Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO 2 Reduction in Water

Smith, Peter T.; Benke, Bahiru Punja; Cao, Zhi; Kim, Younghoon; Nichols, Eva M.; Kim, Kimoon; Chang, Christopher J.

doi:10.1002/ange.201803873

Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO ₂ Reduction in Water

Journal Article · Thu Jul 05 00:00:00 EDT 2018 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201803873· OSTI ID:1459221

Smith, Peter T. ^[1]; Benke, Bahiru Punja ^[2]; Cao, Zhi ^[1]; ^[3]; Nichols, Eva M. ^[1]; ^[4]; ^[5]

Department of Chemistry University of California, Berkeley Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720-1460 USA
Center for Self-assembly and Complexity (CSC) Institute for Basic Science (IBS) Pohang 37673 Republic of Korea
Department of Chemistry Pohang University of Science and Technology Pohang 37673 Republic of Korea
Center for Self-assembly and Complexity (CSC) Institute for Basic Science (IBS) Pohang 37673 Republic of Korea, Department of Chemistry Pohang University of Science and Technology Pohang 37673 Republic of Korea
Department of Chemistry University of California, Berkeley Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720-1460 USA, Department Molecular and Cell Biology and the Howard Hughes Medical Institute University of California, Berkeley Berkeley CA 94720-1460 USA

Abstract

A porous organic cage composed of six iron tetraphenylporphyrins was used as a supramolecular catalyst for electrochemical CO ₂ ‐to‐CO conversion. This strategy enhances active site exposure and substrate diffusion relative to the monomeric catalyst, resulting in CO generation with near‐quantitative Faradaic efficiency in pH 7.3 water, with activities reaching 55 250 turnovers. These results provide a starting point for the design of supramolecular catalysts that can exploit the properties of the surrounding matrix yet retain the tunability of the original molecular unit.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1459221

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 31 Vol. 130; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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