Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives

Ciesielski, Peter N.; Pecha, M. Brennan; Bharadwaj, Vivek S.; Mukarakate, Calvin; Leong, G. Jeremy; Kappes, Branden; Crowley, Michael F.; Kim, Seonah; Foust, Thomas D.; Nimlos, Mark R.

doi:10.1002/wene.297

Title: Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives

Journal Article · Thu Apr 26 00:00:00 EDT 2018 · Wiley Interdisciplinary Reviews. Energy and Environment

DOI:https://doi.org/10.1002/wene.297· OSTI ID:1458816

Ciesielski, Peter N. ^[1]; Pecha, M. Brennan ^[1]; Bharadwaj, Vivek S. ^[1]; Mukarakate, Calvin ^[2]; Leong, G. Jeremy ^[3]; Kappes, Branden ^[3]; Crowley, Michael F. ^[1]; Kim, Seonah ^[1]; Foust, Thomas D. ^[2]; Nimlos, Mark R. ^[2]

Biosciences Center, National Renewable Energy Laboratory, Golden Colorado
National Bioenergy Center, National Renewable Energy Laboratory, Golden Colorado
Department of Mechanical Engineering, Colorado School of Mines, Golden Colorado

Catalytic fast pyrolysis (CFP) is a conversion process that integrates rapid thermochemical depolymerization of solid feedstocks with catalytic transformation to yield small molecules for fuel and chemical products. This process is well-suited for the conversion of nonfossil feedstocks such as biomass and waste plastics, and thereby holds great potential for the production of renewable commodities. In spite of many technological developments in various aspects of CFP achieved over decades of research, this technology has yet to attain commercial success for the production of fuels and chemicals from renewable feedstocks. Effective CFP processes require careful coordination of chemical and physical phenomena that span very large length and time scales. A broad spectrum of scientific progress in both pyrolysis and catalytic upgrading has provided the foundation for successful deployment of CFP, although additional progress in process-scale integration is yet required for commercial realization. Modeling and simulation tools provide an important framework wherein the CFP technologies by be better understood and evaluated from a holistic perspective. Here we provide a detailed description of the multiscale phenomena underlying CFP, describe challenges and associated technical progress, and suggest strategies for an integrated approach to advance this technology toward commercialization.

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Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Bioenergy Technologies Office

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 1458816

Report Number(s):: NREL/JA-2700-71246

Journal Information:: Wiley Interdisciplinary Reviews. Energy and Environment, Vol. 7, Issue 4; ISSN 2041-8396

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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