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Investigation of Solid Electrolyte Interphase Layer Formation and Electrochemical Reversibility of Magnetite, Fe3O4, Electrodes: A Combined X-ray Absorption Spectroscopy and X-ray Photoelectron Spectroscopy Study

Journal Article · · Journal of Physical Chemistry. C
 [1];  [2];  [2];  [3];  [4];  [3]
  1. Energy Sciences Directorate, Brookhaven National Laboratory, Upton, New York 11973, United States
  2. Naval Surface Warfare Center, Carderock Division, West Bethesda, Maryland 20817, United States
  3. Energy Sciences Directorate, Brookhaven National Laboratory, Upton, New York 11973, United States; Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, United States; Department of Materials Science and Chemical Engineering, State University of New York at Stony Brook, Stony Brook, New York 11794-2275, United States
  4. Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, United States; Department of Materials Science and Chemical Engineering, State University of New York at Stony Brook, Stony Brook, New York 11794-2275, United States
+ Show Author Affiliations

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI ID:
1459963
Journal Information:
Journal of Physical Chemistry. C, Vol. 122, Issue 26; ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
ENGLISH

References (56)

Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions journal August 2010
The structure of magnetite: Symmetry of cubic spinels journal March 1986
Insights into Ionic Transport and Structural Changes in Magnetite during Multiple-Electron Transfer Reactions journal March 2016
Formation of Uniform Fe 3 O 4 Hollow Spheres Organized by Ultrathin Nanosheets and Their Excellent Lithium Storage Properties journal June 2015
Synthesis of Hierarchical Hollow-Structured Single-Crystalline Magnetite (Fe 3 O 4 ) Microspheres: The Highly Powerful Storage versus Lithium as an Anode for Lithium Ion Batteries journal March 2012
Review on recent progress of nanostructured anode materials for Li-ion batteries journal July 2014
Investigation of SEI Layer Formation in Conversion Iron Fluoride Cathodes by Combined STEM/EELS and XPS journal April 2015
Formation, dynamics, and implication of solid electrolyte interphase in high voltage reversible conversion fluoride nanocomposites journal January 2010
Self-Assembled Fe 3 O 4 Nanoparticle Clusters as High-Performance Anodes for Lithium Ion Batteries via Geometric Confinement journal August 2013
Carbon Coated Fe 3 O 4 Nanospindles as a Superior Anode Material for Lithium-Ion Batteries journal December 2008
The effect of fluoroethylene carbonate additive content on the formation of the solid-electrolyte interphase and capacity fade of Li-ion full-cell employing nano Si–graphene composite anodes journal July 2014
Reduction Mechanism of Fluoroethylene Carbonate for Stable Solid-Electrolyte Interphase Film on Silicon Anode journal November 2013
Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode journal October 2006
Performance Enhancing Electrolyte Additives for Lithium Ion Batteries with Silicon Anodes journal January 2012
Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes journal December 2011
Consumption of Fluoroethylene Carbonate (FEC) on Si-C Composite Electrodes for Li-Ion Batteries journal January 2016
The Impact of Vinylene Carbonate, Fluoroethylene Carbonate and Vinyl Ethylene Carbonate Electrolyte Additives on Electrode/Electrolyte Reactivity Studied Using Accelerating Rate Calorimetry journal January 2014
Comparative Study of Fluoroethylene Carbonate and Vinylene Carbonate for Silicon Anodes in Lithium Ion Batteries journal January 2014
The Effect of Fluoroethylene Carbonate as an Additive on the Solid Electrolyte Interphase on Silicon Lithium-Ion Electrodes journal August 2015
Improved Performance of the Silicon Anode for Li-Ion Batteries: Understanding the Surface Modification Mechanism of Fluoroethylene Carbonate as an Effective Electrolyte Additive journal March 2015
Improved stability of nano-Sn electrode with high-quality nano-SEI formation for lithium ion battery journal March 2015
Characterizing Solid Electrolyte Interphase on Sn Anode in Lithium Ion Battery journal January 2015
Investigation of Fluoroethylene Carbonate Effects on Tin-based Lithium-Ion Battery Electrodes journal March 2015
The effects of FEC (fluoroethylene carbonate) electrolyte additive on the lithium storage properties of NiO (nickel oxide) nanocuboids journal September 2013
Electrolytes and Interphases in Li-Ion Batteries and Beyond journal October 2014
Electrodeposition of Fe 3 O 4 Thin Film and Its Application as Anode for Lithium Ion Batteries journal January 2016
Synthesis of Fe3O4 nanoparticles with various sizes and magnetic properties by controlled hydrolysis journal October 2007
Theoretical x-ray absorption fine structure standards journal July 1991
An X‐Ray Study of the Wüstite (FeO) Solid Solutions journal January 1933
XLI. Precision measurements of crystal parameters journal February 1933
Facile and economical synthesis of hierarchical carbon-coated magnetite nanocomposite particles and their applications in lithium ion battery anodes journal January 2012
Sandwich-Structured Graphene-Fe 3 O 4 @Carbon Nanocomposites for High-Performance Lithium-Ion Batteries journal April 2015
Facile synthesis of carbon-decorated single-crystalline Fe3O4 nanowires and their application as high performance anode in lithium ion batteries journal January 2009
Reflections on the history of electrochemical impedance spectroscopy journal January 2006
Kinetics of rapid electrode reactions journal January 1947
Boosting the power performance of multilayer graphene as lithium-ion battery anode via unconventional doping with in-situ formed Fe nanoparticles journal March 2016
Dispersion of Nanocrystalline Fe 3 O 4 within Composite Electrodes: Insights on Battery-Related Electrochemistry journal April 2016
The lattice expansion of iron
  • Basinski, Zbigniew Stanislaw; Hume-Rothery, William; Sutton, A. L.
  • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 229, Issue 1179, p. 459-467 https://doi.org/10.1098/rspa.1955.0102
journal May 1955
Probing the Li Insertion Mechanism of ZnFe 2 O 4 in Li-Ion Batteries: A Combined X-Ray Diffraction, Extended X-Ray Absorption Fine Structure, and Density Functional Theory Study journal May 2017
Primary and secondary oxygen-induced C1s binding energy shifts in x-ray photoelectron spectroscopy of polymers journal August 1992
Surface film formation on a graphite electrode in Li-ion batteries: AFM and XPS study journal January 2005
High capacity Li-ion battery anodes: Impact of crystallite size, surface chemistry and PEG-coating journal January 2018
Combined Surface and Electrochemical Study of the Lithiation/Delithiation Mechanism of the Iron Oxide Thin-Film Anode for Lithium-Ion Batteries journal October 2013
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries journal September 2010
Characterization of Lithium Alkyl Carbonates by X-ray Photoelectron Spectroscopy: Experimental and Theoretical Study journal August 2005
Amorphous Columnar Silicon Anodes for Advanced High Voltage Lithium Ion Full Cells: Dominant Factors Governing Cycling Performance journal January 2013
XPS studies of the oxygen 1s and 2s levels in a wide range of functional polymers journal June 1993
Binding state information from XPS depth profiling: capabilities and limits journal July 2001
Investigation of the Solid Electrolyte Interphase Formed by Fluoroethylene Carbonate on Si Electrodes journal January 2011
What Makes Fluoroethylene Carbonate Different? journal June 2015
Silicon Solid Electrolyte Interphase (SEI) of Lithium Ion Battery Characterized by Microscopy and Spectroscopy journal June 2013
Modeling Electrochemical Decomposition of Fluoroethylene Carbonate on Silicon Anode Surfaces in Lithium Ion Batteries journal December 2013
Thermal stability of LiPF6 salt and Li-ion battery electrolytes containing LiPF6 journal October 2006
Synergetic Effects of Inorganic Components in Solid Electrolyte Interphase on High Cycle Efficiency of Lithium Ion Batteries journal February 2016
X-ray Photoelectron Spectroscopy Studies of Lithium Surfaces Prepared in Several Important Electrolyte Solutions. A Comparison with Previous Studies by Fourier Transform Infrared Spectroscopy journal January 1996
A Study of Electrochemical Reduction of Ethylene and Propylene Carbonate Electrolytes on Graphite Using ATR-FTIR Spectroscopy journal January 2005

Cited By (1)

The Systematic Refinement for the Phase Change and Conversion Reactions Arising from the Lithiation of Magnetite Nanocrystals journal November 2019

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