Towards an all-vanadium redox flow battery with higher theoretical volumetric capacities by utilizing the VO2+ /V3+ couple

Duan, Wentao; Li, Bin; Lu, Dongping; Wei, Xiaoliang; Nie, Zimin; Vijayakumar, M.; Kizewski, James P.; Hollas, Aaron; Reed, David; Sprenkle, Vincent; Wang, Wei

doi:10.1016/J.JECHEM.2018.05.020

Title: Towards an all-vanadium redox flow battery with higher theoretical volumetric capacities by utilizing the VO²⁺ /V³⁺ couple

Journal Article · Fri Jun 15 00:00:00 EDT 2018 · Journal of Energy Chemistry

DOI:https://doi.org/10.1016/J.JECHEM.2018.05.020· OSTI ID:1457754

Duan, Wentao ^[1]; Li, Bin ^[1]; Lu, Dongping ^[1]; Wei, Xiaoliang ^[1]; Nie, Zimin ^[1]; Vijayakumar, M. ^[1]; Kizewski, James P. ^[1]; Hollas, Aaron ^[1]; Reed, David ^[1]; Sprenkle, Vincent ^[1]; Wang, Wei ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

In this study, an all-vanadium redox flow battery with V(IV) as the sole parent active species is developed by accessing the VO²⁺/V³⁺ redox couple. These batteries, referred to as V4RBs, possess a higher theoretical volumetric capacity than traditional VRBs. Copper ions were identified as an effective additive to boost the battery performance.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Electricity (OE)

Grant/Contract Number:: AC05-76RL01830; 57558

OSTI ID:: 1457754

Alternate ID(s):: OSTI ID: 1724449

Report Number(s):: PNNL-SA-127931; PII: S2095495618300123

Journal Information:: Journal of Energy Chemistry, Vol. 27, Issue 5; ISSN 2095-4956

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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Cited By (1)

Adaptation of Cu(In, Ga)Se ₂ photovoltaics for full unbiased photocharge of integrated solar vanadium redox flow batteries Murcia-López, Sebastián; Chakraborty, Monalisa; Carretero, Nina M. Sustainable Energy & Fuels, Vol. 4, Issue 3 https://doi.org/10.1039/c9se00949c	journal	January 2020

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Title: Towards an all-vanadium redox flow battery with higher theoretical volumetric capacities by utilizing the VO2+ /V3+ couple

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