High voltage redox shuttles, method for making high voltage redox shuttles

Krumdick, Gregory K.; Dzwiniel, Trevor L.; Pupek, Krzysztof

Title: High voltage redox shuttles, method for making high voltage redox shuttles

Patent · Tue Jun 26 00:00:00 EDT 2018

OSTI ID:1459568

Krumdick, Gregory K.; Dzwiniel, Trevor L.; Pupek, Krzysztof

The invention provides a method for producing a molecule capable of undergoing reduction-oxidation when subjected to a voltage potential, the method comprising phosphorylating hydroquinone to create a first intermediate; rearranging the first intermediate to an aryl-bis-(phosphonate) thereby creating a second intermediate comprising phosphorous alkoxy groups; alkylating (e.g., methylating) the second intermediate; converting the alkoxy groups to halides; and substituting the halides to alkyl or aryl groups. Also provided is a system for preventing overcharge in a Lithium-ion battery, the method comprising a mixture of a redox shuttle with electrolyte in the battery such that the shuttle comprises between about 10 and about 20 weight percent of the mixture.

View Patent

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: UCHICAGO ARGONNE, LLC (Chicago, IL)

Patent Number(s):: 10,008,743

Application Number:: 14/171,556

OSTI ID:: 1459568

Resource Relation:: Patent File Date: 2014 Feb 03

Country of Publication:: United States

Language:: English

References (15)

Process for the methylation of hydroxybenzene derivatives Findlay, David M. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4065504 US Patent Document 4,065,504	patent	December 1977
Bisphosphine dioxides Moloy, Kenneth Gene https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4902833 US Patent Document 4,902,833	patent	February 1990
Lithium based compounds useful as electrodes and method for preparing same Dahn, Jeffrey R.; Zheng, Tao https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5858324 US Patent Document 5,858,324	patent	January 1999
Nickel--containing compounds useful as electrodes and method for preparing same Dahn, Jeffrey R.; Zheng, Tao https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5900385 US Patent Document 5,900,385	patent	May 1999
Hydrocarbon treatment of carbonaceous materials Dahn, Jeffery R.; Buiel, Eddie R. P. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6143268 US Patent Document 6,143,268	patent	November 2000
Lithium-ion batteries Obrovac, Mark N.; Dahn, Jeffrey R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6680145 US Patent Document 6,680,145	patent	January 2004
Cathode compositions for lithium-ion batteries Lu, Zhonghua; Dahn, Jeffrey R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6964828 US Patent Document 6,964,828	patent	November 2005
Cathode compositions for lithium-ion batteries Lu, Zhonghua; Dahn, Jeffrey R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7078128 US Patent Document 7,078,128	patent	July 2006
Solid state synthesis of lithium ion battery cathode material Eberman, Kevin W.; Scanlan, Jerome E.; Goodbrake, Chris J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7211237 US Patent Document 7,211,237	patent	May 2007
Cathode compositions for lithium-ion batteries Lu, Zhonghua; Dahn, Jeffrey R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030027048 US Patent Application 09/845178; 20030027048	patent-application	February 2003
Cathode composition for rechargeable lithium battery Le, Dinh Ba https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040121234 US Patent Application 10/328563; 20040121234	patent-application	June 2004
Method of producing lithium ion cathode materials Dahn, Jeffrey R.; Jouanneau, Severine; Eberman, Kevin W. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040179993 US Patent Application 10/757645; 20040179993	patent-application	September 2004
Diode laser array beam homogenizer Karlsen, Scott R.; Crum, Trevor Radley https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060045144 US Patent Application 10/932719; 20060045144	patent-application	March 2006
Redox shuttles for lithium ion batteries Weng, Wei; Zhang, Zhengcheng; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110294017 US Patent Application 13/113499; 20110294017	patent-application	December 2011
Phosphonated poly(arylene ether)s as potential high temperature proton conducting materials Abouzari-Lotf, Ebrahim; Ghassemi, Hossein; Shockravi, Abbas Polymer, Vol. 52, Issue 21, p. 4709-4717 https://doi.org/10.1016/j.polymer.2011.08.020	journal	September 2011

Similar Records

Method for producing redox shuttles

Patent · Tue Mar 03 00:00:00 EST 2015 · OSTI ID:1459568

Pupek, Krzysztof Z.; Dzwiniel, Trevor L.; Krumdick, Gregory K.

Iron Redox Shuttles with Wide Optical Gap Dyes for High–Voltage Dye–Sensitized Solar Cells

Journal Article · Fri May 21 00:00:00 EDT 2021 · ChemSusChem · OSTI ID:1459568

Curiac, Christine; Rodrigues, Roberta R.; Watson, Jonathon; +6 more

Redox shuttles for overcharge protection of lithium batteries

Patent · Tue Dec 14 00:00:00 EST 2010 · OSTI ID:1459568

Amine, Khalil; Chen, Zonghai; Wang, Qingzheng

Title: High voltage redox shuttles, method for making high voltage redox shuttles

Citation Formats

References (15)

Similar Records

Related Subjects