, Vol. 212, Issue 2-3 https://doi.org/10.1016/S0022-3093(97)00023-9	journal	June 1997
Influences of different phosphorus contents on NiMoP/Al2O3 hydrotreating catalysts Zhou, Tong-na; Yin, Hai-liang; Han, Shu-na Journal of Fuel Chemistry and Technology, Vol. 37, Issue 3 https://doi.org/10.1016/S1872-5813(09)60023-2	journal	June 2009
HDN and HDS of model compounds and light gas oil derived from Athabasca bitumen using supported metal phosphide catalysts Abu, Ibrahim I.; Smith, Kevin J. Applied Catalysis A: General, Vol. 328, Issue 1 https://doi.org/10.1016/j.apcata.2007.05.018	journal	August 2007
Hydrodesulfurization of 4,6-dimethyldibenzothiophene over high surface area metal phosphides Wang, Rui; Smith, Kevin J. Applied Catalysis A: General, Vol. 361, Issue 1-2 https://doi.org/10.1016/j.apcata.2009.03.037	journal	June 2009
A review of catalytic upgrading of bio-oil to engine fuels Mortensen, P. M.; Grunwaldt, J.-D.; Jensen, P. A. Applied Catalysis A: General, Vol. 407, Issue 1-2, p. 1-19 https://doi.org/10.1016/j.apcata.2011.08.046	journal	November 2011
Investigating the multifunctional nature of bimetallic FeMoP catalysts using dehydration and hydrogenolysis reactions Rensel, Dallas J.; Kim, Jongsik; Bonita, Yolanda Applied Catalysis A: General, Vol. 524 https://doi.org/10.1016/j.apcata.2016.06.011	journal	August 2016
Hydrodeoxygenation of guaiacol with CoMo catalysts. Part I: Promoting effect of cobalt on HDO selectivity and activity Bui, Van Ngoc; Laurenti, Dorothée; Afanasiev, Pavel Applied Catalysis B: Environmental, Vol. 101, Issue 3-4, p. 239-245 https://doi.org/10.1016/j.apcatb.2010.10.025	journal	January 2011
The effect of nickel content on the hydrodeoxygenation of 4-methylphenol over unsupported NiMoW sulfide catalysts Wang, Changlong; Wu, Zhuangzhi; Tang, Chaoyun Catalysis Communications, Vol. 32 https://doi.org/10.1016/j.catcom.2012.11.031	journal	February 2013
Transition metal phosphide hydroprocessing catalysts: A review Oyama, S. Ted; Gott, Travis; Zhao, Haiyan Catalysis Today, Vol. 143, Issue 1-2, p. 94-107 https://doi.org/10.1016/j.cattod.2008.09.019	journal	May 2009
Hydrodeoxygenation of guaiacol on noble metal catalysts Gutierrez, A.; Kaila, R. K.; Honkela, M. L. Catalysis Today, Vol. 147, Issue 3-4 https://doi.org/10.1016/j.cattod.2008.10.037	journal	October 2009
Catalytic hydrodeoxygenation (HDO) of phenol over supported molybdenum carbide, nitride, phosphide and oxide catalysts Boullosa-Eiras, Sara; Lødeng, Rune; Bergem, Håkon Catalysis Today, Vol. 223 https://doi.org/10.1016/j.cattod.2013.09.044	journal	March 2014
Regulating product distribution in deoxygenation of methyl laurate on silica-supported Ni–Mo phosphides: Effect of Ni/Mo ratio Chen, Jixiang; Yang, Yan; Shi, Heng Fuel, Vol. 129 https://doi.org/10.1016/j.fuel.2014.03.049	journal	August 2014
Dibenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP, Ni2P, and NiMoP catalysts Sun, Fuxia; Wu, Weicheng; Wu, Zili Journal of Catalysis, Vol. 228, Issue 2 https://doi.org/10.1016/j.jcat.2004.09.002	journal	December 2004
Bifunctional nature of a SiO2-supported Ni2P catalyst for hydrotreating: EXAFS and FTIR studies Lee, Y.; Oyama, S. Journal of Catalysis, Vol. 239, Issue 2 https://doi.org/10.1016/j.jcat.2005.12.029	journal	April 2006
The active site of nickel phosphide catalysts for the hydrodesulfurization of 4,6-DMDBT Oyama, S.; Lee, Y. Journal of Catalysis, Vol. 258, Issue 2 https://doi.org/10.1016/j.jcat.2008.06.023	journal	September 2008
Mössbauer spectroscopy investigation and hydrodesulfurization properties of iron–nickel phosphide catalysts Gaudette, Amy F.; Burns, Autumn W.; Hayes, John R. Journal of Catalysis, Vol. 272, Issue 1, p. 18-27 https://doi.org/10.1016/j.jcat.2010.03.016	journal	May 2010
CoMo sulfide-catalyzed hydrodeoxygenation of lignin model compounds: An extended reaction network for the conversion of monomeric and dimeric substrates Jongerius, Anna L.; Jastrzebski, Robin; Bruijnincx, Pieter C. A. Journal of Catalysis, Vol. 285, Issue 1 https://doi.org/10.1016/j.jcat.2011.10.006	journal	January 2012
Highly selective bimetallic FeMoP catalyst for C–O bond cleavage of aryl ethers Rensel, Dallas J.; Rouvimov, Sergei; Gin, Megan E. Journal of Catalysis, Vol. 305 https://doi.org/10.1016/j.jcat.2013.05.026	journal	September 2013
Impact of solvent for individual steps of phenol hydrodeoxygenation with Pd/C and HZSM-5 as catalysts He, Jiayue; Zhao, Chen; Lercher, Johannes A. Journal of Catalysis, Vol. 309 https://doi.org/10.1016/j.jcat.2013.09.009	journal	January 2014
Selective vapor-phase hydrodeoxygenation of anisole to benzene on molybdenum carbide catalysts Lee, Wen-Sheng; Wang, Zhenshu; Wu, Ryan J. Journal of Catalysis, Vol. 319 https://doi.org/10.1016/j.jcat.2014.07.025	journal	November 2014
Reactivity and stability investigation of supported molybdenum oxide catalysts for the hydrodeoxygenation (HDO) of m-cresol Shetty, Manish; Murugappan, Karthick; Prasomsri, Teerawit Journal of Catalysis, Vol. 331 https://doi.org/10.1016/j.jcat.2015.07.034	journal	November 2015
Mechanistic analysis of the role of metal oxophilicity in the hydrodeoxygenation of anisole Tan, Qiaohua; Wang, Gonghua; Long, Alex Journal of Catalysis, Vol. 347 https://doi.org/10.1016/j.jcat.2017.01.008	journal	March 2017
Next-nearest neighbour contributions to P 2p3/2 X-ray photoelectron binding energy shifts of mixed transition-metal phosphides M1−xM′xP with the MnP-type structure Grosvenor, Andrew P.; Cavell, Ronald G.; Mar, Arthur Journal of Solid State Chemistry, Vol. 180, Issue 10 https://doi.org/10.1016/j.jssc.2007.07.027	journal	October 2007
Mechanistic Study of Formic Acid Decomposition over Ru(0001) and P _x -Ru(0001): Effects of Phosphorus on C–H and C–O Bond Rupture Chang, SiWei A.; Flaherty, David W. The Journal of Physical Chemistry C, Vol. 120, Issue 44 https://doi.org/10.1021/acs.jpcc.6b08337	journal	October 2016
Different Product Distributions and Mechanistic Aspects of the Hydrodeoxygenation of m-Cresol over Platinum and Ruthenium Catalysts Tan, Qiaohua; Wang, Gonghua; Nie, Lei ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b00765	journal	September 2015
Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review Robinson, Allison M.; Hensley, Jesse E.; Medlin, J. Will ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b00923	journal	July 2016
Enhanced Hydrodeoxygenation of m -Cresol over Bimetallic Pt–Mo Catalysts through an Oxophilic Metal-Induced Tautomerization Pathway Robinson, Allison; Ferguson, Glen Allen; Gallagher, James R. ACS Catalysis, Vol. 6, Issue 7 https://doi.org/10.1021/acscatal.6b01131	journal	June 2016
X-ray Photoelectron and Absorption Spectroscopy of Metal-Rich Phosphides M ₂ P and M ₃ P ( M = Cr−Ni) Blanchard, Peter E. R.; Grosvenor, Andrew P.; Cavell, Ronald G. Chemistry of Materials, Vol. 20, Issue 22 https://doi.org/10.1021/cm802123a	journal	November 2008
Synthesis and Hydrodeoxygenation Properties of Ruthenium Phosphide Catalysts Bowker, Richard H.; Smith, Mica C.; Pease, Melissa L. ACS Catalysis, Vol. 1, Issue 8 https://doi.org/10.1021/cs200238v	journal	July 2011
Novel Hierarchical Cerium-Incorporated MFI Zeolite Catalysts for the Catalytic Fast Pyrolysis of Lignocellulosic Biomass Neumann, Gregory T.; Hicks, Jason C. ACS Catalysis, Vol. 2, Issue 4 https://doi.org/10.1021/cs200648q	journal	March 2012
Hydrodeoxygenation of Anisole over Silica-Supported Ni ₂ P, MoP, and NiMoP Catalysts Li, Kelun; Wang, Rijie; Chen, Jixiang Energy & Fuels, Vol. 25, Issue 3 https://doi.org/10.1021/ef101258j	journal	March 2011
Hydrodeoxygenation of 4-Methylphenol over Unsupported MoP, MoS ₂ , and MoO _x Catalysts ^† Whiffen, Victoria M. L.; Smith, Kevin J. Energy & Fuels, Vol. 24, Issue 9 https://doi.org/10.1021/ef901270h	journal	September 2010
Examination of the Bonding in Binary Transition-Metal Monophosphides MP (M = Cr, Mn, Fe, Co) by X-Ray Photoelectron Spectroscopy Grosvenor, Andrew P.; Wik, Stephen D.; Cavell, Ronald G. Inorganic Chemistry, Vol. 44, Issue 24 https://doi.org/10.1021/ic051004d	journal	November 2005
Gas-Phase Hydrogenation/Hydrogenolysis of Phenol over Supported Nickel Catalysts Shin, Eun-Jae; Keane, Mark A. Industrial & Engineering Chemistry Research, Vol. 39, Issue 4 https://doi.org/10.1021/ie990643r	journal	April 2000
Phosphorus 2p electron binding energies. Correlation with extended Hueckel charges Pelavin, M.; Hendrickson, D. N.; Hollander, J. M. The Journal of Physical Chemistry, Vol. 74, Issue 5 https://doi.org/10.1021/j100700a027	journal	March 1970
Alicyclic Diamines. Preparation of Bis-(4-aminocyclohexyl)-methane Barkdoll, A. E.; England, D. C.; Gray, H. W. Journal of the American Chemical Society, Vol. 75, Issue 5 https://doi.org/10.1021/ja01101a044	journal	March 1953
Reductions with Ruthenium Catalysts. I. Preparation of Some Cyclohexylalkylamines ¹ Freifelder, Morris; Stone, George R. Journal of the American Chemical Society, Vol. 80, Issue 19 https://doi.org/10.1021/ja01552a063	journal	October 1958
Infrared Spectroscopic Investigation of CO Adsorption on Silica-Supported Nickel Phosphide Catalysts Layman, Kathryn A.; Bussell, Mark E. The Journal of Physical Chemistry B, Vol. 108, Issue 30 https://doi.org/10.1021/jp037101e	journal	July 2004
Advances in C–O Bond Transformations in Lignin-Derived Compounds for Biofuels Production Hicks, Jason C. The Journal of Physical Chemistry Letters, Vol. 2, Issue 18 https://doi.org/10.1021/jz2007885	journal	August 2011
Correlating lignin structure to aromatic products in the catalytic fast pyrolysis of lignin model compounds containing β–O–4 linkages Neumann, Gregory T.; Pimentel, Brian R.; Rensel, Dallas J. Catal. Sci. Technol., Vol. 4, Issue 11 https://doi.org/10.1039/C4CY00569D	journal	January 2014
Selective hydrogenation of phenol and related derivatives Zhong, Jiawei; Chen, Jinzhu; Chen, Limin Catal. Sci. Technol., Vol. 4, Issue 10 https://doi.org/10.1039/C4CY00583J	journal	January 2014
Exceptional control of carbon-supported transition metal nanoparticles using metal-organic frameworks Kim, Jongsik; Neumann, Gregory T.; McNamara, Nicholas D. Journal of Materials Chemistry A, Vol. 2, Issue 34 https://doi.org/10.1039/C4TA03050H	journal	January 2014
Composition-directed Fe _X Mo _2−X P bimetallic catalysts for hydrodeoxygenation reactions Rensel, Dallas J.; Kim, Jongsik; Jain, Varsha Catalysis Science & Technology, Vol. 7, Issue 9 https://doi.org/10.1039/C7CY00324B	journal	January 2017
Effects of metal substitution in transition-metal phosphides (Ni1−xM′x)2P (M′ = Cr, Fe, Co) studied by X-ray photoelectron and absorption spectroscopy Blanchard, Peter E. R.; Grosvenor, Andrew P.; Cavell, Ronald G. Journal of Materials Chemistry, Vol. 19, Issue 33 https://doi.org/10.1039/b904250d	journal	January 2009
Bimetallic catalysts for upgrading of biomass to fuels and chemicals Alonso, David Martin; Wettstein, Stephanie G.; Dumesic, James A. Chemical Society Reviews, Vol. 41, Issue 24, p. 8075-8098 https://doi.org/10.1039/c2cs35188a	journal	January 2012
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011

Cited By (5)

Mechanistic insights into hydrodeoxygenation of phenol on bimetallic phosphide catalysts Jain, Varsha; Bonita, Yolanda; Brown, Alicia Catalysis Science & Technology, Vol. 8, Issue 16 https://doi.org/10.1039/c8cy00977e	journal	January 2018
Recent developments of transition metal phosphides as catalysts in the energy conversion field Pei, Yu; Cheng, Yu; Chen, Jiyi Journal of Materials Chemistry A, Vol. 6, Issue 46 https://doi.org/10.1039/c8ta09454c	journal	January 2018
Direct synthesis of furfuryl alcohol from furfural: catalytic performance of monometallic and bimetallic Mo and Ru phosphides Bonita, Yolanda; Jain, Varsha; Geng, Feiyang Catalysis Science & Technology, Vol. 9, Issue 14 https://doi.org/10.1039/c9cy00705a	journal	January 2019
Effects of phosphorus addition on selectivity and stability of Pd model catalysts during cyclohexene dehydrogenation Sampath, Abinaya; Flaherty, David W. Catalysis Science & Technology, Vol. 10, Issue 4 https://doi.org/10.1039/c9cy02134e	journal	January 2020
Bimetallic metal–organic framework-derived MoFe-PC microspheres for electrocatalytic ammonia synthesis under ambient conditions Chen, Silong; Jang, Haeseong; Wang, Jia Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta10524g	journal	January 2020

Similar Records

Composition-directed Fe _X Mo_2-XP bimetallic catalysts for hydrodeoxygenation reactions

Journal Article · Sat Dec 31 23:00:00 EST 2016 · Catalysis Science and Technology · OSTI ID:1492848

Mechanistic insights into hydrodeoxygenation of phenol on bimetallic phosphide catalysts

Journal Article · Sun Jul 15 20:00:00 EDT 2018 · Catalysis Science and Technology · OSTI ID:1543804

The synergistic effect between Ni sites and Ni-Fe alloy sites on hydrodeoxygenation of lignin-derived phenols

Journal Article · Sun Sep 15 00:00:00 EDT 2019 · Applied Catalysis B: Environmental · OSTI ID:1523385

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
aromatic compounds
catalysts
inorganic compounds
metals
redox reactions

Periodic Trends from Metal Substitution in Bimetallic Mo-Based Phosphides for Hydrodeoxygenation and Hydrogenation Reactions

Citation Formats

References (69)

Cited By (5)

Similar Records

Related Subjects