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Method to synthesize lanthanide fluoride materials from lanthanide fluorinated alkoxides

Patent ·
OSTI ID:1455058

Lanthanide fluorinated alkoxide derivatives can be synthesized from the alcoholysis reaction of the lanthanide bis-trimethylsilyl amide and an excess amount of hexafluoro iso-propanol. Nanoparticles can be formed from the lanthanide fluorinated alkoxide derivatives by a solvothermal or solution precipitation process.

Research Organization:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
Assignee:
National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
Patent Number(s):
9,981,893
Application Number:
15/010,899
OSTI ID:
1455058
Country of Publication:
United States
Language:
English

References (5)

Advances in Structurally Characterized Lanthanide Alkoxide, Aryloxide, and Silyloxide Compounds journal June 2008
Fluoride electrode with LaF3-membrane and simple disjoining solid-state internal contact journal September 2001
The preparation and characterization of volatile derivatives of trivalent metals using fluorinated alkoxide ligands. X-ray structures of [Sc{OCH(CF3)2}3(NH3)2]2, [Pr{OCMe(CF3)2}3(NH3)2]2, [Y{OCMe(CF3)2}3(thf)3] and [Pr{OCMe2(CF3}3]3 journal January 1992
Nonstoichiometric fluorides—Solid electrolytes for electrochemical devices: A review journal September 2007
Synthesizing Biofunctionalized Nanoparticles to Image Cell Signaling Pathways journal December 2006

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY