Gram scale synthesis of Fe/FexOy core–shell nanoparticles and their incorporation into matrix-free superparamagnetic nanocomposites

Watt, John Daniel; Bleier, Grant C.; Romero, Zachary William; Hance, Bradley G.; Bierner, Jessica Anne; Monson, Todd C.; Huber, Dale L.

doi:10.1557/jmr.2018.139

Title: Gram scale synthesis of Fe/Fe_xO_y core–shell nanoparticles and their incorporation into matrix-free superparamagnetic nanocomposites

Journal Article · Tue May 15 00:00:00 EDT 2018 · Journal of Materials Research

DOI:https://doi.org/10.1557/jmr.2018.139· OSTI ID:1444097

Watt, John Daniel ^[1]; Bleier, Grant C. ^[1]; Romero, Zachary William ^[1]; Hance, Bradley G. ^[1]; Bierner, Jessica Anne ^[1]; Monson, Todd C. ^[1]; Huber, Dale L. ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

In this paper, significant reductions recently seen in the size of wide-bandgap power electronics have not been accompanied by a relative decrease in the size of the corresponding magnetic components. To achieve this, a new generation of materials with high magnetic saturation and permeability are needed. Here, we develop gram-scale syntheses of superparamagnetic Fe/Fe_xO_y core–shell nanoparticles and incorporate them as the magnetic component in a strongly magnetic nanocomposite. Nanocomposites are typically formed by the organization of nanoparticles within a polymeric matrix. However, this approach can lead to high organic fractions and phase separation; reducing the performance of the resulting material. Here, we form aminated nanoparticles that are then cross-linked using epoxy chemistry. The result is a magnetic nanoparticle component that is covalently linked and well separated. By using this ‘matrix-free’ approach, we can substantially increase the magnetic nanoparticle fraction, while still maintaining good separation, leading to a superparamagnetic nanocomposite with strong magnetic properties.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1444097

Report Number(s):: SAND-2018-5581J; 663407

Journal Information:: Journal of Materials Research, Vol. 33, Issue 15; ISSN 0884-2914

Publisher:: Materials Research SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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References (48)

Multipole interaction of polarized single-domain particles Mikuszeit, N.; Vedmedenko, E. Y.; Oepen, H. P. Journal of Physics: Condensed Matter, Vol. 16, Issue 49 https://doi.org/10.1088/0953-8984/16/49/019	journal	November 2004
Synthesis and characterization of novel covalently linked waterborne polyurethane/Fe 3 O 4 nanocomposite films with superior magnetic, conductive properties and high latex storage stability Chen, Suli; Zhang, Sidi; Jin, Tao Chemical Engineering Journal, Vol. 286 https://doi.org/10.1016/j.cej.2015.10.089	journal	February 2016
Superparamagnetism and Other Magnetic Features in Granular Materials: A Review on Ideal and Real Systems Knobel, M.; Nunes, W. C.; Socolovsky, L. M. Journal of Nanoscience and Nanotechnology, Vol. 8, Issue 6 https://doi.org/10.1166/jnn.2008.15348	journal	June 2008
Thermal Decomposition Synthesis of Iron Oxide Nanoparticles with Diminished Magnetic Dead Layer by Controlled Addition of Oxygen Unni, Mythreyi; Uhl, Amanda M.; Savliwala, Shehaab ACS Nano, Vol. 11, Issue 2 https://doi.org/10.1021/acsnano.7b00609	journal	February 2017
Reversible Magnetic Agglomeration: A Mechanism for Thermodynamic Control over Nanoparticle Size Bleier, Grant C.; Watt, John; Simocko, Chester K. Angewandte Chemie International Edition, Vol. 57, Issue 26 https://doi.org/10.1002/anie.201800959	journal	April 2018
Extended LaMer Synthesis of Cobalt-Doped Ferrite Fellows, Benjamin D.; Sandler, Sarah; Livingston, Jacob IEEE Magnetics Letters, Vol. 9 https://doi.org/10.1109/LMAG.2017.2787683	journal	January 2018
Reduction of supported iron oxide studied by temperature-programmed reduction combined with mössbauer spectroscopy and X-ray diffraction Gao, Xingtao; Shen, Jianyi; Hsia, Yuanfu J. Chem. Soc., Faraday Trans., Vol. 89, Issue 7 https://doi.org/10.1039/FT9938901079	journal	January 1993
The effect of needle gauge, needle type, and needle orientation on the volume of a drop Tripp, Geneva K.; Good, Kathryn L.; Motta, Monica J. Veterinary Ophthalmology, Vol. 19, Issue 1 https://doi.org/10.1111/vop.12253	journal	January 2015
Synthesis of Monodisperse Spherical Nanocrystals Park, Jongnam; Joo, Jin; Kwon, Soon Gu Angewandte Chemie International Edition, Vol. 46, Issue 25 https://doi.org/10.1002/anie.200603148	journal	June 2007
Thermal surface free energy and stress of iron Schönecker, Stephan; Li, Xiaoqing; Johansson, Börje Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep14860	journal	October 2015
Fluorescence of Aromatic Amines and Their Fluorescamine Derivatives for Detection of Explosive Vapors Eastwood, Delyle; Fernandez, Carlos; Yoon, B. Yunghoon Applied Spectroscopy, Vol. 60, Issue 9 https://doi.org/10.1366/000370206778397353	journal	September 2006
Polyaniline Stabilized Magnetite Nanoparticle Reinforced Epoxy Nanocomposites Gu, Hongbo; Tadakamalla, Sruthi; Huang, Yudong ACS Applied Materials & Interfaces, Vol. 4, Issue 10 https://doi.org/10.1021/am301529t	journal	September 2012
Determination of Blocking Temperature in Magnetization and Mössbauer Time Scale: A Functional Form Approach Concas, G.; Congiu, F.; Muscas, G. The Journal of Physical Chemistry C, Vol. 121, Issue 30 https://doi.org/10.1021/acs.jpcc.7b01748	journal	July 2017
Thermo-mechanical behaviors of epoxy resins reinforced with silane-epoxide functionalized α-Fe2O3 nanoparticles Pour, Zahra Sekhavat; Ghaemy, Mousa Progress in Organic Coatings, Vol. 77, Issue 8 https://doi.org/10.1016/j.porgcoat.2014.04.001	journal	August 2014
Water-Soluble Iron Oxide Nanoparticles with High Stability and Selective Surface Functionality Xu, Yaolin; Qin, Ying; Palchoudhury, Soubantika Langmuir, Vol. 27, Issue 14 https://doi.org/10.1021/la201652h	journal	July 2011
Carbonyl-Iron/Epoxy Composite Magnetic Core for Planar Power Inductor Used in Package-Level Power Grid Sugawa, Yuichiro; Ishidate, Kazuma; Sonehara, Makoto IEEE Transactions on Magnetics, Vol. 49, Issue 7 https://doi.org/10.1109/TMAG.2013.2250925	journal	July 2013
Alternate current magnetic property characterization of nonstoichiometric zinc ferrite nanocrystals for inductor fabrication via a solution based process Yun, Hongseok; Kim, Jungkwun; Paik, Taejong Journal of Applied Physics, Vol. 119, Issue 11 https://doi.org/10.1063/1.4942865	journal	March 2016
High performance polymer nanocomposites for additive manufacturing applications de Leon, Al C.; Chen, Qiyi; Palaganas, Napolabel B. Reactive and Functional Polymers, Vol. 103 https://doi.org/10.1016/j.reactfunctpolym.2016.04.010	journal	June 2016
Stabilized, Superparamagnetic Functionalized Graphene/Fe ₃ O ₄ @Au Nanocomposites for a Magnetically-Controlled Solid-State Electrochemiluminescence Biosensing Application Gu, Wenling; Deng, Xi; Gu, Xiaoxiao Analytical Chemistry, Vol. 87, Issue 3 https://doi.org/10.1021/ac503966u	journal	January 2015
Iron-Catalyzed Reactions in Organic Synthesis Bolm, Carsten; Legros, Julien; Le Paih, Jacques Chemical Reviews, Vol. 104, Issue 12 https://doi.org/10.1021/cr040664h	journal	December 2004
Core loss and magnetic susceptibility of superparamagnetic Fe nanoparticle assembly Kin, Masane; Kura, Hiroaki; Ogawa, Tomoyuki AIP Advances, Vol. 6, Issue 12 https://doi.org/10.1063/1.4972059	journal	December 2016
Small Angle X-ray Scattering for Nanoparticle Research Li, Tao; Senesi, Andrew J.; Lee, Byeongdu Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.5b00690	journal	April 2016
“Exact” surface free energies of iron surfaces using a modified embedded atom method potential and λ integration Grochola, Gregory; Russo, Salvy P.; Yarovsky, Irene The Journal of Chemical Physics, Vol. 120, Issue 7 https://doi.org/10.1063/1.1637334	journal	February 2004
Enhanced Nanoparticle Size Control by Extending LaMer’s Mechanism Vreeland, Erika C.; Watt, John; Schober, Gretchen B. Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02510	journal	August 2015
Synthesis and magnetic properties of FePt nanocomposite magnets via self-assembled block copolymer templates Wakayama, Hiroaki; Yonekura, Hirotaka Materials Letters, Vol. 171 https://doi.org/10.1016/j.matlet.2016.02.098	journal	May 2016
Facile Synthesis of Monodisperse Superparamagnetic Fe3O4 Core@hybrid@Au Shell Nanocomposite for Bimodal Imaging and Photothermal Therapy Dong, Wenjie; Li, Yongsheng; Niu, Dechao Advanced Materials, Vol. 23, Issue 45 https://doi.org/10.1002/adma.201103521	journal	October 2011
Highly scalable nanoparticle-polymer composite fiber via wet spinning Stone, Roland; Hipp, Stephen; Barden, Joel Journal of Applied Polymer Science, Vol. 130, Issue 3 https://doi.org/10.1002/app.39408	journal	May 2013
Modified Superparamagnetic Nanocomposite Microparticles for Highly Selective Hg ^II or Cu ^II Separation and Recovery from Aqueous Solutions Mandel, Karl; Hutter, Frank; Gellermann, Carsten ACS Applied Materials & Interfaces, Vol. 4, Issue 10 https://doi.org/10.1021/am301910m	journal	September 2012
Cross-Linked “Matrix-Free” Nanocomposites from Reactive Polymer−Silica Hybrid Nanoparticles Dach, Benjamin I.; Rengifo, Hernán R.; Turro, Nicholas J. Macromolecules, Vol. 43, Issue 16 https://doi.org/10.1021/ma101054w	journal	August 2010
Covalent Incorporation of Aminated Nanodiamond into an Epoxy Polymer Network Mochalin, Vadym N.; Neitzel, Ioannis; Etzold, Bastian J. M. ACS Nano, Vol. 5, Issue 9 https://doi.org/10.1021/nn2024539	journal	August 2011
Magnetic nanocomposites Behrens, Silke; Appel, Ingo Current Opinion in Biotechnology, Vol. 39 https://doi.org/10.1016/j.copbio.2016.02.005	journal	June 2016
Implication of Ligand Choice on Surface Properties, Crystal Structure, and Magnetic Properties of Iron Nanoparticles Monson, Todd C.; Ma, Qing; Stevens, Tyler E. Particle & Particle Systems Characterization, Vol. 30, Issue 3 https://doi.org/10.1002/ppsc.201200055	journal	February 2013
Magnetic Epoxy Resin Nanocomposites Reinforced with Core−Shell Structured Fe@FeO Nanoparticles: Fabrication and Property Analysis Zhu, Jiahua; Wei, Suying; Ryu, Jongeun ACS Applied Materials & Interfaces, Vol. 2, Issue 7 https://doi.org/10.1021/am100361h	journal	June 2010
3D-Printing of Lightweight Cellular Composites Compton, Brett G.; Lewis, Jennifer A. Advanced Materials, Vol. 26, Issue 34, p. 5930-5935 https://doi.org/10.1002/adma.201401804	journal	June 2014
Synthesis, Properties, and Applications of Iron Nanoparticles Huber, Dale?L. Small, Vol. 1, Issue 5 https://doi.org/10.1002/smll.200500006	journal	May 2005
Magnetic Properties of Nickel–Zinc Ferrite Toroids Prepared from Nanoparticles Naughton, Brian T.; Majewski, Pawel; Clarke, David R. Journal of the American Ceramic Society, Vol. 90, Issue 11 https://doi.org/10.1111/j.1551-2916.2007.01981.x	journal	November 2007
Nanocomposite Materials from Functional Polymers and Magnetic Colloids Pyun, Jeffrey Polymer Reviews, Vol. 47, Issue 2 https://doi.org/10.1080/15583720701271294	journal	April 2007
Fluorometric determination of secondary amines based on their reaction with fluorescamine Nakamura, Hiroshi.; Tamura, Zenzo. Analytical Chemistry, Vol. 52, Issue 13 https://doi.org/10.1021/ac50063a023	journal	November 1980
Synthesis and application of epoxy resins: A review Jin, Fan-Long; Li, Xiang; Park, Soo-Jin Journal of Industrial and Engineering Chemistry, Vol. 29 https://doi.org/10.1016/j.jiec.2015.03.026	journal	September 2015
Superparamagnetic Nanocomposites Based on the Dispersion of Oleic Acid-Stabilized Magnetite Nanoparticles in a Diglycidylether of Bisphenol A-Based Epoxy Matrix: Magnetic Hyperthermia and Shape Memory Puig, J.; Hoppe, C. E.; Fasce, L. A. The Journal of Physical Chemistry C, Vol. 116, Issue 24 https://doi.org/10.1021/jp3026754	journal	June 2012
Theory of Phase Separation in Polymer Nanocomposites Hooper, Justin B.; Schweizer, Kenneth S. Macromolecules, Vol. 39, Issue 15 https://doi.org/10.1021/ma060577m	journal	July 2006
Broadband magnetic losses of nanocrystalline ribbons and powder cores Beatrice, Cinzia; Dobák, Samuel; Ferrara, Enzo Journal of Magnetism and Magnetic Materials, Vol. 420 https://doi.org/10.1016/j.jmmm.2016.07.045	journal	December 2016
Multifunctional pH-sensitive superparamagnetic iron-oxide nanocomposites for targeted drug delivery and MR imaging Zhu, Lijuan; Wang, Dali; Wei, Xuan Journal of Controlled Release, Vol. 169, Issue 3 https://doi.org/10.1016/j.jconrel.2013.02.015	journal	August 2013
Non-volatile iron carbonyls as versatile precursors for the synthesis of iron-containing nanoparticles Watt, John; Bleier, Grant C.; Austin, Mariah J. Nanoscale, Vol. 9, Issue 20 https://doi.org/10.1039/C7NR01028A	journal	January 2017
Reversible Magnetic Agglomeration: A Mechanism for Thermodynamic Control over Nanoparticle Size Bleier, Grant C.; Watt, John; Simocko, Chester K. Angewandte Chemie, Vol. 130, Issue 26 https://doi.org/10.1002/ange.201800959	journal	April 2018
Iron-Catalyzed Reactions in Organic Synthesis Bolm, Carsten; Legros, Julien; Le Paih, Jacques ChemInform, Vol. 36, Issue 14 https://doi.org/10.1002/chin.200514264	journal	April 2005
Synthesis, Properties, and Applications of Iron Nanoparticles Huber, Dale L. ChemInform, Vol. 36, Issue 47 https://doi.org/10.1002/chin.200547224	journal	November 2005
Synthesis of Monodisperse Spherical Nanocrystals Park, Jongnam; Joo, Jin; Kwon, Soon Gu ChemInform, Vol. 38, Issue 33 https://doi.org/10.1002/chin.200733240	journal	August 2007

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