Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers

An, Litao; Wang, Hao; Teat, Simon J.; Xu, Feng; Wang, Xin-Long; Wang, Fangming; Li, Jing

doi:10.1021/acs.inorgchem.6b02332

Title: Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers

Journal Article · Wed Nov 23 00:00:00 EST 2016 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.6b02332· OSTI ID:1459900

An, Litao ^[1]; Wang, Hao ^[2]; Teat, Simon J. ^[3]; Xu, Feng ^[2]; Wang, Xin-Long ^[2]; Wang, Fangming ^[2];

^[2]

Huaiyin Normal Univ.,(China). Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, College of Chemistry and Chemical Engineering; Rutgers Univ., New Brunswick, NJ (United States). Dept. of Chemistry and Chemical Biology
Rutgers Univ., New Brunswick, NJ (United States). Dept. of Chemistry and Chemical Biology
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

In the present work we report the design, synthesis, crystal structure determination, and adsorption properties of two new cadmium-based porous coordination polymers, [Cd(pda)_0.5(spiro-4-py)_0.5(HCOO)]•2H₂O•DMF (compound 1, pda = p-phenylenediacetate, spiro- 4-py = (2,2’,7,7’-tetra(pyridin-4-yl)-9,9’-spirobi[fluorene], DMF = N,N’-dimethylformamide) and [Cd₂(pda)(spiro-4-py)(CH₃COO)₂]•DMA (compound 2, DMA = N,N’-dimethylacetamide) with similar structures. The coordination between cadmium and two organic linkers, pda and spiro-4-py, has yielded two-dimensional frameworks with rhombic openings. Stacking of these two-dimensional networks does not block the openings but rather results in permanent porosity with one-dimensional channels in the final structures. The permanent porosity of these compounds is confirmed by gas adsorption measurements. Compounds 1 and 2 have BET (Brunauer-Emmett-Teller) surface areas of 687 and 584 m²/g, respectively. Both compounds show favorable adsorption towards carbon dioxide over other light gases such as nitrogen, oxygen, and carbon monoxide. IAST (Ideal adsorbed solution theory) is employed to predict the adsorption selectivity of binary gas mixtures. Though compounds 1 and 2 possess similar structures, differences are observed in their gas adsorption behaviors, which can be attributed to their different terminal ligands of formate and acetate, respectively. Strikingly, both compounds show exceptionally high stability in aqueous media with a wide pH range, a characteristic that is highly desirable for gas separation-related applications. The robustness of these structures suggests that the use of hydrophobic spiro based multipyridine ligands can lead to water stable frameworks built on late-transition metals that are otherwise sensitive to moisture.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation of Jiangsu Provincial Department of Education

Grant/Contract Number:: FG02-08ER-46491; 12KJD150002; 15KJA150003; 21375044; 51602118

OSTI ID:: 1459900

Journal Information:: Inorganic Chemistry, Vol. 55, Issue 24; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 24 works

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CCDC 1502463: Experimental Crystal Structure Determination: JAMSIC : catena-[(μ-2,2'-(1,4-phenylene)diacetato)-(μ-4,4',4'',4'''-(9,9'-spirobi[fluorene]-2,2',7,7'-tetrayl)tetrapyridine)-bis(acetato)-di-cadmium N,N-dimethylacetamide solvate hydrate] An, Litao; Wang, Hao; Xu, Feng https://doi.org/10.5517/ccdc.csd.cc1mffk1 The current record is supplemented by this dataset	dataset	September 2016
CCDC 1502464: Experimental Crystal Structure Determination: JAMSOI : catena-((μ-2,2'-(1,4-phenylene)diacetato)-(μ-4-(2',7,7'-tris(pyridin-4-yl)-9,9'-spirobi[fluoren]-2-yl)pyridine)-bis(formato)-di-cadmium unknown solvate tetrahydrate) An, Litao; Wang, Hao; Xu, Feng https://doi.org/10.5517/ccdc.csd.cc1mffl2 The current record is supplemented by this dataset	dataset	September 2016