Spin-orbit coupled systems in the atomic limit: rhenates, osmates, iridates
Journal Article
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· Physical Review B
- Univ. of Toronto, Toronto, ON (Canada). Dept. of Physics; Canadian Institute for Advanced Research, Toronto, ON (Canada)
- Univ. of Missouri, Columbia, MO (United States). Dept. of Physics and Astronomy
- Univ. of Toronto, Toronto, ON (Canada). Dept. of Physics
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division and Neutron Scattering Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy
Motivated by RIXS experiments on a wide range of complex heavy oxides, including rhenates, osmates, and iridates, we discuss the theory of RIXS for site-localized t2g orbital systems with strong spin-orbit coupling. For such systems, we present exact diagonalization results for the spectrum at different electron fillings, showing that it accesses “single-particle” and “multiparticle” excitations. This leads to a simple picture for the energies and intensities of the RIXS spectra in Mott insulators such as double perovskites which feature highly localized electrons, and yields estimates of the spin-orbit coupling and Hund's coupling in correlated 5d oxides. We present new higher resolution RIXS data at the Re L3 edge in Ba2YReO6 which finds a previously unresolved peak splitting, providing further confirmation of our theoretical predictions. Using ab initio electronic structure calculations on Ba2MReO6 (with M=Re, Os, Ir) we show that while the atomic limit yields a reasonable effective Hamiltonian description of the experimental observations, effects such as t2g–eg interactions and hybridization with oxygen are important. Our ab initio estimate for the strength of the intersite exchange coupling shows that, compared to the d3 systems, the exchange is one or two orders of magnitude weaker in the d2 and d4 materials, which may partly explain the suppression of long-range magnetic order in the latter compounds. As a way to interpolate between the site-localized picture and our electronic structure band calculations, we discuss the spin-orbital levels of the MO6 cluster. In conclusion, this suggests a possible role for intracluster excitons in Ba2YIrO6 which may lead to a weak breakdown of the atomic Jeff = 0 picture and to small magnetic moments.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- Natural Sciences and Engineering Research Council of Canada (NSERC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- Grant/Contract Number:
- AC02-06CH11357; AC05-00OR22725
- OSTI ID:
- 1454394
- Alternate ID(s):
- OSTI ID: 1441102
OSTI ID: 1462735
- Journal Information:
- Physical Review B, Journal Name: Physical Review B Journal Issue: 23 Vol. 97; ISSN 2469-9950; ISSN PRBMDO
- Publisher:
- American Physical Society (APS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Octupolar order in d -orbital Mott insulators
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journal | February 2020 |
Origin of magnetic excitation gap in double perovskite Sr 2 FeOsO 6
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journal | December 2018 |
| Octupolar order in d-orbital Mott insulators | text | January 2019 |
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Spin-orbit coupling controlled ground states in the double perovskite iridates $\textit{A}_2\textit{B}$IrO$_6$ ($\textit{A}$ = Ba, Sr; $\textit{B}$ = Lu, Sc)
Journal Article
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Sun Sep 18 20:00:00 EDT 2022
· Physical Review Materials
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OSTI ID:1892414