“Ni-Less” Cathodes for High Energy Density, Intermediate Temperature Na-NiCl2 Batteries

Chang, Hee-Jung; Lu, Xiaochuan; Bonnett, Jeffery F.; Canfield, Nathan L.; Son, Sori; Park, Yoon-Cheol; Jung, Keeyoung; Sprenkle, Vincent L.; Li, Guosheng

doi:10.1002/admi.201701592

“Ni-Less” Cathodes for High Energy Density, Intermediate Temperature Na-NiCl₂ Batteries

Journal Article · Wed Mar 07 23:00:00 EST 2018 · Advanced Materials Interfaces

DOI:https://doi.org/10.1002/admi.201701592· OSTI ID:1455259

Chang, Hee-Jung ^[1]; Lu, Xiaochuan ^[1]; Bonnett, Jeffery F. ^[1]; Canfield, Nathan L. ^[1]; Son, Sori ^[2]; Park, Yoon-Cheol ^[2]; Jung, Keeyoung ^[2]; Sprenkle, Vincent L. ^[1]; ^[1]

Electrochemical Materials and Systems Group, Energy and Environmental Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA
Materials Research Division, Research Institute of Industrial Science and Technology, Pohang 37673 South Korea

Among various battery technologies being considered for stationary energy storage applications, sodium-metal halide (Na-MH) batteries have become one of the most attractive candidates because of the abundance of raw materials, long cycle life, high energy density, and superior safety. However, one of issues limiting its practical application is the relatively expensive nickel (Ni) used in the cathode. In the present work, we focus on of efforts to develop new Ni-based cathodes, and demonstrate that a much higher specific energy density of 405 Wh/kg (23% higher than state-of-the-art Na-MH batteries) can be achieved at an operating temperature of 190oC. Furthermore, 15% less Ni is used in the new cathode than that in conventional Na-NiCl2 batteries. Long-term cycling tests also show stable electrochemical performance for over 300 cycles with excellent capacity retention (~100%). The results in this work indicate that these advances can significantly reduce the raw material cost associated with Ni (a 31% reduction) and promote practical applications of Na-MH battery technologies in stationary energy storage systems.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (US)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1455259

Report Number(s):: PNNL-SA-130933; TE1400000

Journal Information:: Advanced Materials Interfaces, Journal Name: Advanced Materials Interfaces Journal Issue: 10 Vol. 5; ISSN 2196-7350

Publisher:: Wiley-VCH

Country of Publication:: United States

Language:: English

References (32)

Advanced intermediate temperature sodium–nickel chloride batteries with ultra-high energy density Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10683	journal	February 2016
High temperature sodium batteries: status, challenges and future trends Hueso, Karina B.; Armand, Michel; Rojo, Teófilo Energy & Environmental Science, Vol. 6, Issue 3 https://doi.org/10.1039/c3ee24086j	journal	January 2013
Development of intermediate temperature sodium nickel chloride rechargeable batteries using conventional polymer sealing technologies Chang, Hee Jung; Lu, Xiaochuan; Bonnett, Jeff F. Journal of Power Sources, Vol. 348 https://doi.org/10.1016/j.jpowsour.2017.02.059	journal	April 2017
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Zebra batteries Sudworth, J. L. Journal of Power Sources, Vol. 51, Issue 1-2 https://doi.org/10.1016/0378-7753(94)01967-3	journal	August 1994
The effects of temperature on the electrochemical performance of sodium–nickel chloride batteries Lu, Xiaochuan; Li, Guosheng; Kim, Jin Y. Journal of Power Sources, Vol. 215 https://doi.org/10.1016/j.jpowsour.2012.05.020	journal	October 2012
Advances in ZEBRA batteries Dustmann, Cord-H Journal of Power Sources, Vol. 127, Issue 1-2, p. 85-92 https://doi.org/10.1016/j.jpowsour.2003.09.039	journal	March 2004
A duplex β″-Al2O3 solid electrolyte consisting of a thin dense layer and a porous substrate Kim, Jin Y.; Canfield, Nathan L.; Bonnett, Jeff F. Solid State Ionics, Vol. 278 https://doi.org/10.1016/j.ssi.2015.06.013	journal	October 2015
The sodium/nickel chloride (ZEBRA) battery Sudworth, J. Journal of Power Sources, Vol. 100, Issue 1-2 https://doi.org/10.1016/S0378-7753(01)00891-6	journal	November 2001
X-ray absorption measurements on nickel cathode of sodium-beta alumina batteries: Fe–Ni–Cl chemical associations Bowden, Mark E.; Alvine, Kyle J.; Fulton, John L. Journal of Power Sources, Vol. 247 https://doi.org/10.1016/j.jpowsour.2013.08.046	journal	February 2014
Sodium-Metal Halide and Sodium-Air Batteries Ha , Seongmin; Kim , Jae-Kwang; Choi, Aram ChemPhysChem, Vol. 15, Issue 10 https://doi.org/10.1002/cphc.201402215	journal	June 2014
Development of a Ni,NiCl[sub 2] Positive Electrode for a Liquid Sodium (ZEBRA) Battery Cell Bones, R. J. Journal of The Electrochemical Society, Vol. 136, Issue 5 https://doi.org/10.1149/1.2096905	journal	January 1989
Molten salt electrochemical synthesis of sodium titanates as high performance anode materials for sodium ion batteries Li, Haomiao; Wang, Kangli; Li, Wei Journal of Materials Chemistry A, Vol. 3, Issue 32 https://doi.org/10.1039/C5TA03250D	journal	January 2015
Sodium-beta alumina batteries: Status and challenges Lu, Xiaochuan; Lemmon, John P.; Sprenkle, Vincent JOM, Vol. 62, Issue 9 https://doi.org/10.1007/s11837-010-0132-5	journal	September 2010
High Temperature Sodium - Zinc Chloride Batteries With Sodium Beta - Alumina Solid Electrolyte Parthasarathy, Preethy; Weber, Neill; Virkar, Anil V. 211th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.2811944	conference	January 2007
Battery Technologies for Large-Scale Stationary Energy Storage Soloveichik, Grigorii L. Annual Review of Chemical and Biomolecular Engineering, Vol. 2, Issue 1, p. 503-527 https://doi.org/10.1146/annurev-chembioeng-061010-114116	journal	July 2011
In Situ Spatially Resolved Neutron Diffraction of a Sodium Metal Halide Battery Zinth, Veronika; Seidlmayer, Stefan; Zanon, Nicola Journal of The Electrochemical Society, Vol. 162, Issue 3 https://doi.org/10.1149/2.0421503jes	journal	December 2014
Effects of Ni particle morphology on cell performance of Na/NiCl2 battery Kim, Mangi; Ahn, Cheol-Woo; Hahn, Byung-Dong Metals and Materials International, Vol. 23, Issue 6 https://doi.org/10.1007/s12540-017-7062-5	journal	November 2017
Advanced Na-NiCl ₂ Battery Using Nickel-Coated Graphite with Core–Shell Microarchitecture Chang, Hee-Jung; Canfield, Nathan L.; Jung, Keeyoung ACS Applied Materials & Interfaces, Vol. 9, Issue 13 https://doi.org/10.1021/acsami.7b00271	journal	March 2017
A new high energy density battery system Coetzer, J. Journal of Power Sources, Vol. 18, Issue 4 https://doi.org/10.1016/0378-7753(86)80093-3	journal	November 1986
Self-Repairing Function of Ni ₃ S ₂ Layer on Ni Particles in the Na/NiCl ₂ Cells with the Addition of Sulfur in the Catholyte Ao, Xin; Wen, Zhaoyin; Wu, Xiangwei ACS Applied Materials & Interfaces, Vol. 9, Issue 25 https://doi.org/10.1021/acsami.7b03873	journal	June 2017
Thermodynamic evaluation and optimization of the (NaCl+KCl+AlCl3) system Robelin, Christian; Chartrand, Patrice; Pelton, Arthur D. The Journal of Chemical Thermodynamics, Vol. 36, Issue 8 https://doi.org/10.1016/j.jct.2004.04.011	journal	August 2004
A Sodium/Beta-Alumina/Nickel Chloride Secondary Cell Galloway, R. C. Journal of The Electrochemical Society, Vol. 134, Issue 1 https://doi.org/10.1149/1.2100421	journal	January 1987
Main Challenges for High Performance NAS Battery: Materials and Interfaces Wen, Zhaoyin; Hu, Yingying; Wu, Xiangwei Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200473	journal	May 2012
Cell degradation of a Na–NiCl2 (ZEBRA) battery Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y. Journal of Materials Chemistry A, Vol. 1, Issue 47 https://doi.org/10.1039/c3ta13644b	journal	January 2013
ZEBRA battery meets USABC goals Dustmann, Cord-H Journal of Power Sources, Vol. 72, Issue 1 https://doi.org/10.1016/S0378-7753(98)00015-9	journal	March 1998
An Advanced Na-FeCl ₂ ZEBRA Battery for Stationary Energy Storage Application Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y. Advanced Energy Materials, Vol. 5, Issue 12 https://doi.org/10.1002/aenm.201500357	journal	April 2015
Novel ternary molten salt electrolytes for intermediate-temperature sodium/nickel chloride batteries Li, Guosheng; Lu, Xiaochuan; Coyle, Christopher A. Journal of Power Sources, Vol. 220 https://doi.org/10.1016/j.jpowsour.2012.07.089	journal	December 2012
Effects of sulfur additive on the performance of Na/NiCl2 cells Ratnakumar, B. V.; Surampudi, S.; Halpert, G. Journal of Power Sources, Vol. 48, Issue 3 https://doi.org/10.1016/0378-7753(94)80031-6	journal	March 1994
Experimental evaluation of the performance of the sodium metal chloride battery below usual operating temperatures Gerovasili, Eirini; May, Johanna F.; Sauer, Dirk Uwe Journal of Power Sources, Vol. 251 https://doi.org/10.1016/j.jpowsour.2013.11.046	journal	April 2014
Development of Sodium-Sulfur Batteries Oshima, Taku; Kajita, Masaharu; Okuno, Akiyasu International Journal of Applied Ceramic Technology, Vol. 1, Issue 3 https://doi.org/10.1111/j.1744-7402.2004.tb00179.x	journal	July 2004

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